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3,3′-Bis(3,4,5-trimethoxybenzoyl)-1,1′-(o-phenylene)dithiourea ethanol solvate
In the molecule of the title compound, C28H30N4O8S2·C2H6O, the benzene ring is oriented at dihedral angles of 38.50 (6) and 5.68 (5)° with respect to the trimethoxyphenyl rings, while the two trimethoxyphenyl rings are oriented at a dihedral angle of 44.18 (5)°. Intramolecular N—H⋯O and N—H⋯S hydrogen bonds result in the formation of non-planar six-, seven- and eight-membered rings. The twisting modes of the two side arms are different [C—N—C—O and C—N—C—N torsion angles = 0.1 (3) and 11.8 (3)°, respectively, in one arm, and 4.6 (3) and −11.5 (3)° in the other]. In the crystal structure, intermolecular N—H⋯O and O—H⋯O hydrogen bonds link the molecules
6-(4-Pyridyl)-3-(3,4,5-trimethoxyphenyl)-1,2,4-triazolo[3,4-b][1,3,4]thiadiazole
In the molecule of the title compound, C17H15N5O3S, the planar central heterocylic ring system is oriented at dihedral angles of 5.32 (4) and 9.41 (4)°, respectively with respect to trimethoxyphenyl and pyridine rings. Intramolecular C—H⋯N, C—H⋯O and C—H⋯S hydrogen bonds result in the formation of a nearly planar six-membered ring, which is oriented at a dihedral angle of 3.07 (5)° with respect to the central heterocylic ring system, and non-planar six- and five-membered rings having twist and envelope conformations, respectively. In the crystal structure, intermolecular C—H⋯N and C—H⋯O hydrogen bonds link the molecules. There is a C—H⋯π contact between the pyridine ring and a methyl group and a π–π contact between the central heterocylic ring system and the trimethoxyphenyl ring [centroid–centroid distance = 3.758 (1) Å]
3,6-Bis(3,4,5-trimethoxyphenyl)-1,2,4-triazolo[3,4-b][1,3,4]thiadiazole
In the molecule of the title compound, C21H22N4O6S, the planar central heterocyclic ring system is oriented with respect to the trimethoxyphenyl rings at dihedral angles of 2.60 (5) and 3.60 (6)°. Intramolecular C—H⋯N and C—H⋯S hydrogen bonds result in the formation of planar five- and six-membered rings. In the crystal structure, intermolecular C—H⋯O hydrogen bonds link the molecules. There is a C—H⋯π contact between a methyl group and a trimethoxyphenyl ring, and a π–π contact between the central heterocyclic ring system and a trimethoxyphenyl ring [centroid–centroid distance = 3.640 (1) Å]
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