High-spectral-resolution terahertz imaging with a quantum-cascade laser

We report on a high-spectral-resolution terahertz imaging system operating with a multi-mode quantum-cascade laser (QCL), a fast scanning mirror, and a sensitive Ge:Ga detector. By tuning the frequency of the QCL, several spectra can be recorded in 1.5 s during the scan through a gas cell filled with methanol (CH3OH). These experiments yield information about the local absorption and the linewidth. Measurements with a faster frame rate of up to 3 Hz allow for the dynamic observation of CH3OH gas leaking from a terahertz-transparent tube into the evacuated cell. In addition to the relative absorption, the local pressure is mapped by exploiting the effect of pressure broadening

Characterization of coatings for straylight and photoluminescence suppression in the Raman Spectrometer for MMX (RAX)

The Martian Moons eXploration (MMX) mission led by JAXA to Mars moons Phobos and Deimos involves a small rover developed by DLR/CNES that will be operating on Phobos’ surface. Aboard it is the Raman Spectrometer for MMX (RAX), whose main scientific objectives address Phobos surface mineralogy, its heterogeneity and relation to the Mars mineralogy. Raman spectrometers require strong suppression of straylight, since this technique operates with few nano-Watt signals that should have significant contrast to all other sources of light inside the instrument. The mission requirements involving RAX call for a compact and sophisticated optical design, precluding space for straylight suppressive elements. To optimize straylight suppression in RAX, Raman scattering, Photoluminescence and reflection were characterized for candidate coatings representing different absorbing materials and fabrication technologies over spectral ranges between 530 nm and 680 nm. This was complimented by mechanical testing to aid selection of the coatings for parts inside the RAX flight model

Relevance of Phobos in-situ science for understanding asteroids

The origin of the martian moons, Phobos and Deimos is under debate since a very long time. There exist arguments and counter arguments that they may be captured asteroids. Other models favor, e.g., a massive impact at Mars as their origin [1]. The Martian Moons eXploration (MMX) mission by the Japan Aerospace Exploration Agency, JAXA, is going to explore both Martian moons remotely, but also return samples from Phobos, and deliver a small Rover to its surface [2,3]. This rover, provided by CNES and DLR, with contributions from INTA and the University of Tokyo has a payload of four scientific instruments, analyzing the physical, dynamical and mineralogical properties of Phobos´ surface. Parallels to asteroids of a similar size are eminent and the results will help deciphering the origin of Phobos [4]

OPTICAL DESIGN AND BREADBOARD OF THE RAMAN SPECTROMETER FOR MMX

This paper reports the laboratory confirmation of an optical design for a 0.2 numerical aperture confocal miniaturized, ruggedized Raman visible light spectroscope (RAX) to be borne by an autonomous rover landed on the martian moon, Phobos

In situ science on Phobos with the Raman spectrometer for MMX (RAX): preliminary design and feasibility of Raman meausrements

Mineralogy is the key to understanding the origin of Phobos and its position in the evolution of the Solar System. In situ Raman spectroscopy on Phobos is an important tool to achieve the scientifc objectives of the Martian Moons eXploration (MMX) mission, and maximize the scientifc merit of the sample return by characterizing the mineral composition and heterogeneity of the surface of Phobos. Conducting in situ Raman spectroscopy in the harsh environment of Phobos requires a very sensitive, compact, lightweight, and robust instrument that can be carried by the compact MMX rover. In this context, the Raman spectrometer for MMX (i.e., RAX) is currently under development via international collaboration between teams from Japan, Germany, and Spain. To demonstrate the capability of a compact Raman system such as RAX, we built an instrument that reproduces the optical performance of the fight model using commercial of-the-shelf parts. Using this performance model, we measured mineral samples relevant to Phobos and Mars, such as anhydrous silicates, carbonates, and hydrous minerals. Our measurements indicate that such minerals can be accurately identifed using a RAX-like Raman spectrometer. We demonstrated a spectral resolution of approximately 10 cm−1, high enough to resolve the strongest olivine Raman bands at ~820 and ~850 cm−1, with highly sensitive Raman peak measurements (e.g., signal-to-noise ratios up to 100). These results strongly suggest that the RAX instrument will be capable of determining the minerals expected on the surface of Phobos, adding valuable information to address the question of the moon’s origin, heterogeneity, and circum-Mars material transport

Real-Time Molecular Spectroscopy through Self-Mixing in a Terahertz Quantum-Cascade Laser

We report on a new detection method for real-time molecular spectroscopy with a terahertz quantum-cascade laser. The self-mixing effect is exploited to tune the lasing frequency across molecular absorption lines of D2O and CH3OD and for the detection of the self-mixing signal. The method allows for realtime monitoring of gas mixtures in an absorption cell

Real-time gas sensing based on optical feedback in a terahertz quantum-cascade laser

We report on real-time gas sensing with a terahertz quantum-cascade laser (QCL). The method is solely based on the modulation of the external cavity length, exploiting the intermediate optical feedback regime. While the QCL is operated in continuous-wave mode, optical feedback results in a change of the QCL frequency as well as its terminal voltage. The first effect is exploited to tune the lasing frequency across a molecular absorption line. The second effect is used for the detection of the self-mixing signal. This allows for fast measurement times on the order of 10 ms per spectrum and for real-time measurements of gas concentrations with a rate of 100 Hz. This technique is demonstrated with a mixture of D2O and CH3OD in an absorption cell