Zero modes' fusion ring and braid group representations for the extended chiral su(2) WZNW model

The zero modes' Fock space for the extended chiral $su(2)$ WZNW model gives room to a realization of the Grothendieck fusion ring of representations of the restricted $U_q sl(2)$ quantum universal enveloping algebra (QUEA) at an even ($2h$-th) root of unity, and of its extension by the Lusztig operators. It is shown that expressing the Drinfeld images of canonical characters in terms of Chebyshev polynomials of the Casimir invariant $C$ allows a streamlined derivation of the characteristic equation of $C$ from the defining relations of the restricted QUEA. The properties of the fusion ring of the Lusztig's extension of the QUEA in the zero modes' Fock space are related to the braiding properties of correlation functions of primary fields of the extended $su(2)_{h-2}$ current algebra model.Comment: 36 pages, 1 figure; version 3 - improvements in Sec. 2 and 3: definitions of the double, as well as R- (and M-)matrix changed to fit the zero modes' one

Quantum matrix algebra for the SU(n) WZNW model

The zero modes of the chiral SU(n) WZNW model give rise to an intertwining quantum matrix algebra A generated by an n x n matrix a=(a^i_\alpha) (with noncommuting entries) and by rational functions of n commuting elements q^{p_i}. We study a generalization of the Fock space (F) representation of A for generic q (q not a root of unity) and demonstrate that it gives rise to a model of the quantum universal enveloping algebra U_q(sl_n), each irreducible representation entering F with multiplicity 1. For an integer level k the complex parameter q is an even root of unity, q^h=-1 (h=k+n) and the algebra A has an ideal I_h such that the factor algebra A_h = A/I_h is finite dimensional.Comment: 48 pages, LaTeX, uses amsfonts; final version to appear in J. Phys.

Extended chiral algebras in the SU(2)_0 WZNW model

We investigate the W-algebras generated by the integer dimension chiral primary operators of the SU(2)_0 WZNW model. These have a form almost identical to that found in the c=-2 model but have, in addition, an extended Kac-Moody structure. Moreover on Hamiltonian reduction these SU(2)_0 W-algebras exactly reduce to those found in c=-2. We explicitly find the free field representations for the chiral j=2 and j=3 operators which have respectively a fermionic doublet and bosonic triplet nature. The correlation functions of these operators accounts for the rational solutions of the Knizhnik-Zamolodchikov equation that we find. We explicitly compute the full algebra of the j=2 operators and find that the associativity of the algebra is only guaranteed if certain null vectors decouple from the theory. We conjecture that these algebras may produce a quasi-rational conformal field theory.Comment: 18 pages LATEX. Minor corrections. Full j=2 algebra adde

Adsorption and reaction of CO on (Pd–)Al2O3 and (Pd–)ZrO2: vibrational spectroscopy of carbonate formation

γ-Alumina is widely used as an oxide support in catalysis, and palladium nanoparticles supported by alumina represent one of the most frequently used dispersed metals. The surface sites of the catalysts are often probed via FTIR spectroscopy upon CO adsorption, which may result in the formation of surface carbonate species. We have examined this process in detail utilizing FTIR to monitor carbonate formation on γ-alumina and zirconia upon exposure to isotopically labelled and unlabelled CO and CO2. The same was carried out for well-defined Pd nanoparticles supported on Al2O3 or ZrO2. A water gas shift reaction of CO with surface hydroxyls was detected, which requires surface defect sites and adjacent OH groups. Furthermore, we have studied the effect of Cl synthesis residues, leading to strongly reduced carbonate formation and changes in the OH region (isolated OH groups were partly replaced or were even absent). To corroborate this finding, samples were deliberately poisoned with Cl to an extent comparable to that of synthesis residues, as confirmed by Auger electron spectroscopy. For catalysts prepared from Cl-containing precursors a new CO band at 2164 cm−1 was observed in the carbonyl region, which was ascribed to Pd interacting with Cl. Finally, the FTIR measurements were complemented by quantification of the amount of carbonates formed via chemisorption, which provides a tool to determine the concentration of reactive defect sites on the alumina surface

Indecomposable U_q(sl_n) modules for q^h = -1 and BRS intertwiners

A class of indecomposable representations of U_q(sl_n) is considered for q an even root of unity (q^h = -1) exhibiting a similar structure as (height h) indecomposable lowest weight Kac-Moody modules associated with a chiral conformal field theory. In particular, U_q(sl_n) counterparts of the Bernard-Felder BRS operators are constructed for n=2,3. For n=2 a pair of dual d_2(h) = h dimensional U_q(sl_2) modules gives rise to a 2h-dimensional indecomposable representation including those studied earlier in the context of tensor product expansions of irreducible representations. For n=3 the interplay between the Poincare'-Birkhoff-Witt and (Lusztig) canonical bases is exploited in the study of d_3(h) = h(h+1)(2h+1)/6 dimensional indecomposable modules and of the corresponding intertwiners.Comment: 31 pages, LaTeX, amsfonts, amssym