Effect of Modification of Mongolian Natural Zeolites on Adsorption of Chromium from Aqueous Solution

Removal of chromium (Cr (III) ) as well as hexavalent chromium (Cr (VI) ) from tannery wastewater at same time by adsorption using Mongolian natural zeolite was studied in terms of the characteristics, modification, and chromium adsorption performance of the zeolite. The cation exchange capacity of the zeolite ranged from 37×10−3 to 144×10−3 eq·g−1. From the results of phase identification and elemental analysis of the zeolite after modification run, the zeolite was not decomposed and was modified successfully. The zeolites modified by Ba2+, Cu2+, and HDTMA-Br could adsorb Cr (III) as well as the unmodified one could. The higher pH gave the higher adsorption ability, similarly to the adsorption of Cr (VI). Consequently, this adsorption method with Mongolian natural zeolite was proposed to remove Cr (III) together with Cr (VI) from tannery wastewater at same time.DOI: http://dx.doi.org/10.5564/pmas.v0i4.49Proceedings of the Mongolian Academy of Sciences 2009 No 4 pp.71-7

Adsorption of heavy metals in mine wastewater by Mongolian natural zeolite

AbstractIn the first, Mongolian natural zeolites, whose base components were clinoptilolite, mordenite, and chabazite, were characterized in terms of element content, cation exchange capacity, and the like. Since the molar ratios of aluminum relative to silicon contained in Mongolian natural zeolites used in this study were lower than those of pure zeolites, the natural zeolite samples contained substantial amounts of impurities. The cation exchange capacity of the natural zeolite sample relatively increased with increasing aluminum content in the zeolite sample. Secondly, the batch equilibrium adsorptions of heavy metals, i.e., copper, zinc, and manganese, from model aqueous wastewater by Mongolian natural zeolites were carried. The natural zeolites could adsorb and remove the heavy metals in the aqueous solutions. The precipitation of metal hydroxide affected the results of adsorption in some cases. The saturated adsorbed amounts of the heavy metals estimated by Langmuir equation were almost same with one another, increased with solution pH and with cation exchange capacity of the natural zeolite

Uptake Rate of Ammonia-nitrogen With Sterile Ulva sp. for Water Quality Control of Intensive ShrimpCulture Ponds in Developing Countries

Ammonia-nitrogen uptake by seaweed was modeled based on the concept of ammonia-nitrogen permeation through cell membrane, and the derived model of uptake rate was experimentally verified. In this study, sterile Ulva sp. was employed as seaweed to treat model culture solution, and the distribution equilibrium of the ammonia-nitrogen between the culture solution and cell inside was measured to obtain the equilibrium. For this measurement, the seaweed was pretreated before the uptake runs to inhibit the assimilation by methionine sulfoximine for removal of the assimilation effects on the uptake rate. The parameters of the distribution equilibrium and permeation rate of ammonia-nitrogen were measured. The pretreated seaweed could uptake ammonia-nitrogen and the ammonia-nitrogen permeated through the cell membrane from the culture solution into the cell according to the concentration gradient. The seaweed saturated with ammonia-nitrogen was immersed in the culture solution without ammonia-nitrogen and it could excrete ammonia-nitrogen once taken in. In both cases of the uptake and excretion, the systems attained equilibrium after around 6 hours. The ammonia-nitrogen concentration in the cell increased with the concentration in the culture solution at equilibrium. The flux of ammonia-nitrogen was almost proportional to the concentration difference, defined as that between the ammonia-nitrogen concentration in the cell and the hypothetical concentration of ammonia-nitrogen in the cell which is in equilibrium with the culture solution. The overall permeation coefficient was measured as 9.1 · 10–3 m h–1 for both cases of uptake and excretion, and this relationship was valid when the concentration difference was large enough relative to the flux

Effects of Sterile Ulva sp. Growth Rate on Water Quality Control of Intensive Shrimp Culture Pond in Developing Countries

To control the water quality in the intensive shrimp mariculture pond by uptaking the total ammonia-nitrogen with sterile Ulva sp., the growth rate of sterile Ulva sp. was experimentally measured and the influence of the rate on the water quality control evaluated. The specific growth rate constant of the seaweed increased with the total ammonia-nitrogen concentration, photosynthetic photon flux density and operating temperature. Then the dynamics of ammonia-nitrogen in the modeled culture pond for the intensive shrimp farming in the tropical region were numerically simulated, in which the seaweed was used to uptake ammonia-nitrogen. The seaweed could uptake ammonia-nitrogen effectively during daytime mainly due to the high intensity of sun light, and the total ammonia-nitrogen concentration in the shrimp pond could be kept very low. The required seaweed density to control the total ammonia-nitrogen concentration less than the recommended maximum concentration of 1.0 ⋅ 10–3 kg N m–3 was estimated to be reasonable

Effects of Inhibitory Factor on Uptake Rate of Ammonia-Nitrogen with Sterile Ulva sp. for Water Quality Control of Intensive Shrimp Culture Ponds

Ammonia-nitrogen uptake by sterile Ulva sp. was studied for the control of culture pond water of intensive shrimp farming. The uptake rates were measured by batch and semi-continuous operations, and analyzed with the Michaelis-Menten model of uncompetitive inhibition. For the batch uptake operations, the Michaelis-Menten parameters were estimated, and the maximum rate and Michaelis constants were estimated as 3.4 × 10–2 kg kg–1 h–1 and 5.5 × 10–3 kg m–3, respectively. The inhibitory factor increased with the uptake time and with the decrease of the seaweed density. In the cases of semi-continuous operations, the seaweed could continuously treat with the model farming culture solution. Although the ratio of the seaweed density relative to the rate of ammonia-nitrogen generation should be appropriately adjusted to keep lower inhibitory factor in the seaweed, the ammonia-nitrogen concentration could be maintained at a relatively low level during operation. Then the ammonia-nitrogen uptake by the alga water was roughly simulated and operation with moderate density of the algae in the pond could maintain the ammonia-nitrogen concentration at a sufficiently low level in the shrimp farming pond. The suggested treatment process might be attractive to control pond water quality for intensive shrimp farming

Uptake Rate of Ammonia-nitrogen With Sterile Ulva sp. for Water Quality Control of Intensive ShrimpCulture Ponds in Developing Countries

Ammonia-nitrogen uptake by seaweed was modeled based on the concept of ammonia-nitrogen permeation through cell membrane, and the derived model of uptake rate was experimentally verified. In this study, sterile Ulva sp. was employed as seaweed to treat model culture solution, and the distribution equilibrium of the ammonia-nitrogen between the culture solution and cell inside was measured to obtain the equilibrium. For this measurement, the seaweed was pretreated before the uptake runs to inhibit the assimilation by methionine sulfoximine for removal of the assimilation effects on the uptake rate. The parameters of the distribution equilibrium and permeation rate of ammonia-nitrogen were measured. The pretreated seaweed could uptake ammonia-nitrogen and the ammonia-nitrogen permeated through the cell membrane from the culture solution into the cell according to the concentration gradient. The seaweed saturated with ammonia-nitrogen was immersed in the culture solution without ammonia-nitrogen and it could excrete ammonia-nitrogen once taken in. In both cases of the uptake and excretion, the systems attained equilibrium after around 6 hours. The ammonia-nitrogen concentration in the cell increased with the concentration in the culture solution at equilibrium. The flux of ammonia-nitrogen was almost proportional to the concentration difference, defined as that between the ammonia-nitrogen concentration in the cell and the hypothetical concentration of ammonia-nitrogen in the cell which is in equilibrium with the culture solution. The overall permeation coefficient was measured as 9.1 · 10–3 m h–1 for both cases of uptake and excretion, and this relationship was valid when the concentration difference was large enough relative to the flux