4,873 research outputs found
Hydrothermal synthesis of α-MnO<inf>2</inf> and β-MnO <inf>2</inf> nanorods as high capacity cathode materials for sodium ion batteries
Two types of MnO2 polymorphs, α-MnO2 and β-MnO2 nanorods, have been synthesized by a hydrothermal method. Their crystallographic phases, morphologies, and crystal structures were characterized by XRD, FESEM and TEM analysis. Different exposed crystal planes have been identified by TEM. The electrochemical properties of α-MnO 2 and β-MnO2 nanorods as cathode materials in Na-ion batteries were evaluated by galvanostatic charge/discharge testing. Both α-MnO2 and β-MnO2 nanorods achieved high initial sodium ion storage capacities of 278 mA h g-1 and 298 mA h g-1, respectively. β-MnO2 nanorods exhibited a better electrochemical performance such as good rate capability and cyclability than that of α-MnO2 nanorods, which could be ascribed to a more compact tunnel structure of β-MnO2 nanorods. Furthermore, the one-dimensional architecture of nanorods could also contribute to facile sodium ion diffusion in the charge and discharge process. © The Royal Society of Chemistry 2013
SnO<inf>2</inf>@graphene nanocomposites as anode materials for Na-ion batteries with superior electrochemical performance
An in situ hydrothermal synthesis approach has been developed to prepare SnO2@graphene nanocomposites. The nanocomposites exhibited a high reversible sodium storage capacity of above 700 mA h g-1 and excellent cyclability for Na-ion batteries. In particular, they also demonstrated a good high rate capability for reversible sodium storage. © 2013 The Royal Society of Chemistry
Effects of shear connectors on plate-reinforced composite coupling beams of short and medium-length spans
Experimental studies on the newly proposed design of plate-reinforced composite (PRC) coupling beams have been carried out. Previous results have demonstrated the useful application of this design in coupling beams of medium span-to-depth ratios (l/h) under both inelastic seismic and elastic wind loading. This paper presents further experimental studies on five PRC coupling beams, which investigated the importance of shear connectors on plate/reinforced concrete composite action. Three medium-length (l/h=2.5) and two short (l/h=1.17) PRC coupling beams, each containing a vertically embedded steel plate, were tested under reversed cyclic loading. While one short beam was welded with expanded metal meshes on the plate surfaces, others were welded with shear studs on the plates in the wall regions and/or the beam spans. Results showed that the expanded metal meshes did not work effectively, and while the shear studs in the beam span only slightly increased the beam capacity, those in the wall regions contributed considerably in improving inelastic beam performance. © 2005 Elsevier Ltd. All rights reserved.postprin
Hydrothermal synthesis of I?-MnO2 and I?-MnO2 nanorods as high capacity cathode materials for sodium ion batteries
Two types of MnO2 polymorphs, I?-MnO2 and I?-MnO2 nanorods, have been synthesized by a hydrothermal method. Their crystallographic phases, morphologies, and crystal structures were characterized by XRD, FESEM and TEM analysis. Different exposed crystal planes have been identified by TEM. The electrochemical properties of I?-MnO2 and I?-MnO2 nanorods as cathode materials in Na-ion batteries were evaluated by galvanostatic charge/discharge testing. Both I?-MnO2 and I?-MnO2 nanorods achieved high initial sodium ion storage capacities of 278 mA h ga??1 and 298 mA h ga??1, respectively. I?-MnO2 nanorods exhibited a better electrochemical performance such as good rate capability and cyclability than that of I?-MnO2 nanorods, which could be ascribed to a more compact tunnel structure of I?-MnO2 nanorods. Furthermore, the one-dimensional architecture of nanorods could also contribute to facile sodium ion diffusion in the charge and discharge process
Behaviour of plate anchorage in plate-reinforced composite coupling beams
As a new alternative design, plate-reinforced composite (PRC) coupling beam achieves enhanced strength and ductility by embedding a vertical steel plate into a conventionally reinforced concrete (RC) coupling beam. Based on a non-linear finite element model developed in the authors’ previous study, a parametric study presented in this paper has been carried out to investigate the influence of several key parameters on the overall performance of PRC coupling beams. The effects of steel plate geometry, span-to-depth ratio of beams and steel reinforcement ratios at beam spans and in wall regions are quantified. It is found that the anchorage length of the steel plate is primarily controlled by the span-to-depth ratio of the beam. Based on the numerical results, a design curve is proposed for determining the anchorage length of the steel plate. The load-carrying capacity of short PRC coupling beams with high steel ratio is found to be controlled by the steel ratio of wall piers. The maximum shear stress of PRC coupling beams should be limited to 15 MPa.published_or_final_versio
PCN44 INCIDENCE AND COSTS OF TREATMENT-RELATED COMPLICATIONS AMONG PATIENTS WITH ADVANCED SQUAMOUS CELL CARCINOMA OF THE HEAD AND NECK
Núm. a Art Públic 9008Batlle, Enric; Roig, Joan; Ros Sabaté, Joaqui
Cavitation of Electrons Bubbles in Liquid Helium Below saturation Pressure
We have used a Hartree-type electron-helium potential together with a density
functional description of liquid He and He to study the explosion of
electron bubbles submitted to a negative pressure. The critical pressure at
which bubbles explode has been determined as a function of temperature. It has
been found that this critical pressure is very close to the pressure at which
liquid helium becomes globally unstable in the presence of electrons. It is
shown that at high temperatures the capillary model overestimates the critical
pressures. We have checked that a commonly used and rather simple
electron-helium interaction yields results very similar to those obtained using
the more accurate Hartree-type interaction. We have estimated that the
crossover temperature for thermal to quantum nucleation of electron bubbles is
very low, of the order of 6 mK for He.Comment: 22 pages, 9 figure
Discordance between Liver Biopsy and FibroScan® in Assessing Liver Fibrosis in Chronic Hepatitis B: Risk Factors and Influence of Necroinflammation
BACKGROUND: Few studies have investigated predictors of discordance between liver biopsy (LB) and liver stiffness measurement (LSM) using FibroScan®. We assessed predictors of discordance between LB and LSM in chronic hepatitis B (CHB) and investigated the effects of necroinflammatory activity. METHODS: In total, 150 patients (107 men, 43 women) were prospectively enrolled. Only LSM with ≥ 10 valid measurements was considered reliable. Liver fibrosis was evaluated using the Laennec system. LB specimens <15 mm in length were considered ineligible. Reference cutoff LSM values to determine discordance were calculated from our cohort (6.0 kPa for ≥ F2, 7.5 kPa for ≥ F3, and 9.4 kPa for F4). RESULTS: A discordance, defined as a discordance of at least two stages between LB and LSM, was identified in 21 (14.0%) patients. In multivariate analyses, fibrosis stages F3-4 and F4 showed independent negative associations with discordance (P = 0.002; hazard ratio [HR], 0.073; 95% confidence interval [CI], 0.014-0.390 for F3-4 and P = 0.014; HR, 0.067; 95% CI, 0.008-0.574 for F4). LSM values were not significantly different between maximal activity grades 1-2 and 3-4 in F1 and F2 fibrosis stages, whereas LSM values were significantly higher in maximal activity grade 3-4 than 1-2 in F3 and F4 fibrosis stage (median 8.6 vs. 11.3 kPa in F3, P = 0.049; median 11.9 vs. 19.2 kPa in F4, P = 0.009). CONCLUSION: Advanced fibrosis stage (F3-4) or cirrhosis (F4) showed a negative correlation with discordance between LB and LSM in patients with CHB, and maximal activity grade 3-4 significantly influenced LSM values in F3 and F4
Anyons in a weakly interacting system
We describe a theoretical proposal for a system whose excitations are anyons
with the exchange phase pi/4 and charge -e/2, but, remarkably, can be built by
filling a set of single-particle states of essentially noninteracting
electrons. The system consists of an artificially structured type-II
superconducting film adjacent to a 2D electron gas in the integer quantum Hall
regime with unit filling fraction. The proposal rests on the observation that a
vacancy in an otherwise periodic vortex lattice in the superconductor creates a
bound state in the 2DEG with total charge -e/2. A composite of this
fractionally charged hole and the missing flux due to the vacancy behaves as an
anyon. The proposed setup allows for manipulation of these anyons and could
prove useful in various schemes for fault-tolerant topological quantum
computation.Comment: 7 pages with 3 figures. For related work and info visit
http://www.physics.ubc.ca/~fran
Impedance of nanometer thickness ferromagnetic Co40Fe40B20 films
Nanocrystalline Co40Fe40B20 films, with film thickness tf = 100 nm, were deposited on glass substrates by the magnetron sputtering method at room temperature. During the film deposition period, a dc magnetic field, h = 40 Oe, was applied to introduce an easy axis for each film sample: one with h||L and the other with h||w, where L and w are the length and width of the film. Ferromagnetic resonance (FMR), ultrahigh frequency impedance (IM), dc electrical resistivity (ρ), and magnetic hysteresis loops (MHL) of these films were studied. From the MHL and r measurements, we obtain saturation magnetization 4πMs = 15.5 kG, anisotropy field Hk = 0.031 kG, and r = 168 mW.cm. From FMR, we can determine the Kittel mode ferromagnetic resonance (FMR-K) frequency fFMRK = 1,963 MHz. In the h||L case, IM spectra show the quasi-Kittel-mode ferromagnetic resonance (QFMR-K) at f0 and the Walker-mode ferromagnetic resonance (FMR-W) at fn, where n = 1, 2, 3, and 4. In the h||w case, IM spectra show QFMR-K at F0 and FMR-W at Fn. We find that f0 and F0 are shifted from fFMRK, respectively, and fn = Fn. The in-plane spin-wave resonances are responsible for those relative shifts
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