Effect of composition on thermoelectric properties of polycrystalline CrSi2

Ingots with compositions CrSi2−x (with 0 < x < 0.1) were synthesized by vacuum arc melting followed by uniaxial hot pressing for densification. This paper reports the temperature and composition dependence of the electrical resistivity, Seebeck coefficient, and thermal conductivity of CrSi2−x samples in the temperature range of 300 K to 800 K. The silicon-deficient samples exhibited substantial reductions in resistivity and Seebeck coefficient over the measured temperature range due to the formation of metallic secondary CrSi phase embedded in the CrSi2 matrix phase. The thermal conductivity was seen to exhibit a U-shaped curve with respect to x, exhibiting a minimum value at the composition of x = 0.04. However, the limit of the homogeneity range of CrSi2 suppresses any further decrease of the lattice thermal conductivity. As a consequence, the maximum figure of merit of ZT = 0.1 is obtained at 650 K for CrSi1.98

Microencrusters from the Upper Jurassic–Lower Cretaceous İnaltı Formation (Central Pontides, Turkey): remarks on the development of reefal/peri-reefal facies

A detailed taxonomical study was carried out for the identification of encrusting micro- organisms. Among these microencrusters, Perturbatacrusta leini, Iberopora bodeuri, Calcistella jachenhausenensis, and Pseudorothpletzella schmidi have been taxonomically revealed for the first time in Turkey. Within the biostratigraphic frame of the I. nalti Formation consisting of Mesoendothyra izjumiana zone ( Kimmeridgian), Calcistella jachenhausenensis zone ( Lower Tithonian- Upper Tithonian) and Protopeneroplis ultragranulata zone ( Upper Tithonian- Berriasian), carbonate sedimentation occurred in five depositional environments comprising slope, fore- reef, reef, back- reef and lagoonal environments. The majority of the reefal deposits of the I. nalti carbonates can be classified as coral- microbial- microencruster boundstones, which frequently occur in association with back- reef and fore- reef deposits within the Kimmeridgian- Berriasian interval. A shallowing and a subsequent deepening of water depth in the Berriasian have been revealed by the examination of stacking patterns and vertical evolution of the microfacies. Based on the observed microfacies and general features of micro- encrusting organisms, it is concluded that I. nalti carbonates share many similarities with the reefal carbonate deposits of Intra- Tethyan domain in terms of microfacies types and microencruster content