The potential biodiesel production from Cerbera odollam oil (Bintaro) in Aceh

© The Authors, published by EDP Sciences, 2018. Biodiesel production from non-edible vegetable oils is an effective way to conquer the linked problems with edible oils such as food versus fuel and other environmental impacts. Cerbera odollam oil is one of these possible non-edible feed stocks for future biodiesel production. This study evaluated the potential biodiesel production from cerbera odollam. The seed was collected and extracted from Aceh, Indonesia. Moreover, biodiesel has been produced using degummed (H3PO4) and two step acid catalyst (HCl) and alkaline catalyst (KOH). The results of properties of the cerbera odollam methyl esters show that such as viscosity was about 847.9 mm2/s, density was 3.1578 kg/m3, flash point was 214.0°C, acid value was 0.4 mg KOH/g, oxidation stability was 6.35 h, FAME content was 97.77 % w/w and heating value was 40.49 MJ/kg. After analysing these properties, it has been found that there is a huge chance to produce biodiesel from this seed which complies with the limits of ASTM 6751 and EN 14214 specifications and therefore it can boost the future production of biodiesel from non-edible sources

Friction and Wear Performance Evaluation of Bio-Lubricants and DLC Coatings on Cam/Tappet Interface of Internal Combustion Engines.

The environmental concerns associated with artificially formulated engine oils have forced a shift towards bio-based lubricants. The deposition of hard coatings on engine components and migrating to environmentally friendly green lubricants can help in this regard. Chemically modified forms of vegetable oils, with better low-temperature characteristics and enhanced thermo-oxidative stability, are suitable substitutes to conventional lubricant base oils. The research presented in this manuscript was undertaken to experimentally investigate the wear and friction performance of a possible future generation of an environmentally friendly bio-based lubricant as a potential replacement for conventional engine lubricants. In order to quantify the tribological benefits which can be gained by the deposition of DLC coatings, (an (a-C:H) hydrogenated DLC coating and an (a-C:H:W) tungsten-doped DLC coating) were applied on the cam/tappet interface of a direct acting valve train assembly of an internal combustion engine. The tribological correlation between DLC-coated engine components, lubricant base oils and lubricant additives have been thoroughly investigated in this study using actual engine operating conditions. Two additive-free base oils (polyalphaolefines (PAO) and chemically-modified palm oil (TMP)) and two multi-additive-containing lubricants were used in this investigation. Real-time drive torque was measured to determine the friction force, detailed post-test analysis was performed, which involved the use of a specialized jig to measure camlobe wear. An optical profilometer was used to measure the wear on the tappet, high-resolution scanning electron microscopy was employed to study the wear mechanism and energy-dispersive X-ray spectroscopy was performed on the tested samples to qualitatively access the degradation of the coating. When using additive-free TMP, a low friction coefficient was observed for the cam/tappet interface. The presence of additives further improved the friction characteristics of TMP, resulting in reduced average friction torque values. A tremendous enhancement in wear performance was recorded with a-C:H-coated parts and the coating was able to withstand the test conditions with little or no delamination

Study on the tribological characteristics of plant oil-based bio-lubricant with automotive liner-piston ring materials

The development of bio-lubricant is an immerging area of research considering the rapid depletion of petroleum reserve and environmental concern. This study aims to develop non-edible jatropha oil-based bio-lubricant and investigate the tribological properties considering commonly used piston ring-cylinder liner materials of stainless steel and cast iron due to their interaction under lubricated conditions in an internal combustion engine. The bio-lubricant was prepared by blending different percentages of vegetable oil with commercial lubricants. The tribological test was carried out using a Reo-Bicerihigh-frequency reciprocating rig (HFRR) for the duration of 6 ​h under standard operating conditions. Different properties of bio-lubricants were measured before and after the HFRR test using various analytical instruments. The morphology of the worn material surfaces was examined via Hitachi S-4700 FE-SEM cold field emission high resolution scanning electron microscopy (SEM). The result showed that addition of vegetable oil lubricant up to 7.5% concentration can be compared with commercial lubricant in case of wear rate and coefficient of wear as weight loss reduced significantly. Minimum change in viscosity was observed at the addition of 7.5% bio-lubricant. Surface morphology analysis confirmed less damage of metal surface when tribological analysis were performed at mixed lubricated condition

An Overview of Biodiesel Production via Calcium Oxide Based Catalysts: Current State and Perspective

Biodiesel is a clean, renewable, liquid fuel that can be used in existing diesel engines without modification as pure or blend. Transesterification (the primary process for biodiesel generation) via heterogeneous catalysis using low-cost waste feedstocks for catalyst synthesis improves the economics of biodiesel production. Heterogeneous catalysts are preferred for the industrial generation of biodiesel due to their robustness and low costs due to the easy separation and relatively higher reusability. Calcium oxides found in abundance in nature, e.g., in seashells and eggshells, are promising candidates for the synthesis of heterogeneous catalysts. However, process improvements are required to design productive calcium oxide-based catalysts at an industrial scale. The current work presents an overview of the biodiesel production advancements using calcium oxide-based catalysts (e.g., pure, supported, and mixed with metal oxides). The review discusses different factors involved in the synthesis of calcium oxide-based catalysts, and the effect of reaction parameters on the biodiesel yield of calcium oxide-based catalysis are studied. Further, the common reactor designs used for the heterogeneous catalysis using calcium oxide-based catalysts are explained. Moreover, the catalytic activity mechanism, challenges and prospects of the application of calcium oxide-based catalysts in biodiesel generation are discussed. The study of calcium oxide-based catalyst should continue to be evaluated for the potential of their application in the commercial sector as they remain the pivotal goal of these studies

Effect of additivized biodiesel blends on diesel engine performance, emission, tribological characteristics, and lubricant tribology

© 2020 by the authors. This research work focuses on investigating the lubricity and analyzing the engine characteristics of diesel-biodiesel blends with fuel additives (titanium dioxide (TiO2) and dimethyl carbonate (DMC)) and their effect on the tribological properties of a mineral lubricant. A blend of palm-sesame oil was used to produce biodiesel using ultrasound-assisted transesterification. B30 (30% biodiesel + 70% diesel) fuel was selected as the base fuel. The additives used in the current study to prepare ternary fuel blends were TiO2 and DMC. B30 + TiO2 showed a significant reduction of 6.72% in the coefficient of friction (COF) compared to B30. B10 (Malaysian commercial diesel) exhibited very poor lubricity and COF among all tested fuels. Both ternary fuel blends showed a promising reduction in wear rate. All contaminated lubricant samples showed an increment in COF due to the dilution of combustible fuels. Lub + B10 (lubricant + B10) showed the highest increment of 42.29% in COF among all contaminated lubricant samples. B30 + TiO2 showed the maximum reduction (6.76%) in brake-specific fuel consumption (BSFC). B30 + DMC showed the maximum increment (8.01%) in brake thermal efficiency (BTE). B30 + DMC exhibited a considerable decline of 32.09% and 25.4% in CO and HC emissions, respectively. The B30 + TiO2 fuel blend showed better lubricity and a significant improvement in engine characteristics

RSM and Artificial Neural Networking based production optimization of sustainable Cotton bio-lubricant and evaluation of its lubricity & tribological properties

Depletion of mineral reservoirs along with health and environmental concerns have led to a greater focus on bio-lubricants. The purpose of this study was to analyze and optimize the reaction conditions of the transesterification process for cotton biolubricant synthesis by using Response Surface Methodology (RSM). In RSM, Rotatable central composite design was selected to examine the effect of reaction input factors on the yield of cotton bio-lubricant during the transesterification process. ANOVA analysis showed that temperature was the most significant factor followed by time, pressure and catalyst-concentration. Optimum reaction conditions obtained by RSM for maximum TMP tri-ester (cotton bio-lubricant) yield of about 37.52% were 144 °C temperature, 10 h time, 25 mbar pressure, and 0.8% catalyst-concentration. RSM predicted results were successfully validated experimentally and by artificial neural networking. About 90%–94% cotton seed oil bio-lubricant was obtained after purification and its physiochemical, lubricity and tribological properties were evaluated and found comparable with ISO VG-46 and SAE-40 mineral lubricant. Hence, cottonseed oil is a potential source for the bio-lubricant industry

Effect of alcoholic and nano-particles additives on tribological properties of diesel–palm–sesame–biodiesel blends

This study focused on evaluating the lubricity of diesel–biodiesel fuel with oxygenated alcoholic and nano-particle additives. Fuel injection system lubrication depended primarily on the fuel used in the diesel engine. Palm–sesame oil blend was used to produce biodiesel using the ultrasound-assisted technique. B30 fuel sample as a base fuel was blended with fuel additives in different proportions prior to tribological behavior analysis. The lubricity of fuel samples measured using HFRR in accordance with the standard method ASTM D6079. All tested fuels’ Tribological behavior examined through worn steel balls and plates using scanning electron microscopy (SEM) to assess wear scar diameter and surface morphology. During the test run, the friction coefficient was measured directly by the HFRR tribometer system. The results exhibited that B10 (diesel) had a very poor coefficient of friction and wear scar diameter, among other tested fuels. The addition of oxygenated alcohol (ethanol) as a fuel additive in the B30 fuel sample decreased the lubricity of fuel and increased the wear and friction coefficient, among other fuel additives. B30 with DMC showed the least wear scar diameter among all tested fuels. B30 with nanoparticle TiO2 exhibited the best results with the least wear scar diameter and lowest friction coefficient among all other fuel samples. B30+DMC demonstrated significant improvement in engine performance (BTE) and carbon emissions compared to different tested samples. B30+TiO2 also showed considerable improvement in engine characteristics

Effect of primary and secondary alcohols as oxygenated additives on the performance and emission characteristics of diesel engine

The demand for renewable energy sources is gradually escalating due to the spontaneously growing population and global economic development. The access to fossil fuels is gradually declining due to the limited available reserves. Hence, renewable energy resources, technology choice, and energy policy are always being revised due to the modernization of society. Meanwhile, the liquid energy sources such as methyl ester from locally produced vegetable oils are readily accepted by many countries globally, although it is currently being blended (up to 20%) with diesel. Oxides of nitrogen are the most substantial emissions from diesel engines produced due to high combustion temperature. The addition of alcohol in the fuel reduces the NOx formation since alcohols have high latent heat of evaporation. The present study's primary purpose is to investigate the effect of different alcohol types on engine performance and emission characteristics. For this purpose, seven test fuels and neat diesel were used. The test fuels P20 (20% palm biodiesel with 70% neat diesel and 10% alcohol on a volume basis), D70P20E10, D70P20Pr10, D70P20B10, D70P20Pe10, D70P20H10 were prepared and tested on a single-cylinder, 4-stroke, DI-diesel engine at different speeds at 100 % load. The P20E10 ternary fuel blend illustrated the most practical combination of all the bioethanol-based blends, which considerably improves the BTE, BSFC and reduces NOxformation at high speed compared to other types of alcoholic fuel blends. Also, the P20E10 fuel blend improved the cloud point of neat diesel

Effect of palm-sesame biodiesel fuels with alcoholic and nanoparticle additives on tribological characteristics of lubricating oil by four ball tribo-tester

Dilution of engine oil with unburned fuels alters its lubricity and tribological properties. In this research paper, SAE-40 lubricating oil samples were contaminated with known percentages (5%) of fuels (diesel, palm-sesame biodiesel blend (B30), B30 + ethanol, B30 + dimethyl carbonate, B30 + carbon nanotubes and, B30 + titanium oxide). The effect of all these fuels on wear and frictional characteristics of lubricating oil was determined by using a 4-ball tribo tester and wear types on worn surfaces were analyzed by using SEM. Lubricating oil diluted with B10 (commercial diesel) showed highest COF (42.95%) with severe abrasive and adhesive wear than mineral lubricant among other fuels. Lubricating oil diluted with palm-sesame biodiesel (B30 blend) with alcoholic additives showed comparatively less COF, less wear scar diameter and polishing wear due to presence of ester molecules. Lub + B30 + Eth exhibited increment in COF value (35.81%) compared to SAE-40 mineral lubricant. While lubricating oil contaminated with B30 with nanoparticles showed least frictional characteristics with abrasive wear. Lub + B30 + TiO2 showed least increment in COF value (13.78%) among all other contaminated fuels compared to SAE-40 mineral lubricant. It is concluded that nanoparticles in biodiesel blends (B30) helps in reducing degradation of lubricants than alcoholic fuel additives and commercial diesel

Particulate Matter Emission Characteristics of a Biodiesel Fueled Engine at Idling Speed

Automotive and transportation sectors will be inclined towards the renewable or green energy in the near future. One of the green energy sources discovered recently is biodiesel. Biodiesel is a source of clean alternative fuel for internal combustion engines, which reduces the exhaust emissions significantly. Like diesel, biodiesel also emits exhaust particulate matter (PM), which is responsible for the black soot coming out from the diesel engine. However, it is not clear that what will be the size of PM formed during the idle speed of a biodiesel fueled engine. In this study, the characteristics of the exhaust particulate during the idling speed of a biodiesel fueled single cylinder diesel engine is analyzed. Biodiesel showed a positive result in terms of the concentration of emitted PM. However, particle sizes were smaller in case of biodiesel than diesel. Further studies should be carried out to improve the properties of biodiesel to ensure that the emitted particle sizes are not toxic to human health