High pressure torsion of nickel powders obtained by electrodeposition

A new synthesis route for the production of bulk nanostructured materials is presented. Fine Ni powder was made by selected appropriate electrolysis conditions. A compact material with an average grain size below 40 nm was obtained by subsequent cold pressing. Then, using the high pressure torsion (HPT) deformation technique dense bulk nanocrystalline Ni was achieved. The detailed structural investigations of the asprepared and HPT deformed Ni powder, including X-ray diffraction (XRD) and transmission electron microscopy (TEM), reveal in both cases the presence of a face centered cubic (FCC) phase without presence of any oxides. Coherently scattering domain size measurements by XRD show a value of 24 nm for the as-deposited powder and an even smaller value of 13.5 nm after HPT deformation. In addition, optical emission spectroscopy was employed to determine the impurity content of the obtained nanostructured material, showing a relatively low content of 0.9 % carbon and oxygen. The microhardness increased after deformation from (1.5 ± 0.08) GPa for the as-deposited Ni powder to (6.6 ± 0.2) GPa for the HPT deformed Ni powder. When you are citing the document, use the following link http://essuir.sumdu.edu.ua/handle/123456789/2061

Nanocrystalline Zr3Al Made through Amorphization by Repeated Cold Rolling and Followed by Crystallization

The intermetallic compound Zr3Al is severely deformed by the method of repeated cold rolling. By X-ray diffraction it is shown that this leads to amorphization. TEM investigations reveal that a homogeneously distributed debris of very small nanocrystals is present in the amorphous matrix that is not resolved by X-ray diffraction. After heating to 773 K, the crystallization of the amorphous structure leads to a fully nanocrystalline structure of small grains (10 - 20 nm in diameter) of the non-equilibrium Zr2Al phase. It is concluded that the debris retained in the amorphous phase acts as nuclei. After heating to 973 K the grains grow to about 100 nm in diameter and the compound Zr3Al starts to form, that is corresponding to the alloy composition

Tem-studies of the dislocation structure in a γ/γ' Ni-based superalloy

No abstract availabl

Tem-studies of the dislocation structure in a γ/γ' Ni-based superalloy

No abstract availabl

Transformation dislocations and transformation induced crystal defects in CoFe alloys

In CoFe alloys the transformation dislocations and the transformation induced defects were analysed by both conventional transmission electron rnicroscopy and high-resolution transmission electron microscopy methods. The thermally induced transformation fcc → dhcp occurs by the glide of transformation dislocations that all have the same Shockley partial Burgers vector and therefore cause large shear strains. Plastic deformation near the front of the glissile interface activates glide dislocations in the fcc parent phase. Their subsequent reactions with the transformation dislocations lead to a high density of grown-in dislocations and stacking faults in the dhcp lattice

Atomic Scale Self Accommodation Observed at hcp/dhcp Martensitic Transformation Interfaces

The martensitic hcp→dhcp transformation was studied in single crystals of Co-0.85at.%Fe by transmission electron microscopy (TEM) methods. During in-situ heating dhcp lamellae emerge into the hcp areas of the TEM specimens. The minimum thickness of the lamellae is about 15 close packed planes. Frequently lamellae are observed that grow in thickness by the movement of superledges that are up to about 100 close packed planes in height. The partials at the fronts of the transformation were analysed on an atomic level in TEM images with atomic resolution. The analysis shows that the transformation fronts consists of a sequence of very narrow dipoles compensating their long range strain fields. Since dipoles of a common Burgers vector are observed it is proposed that their short range interactions might promote their correlated nucleation