52 research outputs found
Non-bar, anopticalcalibrationsystemforfive-axisCNCmachinetools
Five-axisCNCmachinetoolscomprisethreelinearaxesandtworotaryaxes,enablingthefabricationof
complexworkpieces,suchasdies,turboblades,andcams.Improvedmeasurementmethodsare
continuallybeingresearchedtoincreasetheaccuracyoffive-axisCNCmachinetools.Thispaper
presentsanovelopticalcalibrationsystem,called non-bar, withnolinkagebars.Thesystemcomprises
a masterdetectormodule,aballlensmodule,andasignalmodule.Theproposedmeasurementsystem
was implementedaccordingtoISO/CD10791-6tomeasureA-type,B-type,andC-typefive-axisCNC
machinetoolsfromthreedifferentmanufacturers.Theresultsdemonstratethattheproposed non-bar
measurementschemeprovideshighaccuracy,highreproducibility,andsimultaneousmulti-axis
measurement
Structure-Activity Relationship Analysis of the Thermal Stabilities of Nitroaromatic Compounds Following Different Decomposition Mechanisms
The decomposition behavior of energetic materi-
als is very important for the safety problems concerning
their production, transportation, use and storage, because
molecular decomposition is intimately connected to their
explosive properties. Nitroaromatic compounds, particularly
nitrobenzene derivatives, are often considered as prototypi-
cal energetic molecules, and some of them are commonly
used as high explosives. Quantitative structure-activity rela-
tionship (QSAR) represents a potential tool for predicting
the thermal stability properties of energetic materials. But it
is reported that constructing general reliable models to
predict their stability and their potential explosive proper-
ties is a very difficult task. In this work, we make our efforts
to investigate the relationship between the molecular
structures and corresponding thermal stabilities of 77 nitro-
benzene derivatives with various substituent functional
groups (in
ortho
,
meta
and/or
para
positions). The pro-
posed best MLR model, developed by the new software
QSARINS, based on Genetic Algorithm for variable selection
and with various validation tools, is robust, stable and pre-
dictive with
R
2
of 0.86,
Q
LOO
2
of 0.79 and
CCC
of 0.90. The
results indicated that, though difficult, it is possible to build
predictive, externally validated QSAR models to estimate
the thermal stability of nitroaromatic compound
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