477 research outputs found
Criticality of the Mean-Field Spin-Boson Model: Boson State Truncation and Its Scaling Analysis
The spin-boson model has nontrivial quantum phase transitions at zero
temperature induced by the spin-boson coupling. The bosonic numerical
renormalization group (BNRG) study of the critical exponents and
of this model is hampered by the effects of boson Hilbert space
truncation. Here we analyze the mean-field spin boson model to figure out the
scaling behavior of magnetization under the cutoff of boson states . We
find that the truncation is a strong relevant operator with respect to the
Gaussian fixed point in and incurs the deviation of the exponents
from the classical values. The magnetization at zero bias near the critical
point is described by a generalized homogeneous function (GHF) of two variables
and . The universal function has a
double-power form and the powers are obtained analytically as well as
numerically. Similarly, is found to be a GHF of
and . In the regime , the truncation produces no effect.
Implications of these findings to the BNRG study are discussed.Comment: 9 pages, 7 figure
Oscillations of a solid sphere falling through a wormlike micellar fluid
We present an experimental study of the motion of a solid sphere falling
through a wormlike micellar fluid. While smaller or lighter spheres quickly
reach a terminal velocity, larger or heavier spheres are found to oscillate in
the direction of their falling motion. The onset of this instability correlates
with a critical value of the velocity gradient scale
s. We relate this condition to the known complex rheology of wormlike
micellar fluids, and suggest that the unsteady motion of the sphere is caused
by the formation and breaking of flow-induced structures.Comment: 4 pages, 4 figure
Regio- and stereoselective organocatalyzed relay glycosylations to synthesize 2-amino-2-deoxy-1,3-dithioglycosides
Herein, we describe a novel methodology for the regio-and stereoselectiveconvergent synthesis of 2-amino-2-deoxy-dithioglycosides via one-potrelay glycosylation of 3-O-acetyl-2-nitroglucal donors.This unique organo-catalysis relay glycosylation features excellentsite- and stereoselectivity, good to excellent yields, mild reactionconditions, and broad substrate scope. 2-Amino-2-deoxy-glucosides/mannosidesbearing 1,3-dithio-linkages were efficiently obtained from 3-O-acetyl-2-nitroglucal donors in both stepwise and one-potglycosylation protocols. The dithiolated O-antigen of E. coli serogroup 64 was successfully synthesizedusing this newly developed method.Bio-organic Synthesi
Measuring neutrino masses with a future galaxy survey
We perform a detailed forecast on how well a Euclid-like photometric galaxy
and cosmic shear survey will be able to constrain the absolute neutrino mass
scale. Adopting conservative assumptions about the survey specifications and
assuming complete ignorance of the galaxy bias, we estimate that the minimum
mass sum of sum m_nu ~ 0.06 eV in the normal hierarchy can be detected at 1.5
sigma to 2.5 sigma significance, depending on the model complexity, using a
combination of galaxy and cosmic shear power spectrum measurements in
conjunction with CMB temperature and polarisation observations from Planck.
With better knowledge of the galaxy bias, the significance of the detection
could potentially reach 5.4 sigma. Interestingly, neither Planck+shear nor
Planck+galaxy alone can achieve this level of sensitivity; it is the combined
effect of galaxy and cosmic shear power spectrum measurements that breaks the
persistent degeneracies between the neutrino mass, the physical matter density,
and the Hubble parameter. Notwithstanding this remarkable sensitivity to sum
m_nu, Euclid-like shear and galaxy data will not be sensitive to the exact mass
spectrum of the neutrino sector; no significant bias (< 1 sigma) in the
parameter estimation is induced by fitting inaccurate models of the neutrino
mass splittings to the mock data, nor does the goodness-of-fit of these models
suffer any significant degradation relative to the true one (Delta chi_eff ^2<
1).Comment: v1: 29 pages, 10 figures. v2: 33 pages, 12 figures; added sections on
shape evolution and constraints in more complex models, accepted for
publication in JCA
Vibrational Properties of Nanoscale Materials: From Nanoparticles to Nanocrystalline Materials
The vibrational density of states (VDOS) of nanoclusters and nanocrystalline
materials are derived from molecular-dynamics simulations using empirical
tight-binding potentials. The results show that the VDOS inside nanoclusters
can be understood as that of the corresponding bulk system compressed by the
capillary pressure. At the surface of the nanoparticles the VDOS exhibits a
strong enhancement at low energies and shows structures similar to that found
near flat crystalline surfaces. For the nanocrystalline materials an increased
VDOS is found at high and low phonon energies, in agreement with experimental
findings. The individual VDOS contributions from the grain centers, grain
boundaries, and internal surfaces show that, in the nanocrystalline materials,
the VDOS enhancements are mainly caused by the grain-boundary contributions and
that surface atoms play only a minor role. Although capillary pressures are
also present inside the grains of nanocrystalline materials, their effect on
the VDOS is different than in the cluster case which is probably due to the
inter-grain coupling of the modes via the grain-boundaries.Comment: 10 pages, 7 figures, accepted for publication in Phys. Rev.
PL-03 Harnessing multidrug resistance gene expression for effective antifungal strategies by a natural product berberine
Effects of columnar disorder on flux-lattice melting in high-temperature superconductors
The effect of columnar pins on the flux-lines melting transition in
high-temperature superconductors is studied using Path Integral Monte Carlo
simulations. We highlight the similarities and differences in the effects of
columnar disorder on the melting transition in YBaCuO
(YBCO) and the highly anisotropic BiSrCaCuO (BSCCO) at
magnetic fields such that the mean separation between flux-lines is smaller
than the penetration length. For pure systems, a first order transition from a
flux-line solid to a liquid phase is seen as the temperature is increased. When
adding columnar defects to the system, the transition temperature is not
affected in both materials as long as the strength of an individual columnar
defect (expressed as a flux-line defect interaction) is less than a certain
threshold for a given density of randomly distributed columnar pins. This
threshold strength is lower for YBCO than for BSCCO. For higher strengths the
transition line is shifted for both materials towards higher temperatures, and
the sharp jump in energy, characteristic of a first order transition, gives way
to a smoother and gradual rise of the energy, characteristic of a second order
transition. Also, when columnar defects are present, the vortex solid phase is
replaced by a pinned Bose glass phase and this is manifested by a marked
decrease in translational order and orientational order as measured by the
appropriate structure factors. For BSCCO, we report an unusual rise of the
translational order and the hexatic order just before the melting transition.
No such rise is observed in YBCO.Comment: 32 pages, 13 figures, revte
Dynamics in online social networks
An increasing number of today's social interactions occurs using online
social media as communication channels. Some online social networks have become
extremely popular in the last decade. They differ among themselves in the
character of the service they provide to online users. For instance, Facebook
can be seen mainly as a platform for keeping in touch with close friends and
relatives, Twitter is used to propagate and receive news, LinkedIn facilitates
the maintenance of professional contacts, Flickr gathers amateurs and
professionals of photography, etc. Albeit different, all these online platforms
share an ingredient that pervades all their applications. There exists an
underlying social network that allows their users to keep in touch with each
other and helps to engage them in common activities or interactions leading to
a better fulfillment of the service's purposes. This is the reason why these
platforms share a good number of functionalities, e.g., personal communication
channels, broadcasted status updates, easy one-step information sharing, news
feeds exposing broadcasted content, etc. As a result, online social networks
are an interesting field to study an online social behavior that seems to be
generic among the different online services. Since at the bottom of these
services lays a network of declared relations and the basic interactions in
these platforms tend to be pairwise, a natural methodology for studying these
systems is provided by network science. In this chapter we describe some of the
results of research studies on the structure, dynamics and social activity in
online social networks. We present them in the interdisciplinary context of
network science, sociological studies and computer science.Comment: 17 pages, 4 figures, book chapte
Hydrogen bond activated glycosylation under mild conditions
Herein, we report a new glycosylation system for the highly efficient and stereoselective formation of glycosidic bonds using glycosyl N-phenyl trifluoroacetimidate (PTFAI) donors and a charged thiourea hydrogen-bond-donor catalyst. The glycosylation protocol features broad substrate scope, controllable stereoselectivity, good to excellent yields and exceptionally mild catalysis conditions. Benefitting from the mild reaction conditions, this new hydrogen bond-mediated glycosylation system in combination with a hydrogen bond-mediated aglycon delivery system provides a reliable method for the synthesis of challenging phenolic glycosides. In addition, a chemoselective glycosylation procedure was developed using different imidate donors (trichloroacetimidates, N-phenyl trifluoroacetimidates, N-4-nitrophenyl trifluoroacetimidates, benzoxazolyl imidates and 6-nitro-benzothiazolyl imidates) and it was applied for a trisaccharide synthesis through a novel one-pot single catalyst strategy.Bio-organic Synthesi
Partial Wave Analysis of
BES data on are presented. The
contribution peaks strongly near threshold. It is fitted with a
broad resonance with mass MeV, width MeV. A broad resonance peaking at 2020 MeV is also required
with width MeV. There is further evidence for a component
peaking at 2.55 GeV. The non- contribution is close to phase
space; it peaks at 2.6 GeV and is very different from .Comment: 15 pages, 6 figures, 1 table, Submitted to PL
- …