477 research outputs found

    Criticality of the Mean-Field Spin-Boson Model: Boson State Truncation and Its Scaling Analysis

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    The spin-boson model has nontrivial quantum phase transitions at zero temperature induced by the spin-boson coupling. The bosonic numerical renormalization group (BNRG) study of the critical exponents β\beta and δ\delta of this model is hampered by the effects of boson Hilbert space truncation. Here we analyze the mean-field spin boson model to figure out the scaling behavior of magnetization under the cutoff of boson states NbN_{b}. We find that the truncation is a strong relevant operator with respect to the Gaussian fixed point in 0<s<1/20<s<1/2 and incurs the deviation of the exponents from the classical values. The magnetization at zero bias near the critical point is described by a generalized homogeneous function (GHF) of two variables τ=α−αc\tau=\alpha-\alpha_{c} and x=1/Nbx=1/N_{b}. The universal function has a double-power form and the powers are obtained analytically as well as numerically. Similarly, m(α=αc)m(\alpha=\alpha_{c}) is found to be a GHF of ϵ\epsilon and xx. In the regime s>1/2s>1/2, the truncation produces no effect. Implications of these findings to the BNRG study are discussed.Comment: 9 pages, 7 figure

    Oscillations of a solid sphere falling through a wormlike micellar fluid

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    We present an experimental study of the motion of a solid sphere falling through a wormlike micellar fluid. While smaller or lighter spheres quickly reach a terminal velocity, larger or heavier spheres are found to oscillate in the direction of their falling motion. The onset of this instability correlates with a critical value of the velocity gradient scale Γc∼1\Gamma_{c}\sim 1 s−1^{-1}. We relate this condition to the known complex rheology of wormlike micellar fluids, and suggest that the unsteady motion of the sphere is caused by the formation and breaking of flow-induced structures.Comment: 4 pages, 4 figure

    Regio- and stereoselective organocatalyzed relay glycosylations to synthesize 2-amino-2-deoxy-1,3-dithioglycosides

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    Herein, we describe a novel methodology for the regio-and stereoselectiveconvergent synthesis of 2-amino-2-deoxy-dithioglycosides via one-potrelay glycosylation of 3-O-acetyl-2-nitroglucal donors.This unique organo-catalysis relay glycosylation features excellentsite- and stereoselectivity, good to excellent yields, mild reactionconditions, and broad substrate scope. 2-Amino-2-deoxy-glucosides/mannosidesbearing 1,3-dithio-linkages were efficiently obtained from 3-O-acetyl-2-nitroglucal donors in both stepwise and one-potglycosylation protocols. The dithiolated O-antigen of E. coli serogroup 64 was successfully synthesizedusing this newly developed method.Bio-organic Synthesi

    Measuring neutrino masses with a future galaxy survey

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    We perform a detailed forecast on how well a Euclid-like photometric galaxy and cosmic shear survey will be able to constrain the absolute neutrino mass scale. Adopting conservative assumptions about the survey specifications and assuming complete ignorance of the galaxy bias, we estimate that the minimum mass sum of sum m_nu ~ 0.06 eV in the normal hierarchy can be detected at 1.5 sigma to 2.5 sigma significance, depending on the model complexity, using a combination of galaxy and cosmic shear power spectrum measurements in conjunction with CMB temperature and polarisation observations from Planck. With better knowledge of the galaxy bias, the significance of the detection could potentially reach 5.4 sigma. Interestingly, neither Planck+shear nor Planck+galaxy alone can achieve this level of sensitivity; it is the combined effect of galaxy and cosmic shear power spectrum measurements that breaks the persistent degeneracies between the neutrino mass, the physical matter density, and the Hubble parameter. Notwithstanding this remarkable sensitivity to sum m_nu, Euclid-like shear and galaxy data will not be sensitive to the exact mass spectrum of the neutrino sector; no significant bias (< 1 sigma) in the parameter estimation is induced by fitting inaccurate models of the neutrino mass splittings to the mock data, nor does the goodness-of-fit of these models suffer any significant degradation relative to the true one (Delta chi_eff ^2< 1).Comment: v1: 29 pages, 10 figures. v2: 33 pages, 12 figures; added sections on shape evolution and constraints in more complex models, accepted for publication in JCA

    Vibrational Properties of Nanoscale Materials: From Nanoparticles to Nanocrystalline Materials

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    The vibrational density of states (VDOS) of nanoclusters and nanocrystalline materials are derived from molecular-dynamics simulations using empirical tight-binding potentials. The results show that the VDOS inside nanoclusters can be understood as that of the corresponding bulk system compressed by the capillary pressure. At the surface of the nanoparticles the VDOS exhibits a strong enhancement at low energies and shows structures similar to that found near flat crystalline surfaces. For the nanocrystalline materials an increased VDOS is found at high and low phonon energies, in agreement with experimental findings. The individual VDOS contributions from the grain centers, grain boundaries, and internal surfaces show that, in the nanocrystalline materials, the VDOS enhancements are mainly caused by the grain-boundary contributions and that surface atoms play only a minor role. Although capillary pressures are also present inside the grains of nanocrystalline materials, their effect on the VDOS is different than in the cluster case which is probably due to the inter-grain coupling of the modes via the grain-boundaries.Comment: 10 pages, 7 figures, accepted for publication in Phys. Rev.

    Effects of columnar disorder on flux-lattice melting in high-temperature superconductors

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    The effect of columnar pins on the flux-lines melting transition in high-temperature superconductors is studied using Path Integral Monte Carlo simulations. We highlight the similarities and differences in the effects of columnar disorder on the melting transition in YBa2_2Cu3_3O7−δ_{7-\delta} (YBCO) and the highly anisotropic Bi2_2Sr2_2CaCu2_2O8+δ_{8+\delta} (BSCCO) at magnetic fields such that the mean separation between flux-lines is smaller than the penetration length. For pure systems, a first order transition from a flux-line solid to a liquid phase is seen as the temperature is increased. When adding columnar defects to the system, the transition temperature is not affected in both materials as long as the strength of an individual columnar defect (expressed as a flux-line defect interaction) is less than a certain threshold for a given density of randomly distributed columnar pins. This threshold strength is lower for YBCO than for BSCCO. For higher strengths the transition line is shifted for both materials towards higher temperatures, and the sharp jump in energy, characteristic of a first order transition, gives way to a smoother and gradual rise of the energy, characteristic of a second order transition. Also, when columnar defects are present, the vortex solid phase is replaced by a pinned Bose glass phase and this is manifested by a marked decrease in translational order and orientational order as measured by the appropriate structure factors. For BSCCO, we report an unusual rise of the translational order and the hexatic order just before the melting transition. No such rise is observed in YBCO.Comment: 32 pages, 13 figures, revte

    Dynamics in online social networks

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    An increasing number of today's social interactions occurs using online social media as communication channels. Some online social networks have become extremely popular in the last decade. They differ among themselves in the character of the service they provide to online users. For instance, Facebook can be seen mainly as a platform for keeping in touch with close friends and relatives, Twitter is used to propagate and receive news, LinkedIn facilitates the maintenance of professional contacts, Flickr gathers amateurs and professionals of photography, etc. Albeit different, all these online platforms share an ingredient that pervades all their applications. There exists an underlying social network that allows their users to keep in touch with each other and helps to engage them in common activities or interactions leading to a better fulfillment of the service's purposes. This is the reason why these platforms share a good number of functionalities, e.g., personal communication channels, broadcasted status updates, easy one-step information sharing, news feeds exposing broadcasted content, etc. As a result, online social networks are an interesting field to study an online social behavior that seems to be generic among the different online services. Since at the bottom of these services lays a network of declared relations and the basic interactions in these platforms tend to be pairwise, a natural methodology for studying these systems is provided by network science. In this chapter we describe some of the results of research studies on the structure, dynamics and social activity in online social networks. We present them in the interdisciplinary context of network science, sociological studies and computer science.Comment: 17 pages, 4 figures, book chapte

    Hydrogen bond activated glycosylation under mild conditions

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    Herein, we report a new glycosylation system for the highly efficient and stereoselective formation of glycosidic bonds using glycosyl N-phenyl trifluoroacetimidate (PTFAI) donors and a charged thiourea hydrogen-bond-donor catalyst. The glycosylation protocol features broad substrate scope, controllable stereoselectivity, good to excellent yields and exceptionally mild catalysis conditions. Benefitting from the mild reaction conditions, this new hydrogen bond-mediated glycosylation system in combination with a hydrogen bond-mediated aglycon delivery system provides a reliable method for the synthesis of challenging phenolic glycosides. In addition, a chemoselective glycosylation procedure was developed using different imidate donors (trichloroacetimidates, N-phenyl trifluoroacetimidates, N-4-nitrophenyl trifluoroacetimidates, benzoxazolyl imidates and 6-nitro-benzothiazolyl imidates) and it was applied for a trisaccharide synthesis through a novel one-pot single catalyst strategy.Bio-organic Synthesi

    Partial Wave Analysis of J/ψ→γ(K+K−π+π−)J/\psi \to \gamma (K^+K^-\pi^+\pi^-)

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    BES data on J/ψ→γ(K+K−π+π−)J/\psi \to \gamma (K^+K^-\pi^+\pi^-) are presented. The K∗Kˉ∗K^*\bar K^* contribution peaks strongly near threshold. It is fitted with a broad 0−+0^{-+} resonance with mass M=1800±100M = 1800 \pm 100 MeV, width Γ=500±200\Gamma = 500 \pm 200 MeV. A broad 2++2^{++} resonance peaking at 2020 MeV is also required with width ∼500\sim 500 MeV. There is further evidence for a 2−+2^{-+} component peaking at 2.55 GeV. The non-K∗Kˉ∗K^*\bar K^* contribution is close to phase space; it peaks at 2.6 GeV and is very different from K∗K∗ˉK^{*}\bar{K^{*}}.Comment: 15 pages, 6 figures, 1 table, Submitted to PL
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