29,390 research outputs found
Synthesis and Structures of Fused N-Heterocylic Carbenes and Their Rhodium Complexes
New procedures for the synthesis of N-heterocyclic carbenes with multiple fused rings have been developed utilizing a key ring-closing metathesis step. Rhodium complexes were obtained via the pentafluorophenyl carbene adducts. Solid-state structural behaviors of the new carbene ligands were analyzed via X-ray crystallography
THE IMPACTS ON THE U.S. GRAPEFRUIT INDUSTRY FROM BANNING THE PESTICIDE SODIUM ORTHO-PHENYLPHENATE
Sodium Ãœrtho-phenylphenate (SOPP) is a postharvest pesticide commonly used on citrus. SOPP poses some food safety risks and is currently in the Environmental Protection Agency's Stage IV of the pesticide re-registration process. Costs to the fresh grapefruit industry are estimated for increases in the postharvest loss rates of fresh grapefruit following an SOPP ban. The ban's effects on domestic and export sales of fresh and processed grapefruit are estimated.Agricultural and Food Policy,
The Rotation Measure and 3.5mm Polarization of Sgr A*
We report the detection of variable linear polarization from Sgr A* at a
wavelength of 3.5mm, the longest wavelength yet at which a detection has been
made. The mean polarization is 2.1 +/- 0.1% at a position angle of 16 +/- 2 deg
with rms scatters of 0.4% and 9 deg over the five epochs. We also detect
polarization variability on a timescale of days. Combined with previous
detections over the range 150-400GHz (750-2000 microns), the average
polarization position angles are all found to be consistent with a rotation
measure of -4.4 +/- 0.3 x 10^5 rad/m^2. This implies that the Faraday rotation
occurs external to the polarized source at all wavelengths. This implies an
accretion rate ~0.2 - 4 x 10^-8 Msun/yr for the accretion density profiles
expected of ADAF, jet and CDAF models and assuming that the region at which
electrons in the accretion flow become relativistic is within 10 R_S. The
inferred accretion rate is inconsistent with ADAF/Bondi accretion. The
stability of the mean polarization position angle between disparate
polarization observations over the frequency range limits fluctuations in the
accretion rate to less than 5%. The flat frequency dependence of the inter-day
polarization position angle variations also makes them difficult to attribute
to rotation measure fluctuations, and suggests that both the magnitude and
position angle variations are intrinsic to the emission.Comment: Ap.J.Lett. accepte
Imports From China and Food Safety Issues
The U.S. Food and Drug Administration’s (FDA) increased attention to food imports from China is an indicator of safety concerns as imported food becomes more common in the United States. U.S. food imports from China more than tripled in value between 2001 and 2008. Addressing safety risks associated with these imports is difficult because of the vast array of products from China, China’s weak enforcement of food safety standards, its heavy use of agricultural chemicals, and its considerable environmental pollution. FDA import refusal data highlight food safety problems that appear to recur in trade and where FDA has focused its import alerts and monitoring efforts. FDA refusals of food shipments from China suggest recurring problems with “filth,” unsafe additives, labeling (typically introduced in food processing and handling), and veterinary drug residues in fish and shellfish (introduced at the farm). Chinese authorities try to control food export safety by certifying exporters and the farms that supply them. However, monitoring such a wide range of products for the different hazards that can arise at varying points in the supply chain is a difficult challenge for Chinese and U.S. officials.China, food imports, food safety, U.S. Food and Drug Administration, FDA, misbranding, labeling, refusals, shipment, violation., Agricultural and Food Policy, Food Consumption/Nutrition/Food Safety, International Relations/Trade,
Approach to equilibrium for the phonon Boltzmann equation
We study the asymptotics of solutions of the Boltzmann equation describing
the kinetic limit of a lattice of classical interacting anharmonic oscillators.
We prove that, if the initial condition is a small perturbation of an
equilibrium state, and vanishes at infinity, the dynamics tends diffusively to
equilibrium. The solution is the sum of a local equilibrium state, associated
to conserved quantities that diffuse to zero, and fast variables that are
slaved to the slow ones. This slaving implies the Fourier law, which relates
the induced currents to the gradients of the conserved quantities.Comment: 23 page
X-ray Bursts from the Accreting Millisecond Pulsar XTE J1814-338
Since the discovery of the accreting millisecond pulsar XTE J1814-338 a total
of 27 thermonuclear bursts have been observed from the source with the
Proportional Counter Array (PCA) onboard the Rossi X-ray Timing Explorer
(RXTE). Spectroscopy of the bursts, as well as the presence of continuous burst
oscillations, suggests that all but one of the bursts are sub-Eddington. The
remaining burst has the largest peak bolometric flux of 2.64 x E^-8
erg/sec/cm^2, as well as a gap in the burst oscillations, similar to that seen
in Eddington limited bursts from other sources. Assuming this burst was
Eddington limited we obtain a source distance of about 8 kpc. All the bursts
show coherent oscillations at the 314.4 Hz spin frequency. The burst
oscillations are strongly frequency and phase locked to the persistent
pulsations. Only two bursts show evidence for frequency drift in the first few
seconds following burst onset. In both cases the initial drift corresponds to a
spin down of a few tenths of a Hz. The large oscillation amplitude during the
bursts confirms that the burst flux is modulated at the spin frequency. We
detect, for the first time, a significant first harmonic component in burst
oscillations. The ratio of countrate in the first harmonic to that in the
fundamental can be > 0.25 and is, on average, less than that of the persistent
pulsations. If the pulsations result from a single bright region on the
surface, the harmonic strength suggests the burst emission is beamed, perhaps
due to a stronger magnetic field than in non-pulsing LMXBs. Alternatively, the
harmonic content could result from a geometry with two bright regions.Comment: AASTeX, 15 pages, 4 figures. Accepted for publication in the
Astrophysical Journal Letter
Description of a quantum convolutional code
We describe a quantum error correction scheme aimed at protecting a flow of
quantum information over long distance communication. It is largely inspired by
the theory of classical convolutional codes which are used in similar
circumstances in classical communication. The particular example shown here
uses the stabilizer formalism, which provides an explicit encoding circuit. An
associated error estimation algorithm is given explicitly and shown to provide
the most likely error over any memoryless quantum channel, while its complexity
grows only linearly with the number of encoded qubits.Comment: 4 pages, uses revtex4. Minor correction in the encoding and decoding
circuit
Interaction-induced impeding of decoherence and anomalous diffusion
We study how the interplay of dissipation and interactions affects the
dynamics of a bosonic many-body quantum system. In the presence of both
dissipation and strongly repulsive interactions, observables such as the
coherence and the compressibility display three dynamical regimes: an initial
exponential variation followed by a power-law regime and finally a slow
exponential convergence to their asymptotic values corresponding to the
infinite temperature state. These very long-time scales arise as dissipation
forces the population of states disfavored by interactions. The long-time,
strong coupling dynamics are understood by performing a mapping onto a
classical diffusion process displaying non-Brownian behavior. While both
dissipation and strong interactions tend to suppress coherence when acting
separately, we find that strong interaction impedes the decoherence process
generated by the dissipation.Comment: 5 pages, 3 figure
Effects of NHC-Backbone Substitution on Efficiency in Ruthenium-Based Olefin Metathesis
series of ruthenium olefin metathesis catalysts bearing N-heterocyclic carbene (NHC) ligands with varying degrees of backbone and N-aryl substitution have been prepared. These complexes show greater resistance to decomposition through C−H activation of the N-aryl group, resulting in increased catalyst lifetimes. This work has utilized robotic technology to examine the activity and stability of each catalyst in metathesis, providing insights into the relationship between ligand architecture and enhanced efficiency. The development of this robotic methodology has also shown that, under optimized conditions, catalyst loadings as low as 25 ppm can lead to 100% conversion in the ring-closing metathesis of diethyl diallylmalonate
- …