Partitioning of a polymer chain between a confining cavity and a gel

A lattice field theory approach to the statistical mechanics of charged polymers in electrolyte solutions [S. Tsonchev, R. D. Coalson, and A. Duncan, Phys. Rev. E 60, 4257, (1999)] is applied to the study of a polymer chain contained in a spherical cavity but able to diffuse into a surrounding gel. The distribution of the polymer chain between the cavity and the gel is described by its partition coefficient, which is computed as a function of the number of monomers in the chain, the monomer charge, and the ion concentrations in the solution.Comment: 17 pages, 6 figure

Private health insurance in social health insurance countries: Market outcomes and policy implications

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Chiral properties of two-flavor QCD in small volume and at large lattice spacing

We present results from simulations of two flavors of dynamical overlap fermions on 8^4 lattices at three values of the sea quark mass and a lattice spacing of about 0.16 fm. We measure the topological susceptibility and the chiral condensate. A comparison of the low-lying spectrum of the overlap operator with predictions from random matrix theory is made. To demonstrate the effect of the dynamical fermions, we compare meson two-point functions with quenched results. Algorithmic improvements over a previous publication and the performance of the algorithm are discussed.Comment: 16 pages, 12 figure

Accuracy and uncertainty of single-shot, nonresonant laser-induced thermal acoustics

We study the accuracy and uncertainty of single-shot nonresonant laser-induced thermal acoustics measurements of the speed of sound and the thermal diffusivity in unseeded atmospheric air from electrostrictive gratings as a function of the laser power settings. For low pump energies, the measured speed of sound is too low, which is due to the influence of noise on the numerical data analysis scheme. For pump energies comparable to and higher than the breakdown energy of the gas, the measured speed of sound is too high. This is an effect of leaving the acoustic limit, and instead creating finite-amplitude density perturbations. The measured thermal diffusivity is too large for high noise levels but it decreases below the predicted value for high pump energies. The pump energy where the error is minimal coincides for the speed of sound and for the thermal diffusivity measurements. The errors at this minimum are 0.03% and 1%, respectively. The uncertainties for the speed of sound and the thermal diffusivity decrease monotonically with signal intensity to 0.25% and 5%, respectively

Spinal stabilization for patients with metastatic lesions of the spine using a titanium spacer

Anterior decompression in spinal metastases of the corporal type with impending (n=5) or present (n=36) neurological complications was performed in 41 patients. For reconstruction, a titanium cylinder was inserted after spondylectomy and augmented with an anterior plate. The titanium implant can easily be adjusted to the length needed without necessitating expensive additional equipment. Outside the patient the implant is filled with polymethylmetacrylate, facilitating plate transfixation for rotational locking. There was a 30-day mortality of 9.7%. Pain relief was apparent in 38 of 41 patients (92.7%), and motor improvement was manifest in 31 of 35 cases (88.6%). Six patients did not present with any neurological symptoms pre- or postoperatively. Neurological deterioration was registered in only 1 case (2.4%). Surgical efficacy was maintained until the death of the patients. Though tumor recurrence at a different spinal level led to consecutive surgery in 5 patients, no implant dislocation occurred during the observation period (maximum 44 months), characterizing the procedure as a mechanically reliable and safe technique

The conditional process model of mindfulness and emotion regulation: An empirical test

BACKGROUND: The conditional process model (CPM) of mindfulness and emotion regulation posits that specific mediators and moderators link these constructs to mental health outcomes. The current study empirically examined the central tenets of the CPM, which posit that nonreactivity moderates the indirect effect of observation on symptoms of emotional disorders through cognitive emotion regulation strategies. METHODS: A clinical sample (n=1667) of individuals from Japan completed a battery of self-report instruments. Several path analyses were conducted to determine whether cognitive emotion regulation strategies mediate the relationship between observation and symptoms of individual emotional disorders, and to determine whether nonreactivity moderated these indirect effects. RESULTS: Results provided support the CPM. Specifically, nonreactivity moderated the indirect effect of observation on symptoms through reappraisal, but it did not moderate the indirect effect of observation on symptoms through suppression. LIMITATIONS: Causal interpretations are limited, and cultural considerations must be acknowledged given the Japanese sample CONCLUSIONS: These results underscore the potential importance of nonreactivity and emotion regulation as targets for interventions.R01 AT007257 - NCCIH NIH HHS; R34 MH099311 - NIMH NIH HH

Van-der-Waals potentials of paramagnetic atoms

We study single- and two-atom van der Waals interactions of ground-state atoms which are both polarizable and paramagnetizable in the presence of magneto-electric bodies within the framework of macroscopic quantum electrodynamics. Starting from an interaction Hamiltonian that includes particle spins, we use leading-order perturbation theory for the van der Waals potentials expressed in terms of the polarizability and magnetizability of the atom(s). To allow for atoms embedded in media, we also include local-field corrections via the real-cavity model. The general theory is applied to the potential of a single atom near a half space and that of two atoms embedded in a bulk medium or placed near a sphere, respectively.Comment: 18 pages, 3 figures, 1 tabl

Spin relaxation and spin Hall transport in 5d transition-metal ultrathin films

The spin relaxation induced by the Elliott-Yafet mechanism and the extrinsic spin Hall conductivity due to the skew-scattering are investigated in 5d transition-metal ultrathin films with self-adatom impurities as scatterers. The values of the Elliott-Yafet parameter and of the spin-flip relaxation rate reveal a correlation with each other that is in agreement with the Elliott approximation. At 10-layer thickness, the spin-flip relaxation time in 5d transition-metal films is quantitatively reported about few hundred nanoseconds at atomic percent which is one and two orders of magnitude shorter than that in Au and Cu thin films, respectively. The anisotropy effect of the Elliott-Yafet parameter and of the spin-flip relaxation rate with respect to the direction of the spin-quantization axis in relation to the crystallographic axes is also analyzed. We find that the anisotropy of the spin-flip relaxation rate is enhanced due to the Rashba surface states on the Fermi surface, reaching values as high as 97% in 10-layer Hf(0001) film or 71% in 10-layer W(110) film. Finally, the spin Hall conductivity as well as the spin Hall angle due to the skew-scattering off self-adatom impurities are calculated using the Boltzmann approach. Our calculations employ a relativistic version of the first-principles full-potential Korringa-Kohn-Rostoker Green function method

Pulse generation without gain-bandwidth limitation in a laser with self-similar evolution

With existing techniques for mode-locking, the bandwidth of ultrashort pulses from a laser is determined primarily by the spectrum of the gain medium. Lasers with self-similar evolution of the pulse in the gain medium can tolerate strong spectral breathing, which is stabilized by nonlinear attraction to the parabolic self-similar pulse. Here we show that this property can be exploited in a fiber laser to eliminate the gain-bandwidth limitation to the pulse duration. Broad (̃200 nm) spectra are generated through passive nonlinear propagation in a normal-dispersion laser, and these can be dechirped to ̃20-fs duration