A self-reconstructed bifunctional electrocatalyst of pseudo-amorphous nickel carbide @ iron oxide network for seawater splitting.

Here, a sol-gel method is used to prepare a Prussian blue analogue (NiFe-PBA) precursor with a 2D network, which is further annealed to an Fe3 O4 /NiCx composite (NiFe-PBA-gel-cal), inheriting the ultrahigh specific surface area of the parent structure. When the composite is used as both anode and cathode catalyst for overall water splitting, it requires low voltages of 1.57 and 1.66 V to provide a current density of 100 mA cm-2 in alkaline freshwater and simulated seawater, respectively, exhibiting no obvious attenuation over a 50 h test. Operando Raman spectroscopy and X-ray photoelectron spectroscopy indicate that NiOOH2-x active species containing high-valence Ni3+ /Ni4+ are in situ generated from NiCx during the water oxidation. Density functional theory calculations combined with ligand field theory reveal that the role of high valence states of Ni is to trigger the production of localized O 2p electron holes, acting as electrophilic centers for the activation of redox reactions for oxygen evolution reaction. After hydrogen evolution reaction, a series of ex situ and in situ investigations indicate the reduction from Fe3+ to Fe2+ and the evolution of Ni(OH)2 are the origin of the high activity

Experimental and numerical studies of the effects of a rail vibration absorber on suppressing short pitch rail corrugation

The effects of a rail vibration absorber on suppressing short pitch rail corrugation are studied. Firstly, a rail vibration field test is carried out to analyze the vibration response of the rail with and without the vibration absorbers. Secondly, based on the hypothesis that friction-induced self-excited vibration of a wheel-rail system causes rail corrugation; two finite element models of a wheel-rail system and a wheel-rail-absorber system are established and analyzed. Both sets of rail vibration test results and theoretical results show that the rail absorbers can effectively reduce the friction-induced self-excited vibration of the wheel-rail system in the frequency range of 200-800 Hz, which corresponds to frequencies of short pitch rail corrugation. This may be a main reason that the rail vibration absorber can suppress the formation of short pitch rail corrugation

Metastability of a granular surface in a spinning bucket

The surface shape of a spinning bucket of granular material is studied using a continuum model of surface flow developed by Bouchaud et al. and Mehta et al. An experimentally observed central subcritical region is reproduced by the model. The subcritical region occurs when a metastable surface becomes unstable via a nonlinear instability mechanism. The nonlinear instability mechanism destabilizes the surface in large systems while a linear instability mechanism is relevant for smaller systems. The range of angles in which the granular surface is metastable vanishes with increasing system size.Comment: 8 pages with postscript figures, RevTex, to appear in Phys. Rev.

The information about the state of a qubit gained by a weakly coupled detector

We analyze the information that one can learn about the state of a quantum two-level system, i.e. a qubit, when probed weakly by a nearby detector. In particular, we focus on the case when the qubit Hamiltonian and the qubit's operator being probed by the detector do not commute. Because the qubit's state keeps evolving while being probed and because the measurement data is mixed with a detector-related background noise, one might expect the detector to fail in this case. We show, however, that under suitable conditions and by proper analysis of the measurement data useful information about the state of the qubit can be extracted. It turns out that the measurement basis is stochastically determined every time the experiment is repeated. We analyze in detail the probability distributions that govern the choice of measurement bases. We also analyze the information acquisition rate and show that it is largely unaffected by the apparent conflict between the measurement and intrinsic qubit dynamics. We discuss the relation between our analysis and the stochastic master equation that describes the evolution of the qubit's state under the influence of measurement and decoherence. In particular, we write down a stochastic equation that encompasses the usual stochastic master equation for the evolution of the qubit's density matrix and additionally contains the measurement information that can be extracted from the observed signal.Comment: 21 pages (two column), 8 figure

Flavor brane on the baryonic branch of moduli space

We study an extra flavor in the cascading SU((k+1)M)xSU(k M) gauge theory by adding probe D7-brane to the geometry. By finding a solution to the kappa-symmetry equation we establish that the D7-brane is mutually supersymmetric with the background everywhere on the baryonic branch of moduli space. We also discuss possible applications of this result.Comment: 15 pages; v2 typo corrected, references adde

Heterostructured core-Shell Ni-Co@Fe-Co nanoboxes of prussian blue analogues for efficient electrocatalytic hydrogen evolution from alkaline seawater.

The rational construction of efficient and low-cost electrocatalysts for the hydrogen evolution reaction (HER) is critical to seawater electrolysis. Herein, trimetallic heterostructured core-shell nanoboxes based on Prussian blue analogues (Ni-Co@Fe-Co PBA) were synthesized using an iterative coprecipitation strategy. The same coprecipitation procedure was used for the preparation of the PBA core and shell, with the synthesis of the shell involving chemical etching during the introduction of ferrous ions. Due to its unique structure and composition, the optimized trimetallic Ni-Co@Fe-Co PBA possesses more active interfacial sites and a high specific surface area. As a result, the developed Ni-Co@Fe-Co PBA electrocatalyst exhibits remarkable electrocatalytic HER performance with small overpotentials of 43 and 183 mV to drive a current density of 10 mA cm-2 in alkaline freshwater and simulated seawater, respectively. Operando Raman spectroscopy demonstrates the evolution of Co2+ from Co3+ in the catalyst during HER. Density functional theory simulations reveal that the H*-N adsorption sites lower the barrier energy of the rate-limiting step, and the introduced Fe species improve the electron mobility of Ni-Co@Fe-Co PBA. The charge transfer at the core-shell interface leads to the generation of H* intermediates, thereby enhancing the HER activity. By pairing this HER catalyst (Ni-Co@Fe-Co PBA) with another core-shell PBA OER catalyst (NiCo@A-NiCo-PBA-AA) reported by our group, the fabricated two-electrode electrolyzer was found to achieve high output current densities of 44 and 30 mA cm-2 at a low voltage of 1.6 V in alkaline freshwater and simulated seawater, respectively, exhibiting remarkable durability over a 100 h test

Turing Instability in a Boundary-fed System

The formation of localized structures in the chlorine dioxide-idodine-malonic acid (CDIMA) reaction-diffusion system is investigated numerically using a realistic model of this system. We analyze the one-dimensional patterns formed along the gradients imposed by boundary feeds, and study their linear stability to symmetry-breaking perturbations (Turing instability) in the plane transverse to these gradients. We establish that an often-invoked simple local linear analysis which neglects longitudinal diffusion is inappropriate for predicting the linear stability of these patterns. Using a fully nonuniform analysis, we investigate the structure of the patterns formed along the gradients and their stability to transverse Turing pattern formation as a function of the values of two control parameters: the malonic acid feed concentration and the size of the reactor in the dimension along the gradients. The results from this investigation are compared with existing experiments.Comment: 41 pages, 18 figures, to be published in Physical Review

Non-collinear magnetic structure and anisotropic magnetoelastic coupling in cobalt pyrovanadate Co2V2O7

The Co2V2O7 is recently reported to exhibit amazing magnetic field-induced magnetization plateaus and ferroelectricity, but its magnetic ground state remains ambiguous due to its structural complexity. Magnetometry measurements, and time-of-flight neutron powder diffraction (NPD) have been employed to study the structural and magnetic properties of Co2V2O7, which consists of two non-equivalent Co sites. Upon cooling below the Ne\'el temperature TN = 6.3 K, we observe magnetic Bragg peaks at 2K in NPD which indicated the formation of long range magnetic order of Co2+ moments. After symmetry analysis and magnetic structure refinement, we demonstrate that Co2V2O7 possesses a complicated non-collinear magnetic ground state with Co moments mainly located in b-c plane and forming a non-collinear spin-chain-like structure along the c-axis. The ab initio calculations demonstrate that the non-collinear magnetic structure is more stable than various ferromagnetic states at low temperature. The non-collinear magnetic structure with canted up-up-down-down spin configuration is considered as the origin of magnetoelectric coupling in Co2V2O7 because the inequivalent exchange striction induced by the spin-exchange interaction between the neighboring spins is the driving force of ferroelectricity. Besides, it is found that the deviation of lattice parameters a and b is opposite below TN, while the lattice parameter c and stay almost constant below TN, evidencing the anisotropic magnetoelastic coupling in Co2V2O7.Comment: 9 pages, 8 figure