Protective Ag :TiO2 thin films for pressure sensors in orthopedic prosthesis: the importance of composition, structural and morphological features on the biological response of the coatings

DC reactive magnetron sputtered Ag:TiO2 nanocomposite thin films were developed to be used as protective coatings in pressure sensor devices. The coatings, with Ag content varying from 0 to about 30 at.%, were prepared and characterized in order to study their biological response. The as-deposited samples were annealed in vacuum at 500 °C in order to evaluate the influence of their morphological and structural differences over the response elicited upon contact with simulated bodily fluids and cultured human cells, as well as selected microorganisms. The results showed that the annealing treatment produced less porous films with an enhanced structure, with a significant reduction in structural defects and improved crystallinity. Additionally, samples with higher Ag contents (≥12.8 at.%) exhibited Ag agglomerates/clusters at the surface, a result anticipated from the XRD data. The crystallization of the TiO2 matrix was also observed by XRD analysis, albeit delayed by the dispersion of Ag into the matrix. Biological characterization showed that the antimicrobial activity and cytotoxicity of the coatings were directly related with their composition, closely followed by the particular structural and morphological features, namely those resulting from annealing process.This research is partially sponsored by FEDER funds through the program COMPETE—Programa Operacional Factores de Competitividade and by national funds through FCT—Fundação para a Ciência e a Tecnologia, under the projects PEst-C/EME/UI0285/2011, PTDC/SAU-ENB/116850/2010, PTDC/CTM-NAN/112574/2009P. T Matamá acknowledges FCT for Grant SFRH/BPD/47555/2008

Tribological characterization of biocompatible HAp-TiO2 coatings obtained by high velocity oxy-fuel spray

Bioceramic coatings have been employed for many years to improve the biological, and consequently the mechanical, properties of bone implants. However, only a few studies have focused on wear behavior, which has been considered of secondary importance compared to other properties. The present study demonstrates that contrary to this assumption, it is important to guarantee the integrity of the coatings during and after implantation, a process that subjects the surface to high wear. Reciprocating ball-on-flat tests were performed to characterize the wear properties of HAp-TiO2 coatings, which have previously been shown to present other good mechanical and biological properties. An alumina ball was used as counterface and the tests were conducted at 37 ºC immersed in Hank's solution, to simulate physiological conditions. Three loads were employed: 5 N, 10 N and 15 N. The results show a clear advantage of more compact coatings, with a lower percentage of amorphous phases, since they present a higher friction coefficient. That could indicate, according to the literature, better implant fixation and a lower wear rate, and thus ensure the integrity of the coating

Importance of Holocene sea level rise in the development of coastal platforms enabling lava delta progradation in El Hierro, Canary Islands

Marine and subaerial erosion of volcanic ocean islands form coastal cliffs and shore platforms, particularly during stable sea levels. Posterosional lava flows can spill over these coastal cliffs and fill the platforms, leading to the progradation of lava deltas. El Hierro Island, Canary Islands, exemplifies a rocky coast with an active sea-cliff profile, reflecting its early evolutionary stage as a young ocean volcanic island with no fringing reef. The occurrence of a contemporary insular shelf formed during the Holocene sea-level highstand (<7 ka) allows constraining the ages of those eruptions forming lava deltas affecting this geomorphological landform. A detailed bathymetry around the island allowed us to distinguish 17 eruptions fulfilling this criterion. The Montaña del Tesoro, which occurred about 1050 years BP, is one of these eruptions and was selected as a case study for morphometric modelling integrating subaerial and submarine data at the scale of a volcanic edifice. We combine field-based observations with topographic and bathymetric data analysis to reconstruct the pre- and post-eruption Digital Elevation Models (DEMs) and, comparing with present-day DEM, to analyze morphometrically the influence of volcanism on the coastal landscape's development. The resulting landform complexity required discretization of the lava field according to the coastline evolution, lava front sectors, and subaerial or submarine lava placement. We quantitatively demonstrate that dominant degradation occurs in the lava field, mainly disturbed by marine erosion (Rodriguez-Gonzalez et al., 2022, Geomorphology 416, 108427). Marine erosion removed 9 % of the erupted volume of lava flows against 1 % by fluvial erosion. This work provides methods and results of great interest with different implications in oceanic volcanic islands, among which we can mention coastal planning (e.g., rock coast evolution) and volcanic risk assessment (e.g., the importance of Holocene sea-level rise on the development of shore platforms facilitating the progradation of lava deltas).This work was supported by grant PGC2018-101027-B-I00 funded by MCIN/AEI/10.13039/501100011033 and by "ERDF A way of making Europe", by the "European Union". CPT acknowledges the PhD grant 2021 FISDU 00347 funded by the Departament de Recerca i Universitats de la Generalitat de Catalunya.Peer reviewe

Lava deltas, a key landform in oceanic volcanic islands: El Hierro, Canary Islands

Marine and subaerial erosion of volcanic ocean islands form coastal cliffs and shore platforms, particularly during stable sea levels. Posterosional lava flows can spill over these coastal cliffs and fill the platforms, leading to the progradation of lava deltas. This work aims to analyze this volcanic rocky coast setting at the island scale and to assess the volcanic constructional and erosive degradational effects on the coast at the scale of one volcanic edifice. El Hierro Island, Canary Islands, exemplifies a rocky coast with an active sea-cliff profile, reflecting its early evolutionary stage as a young ocean volcanic island with no fringing reef. The occurrence of a contemporary insular shelf formed during the Holocene sea-level highstand (<7 ka) allows constraining the ages of those eruptions forming lava deltas affecting this geomorphological landform. A detailed bathymetry around the island allowed us to distinguish 17 eruptions fulfilling this criterion. The Montaña del Tesoro, which occurred about 1050 years BP, is one of these eruptions and was selected as a case study for morphometric modeling integrating subaerial and submarine data at the scale of a volcanic edifice. This eruption was a Strombolian basaltic volcanic event that produced a scoria cone, pyroclastic fall deposits, and lava flows that reached the ocean in the eastern rift zone of El Hierro island. We combine field-based observations with topographic and bathymetric data analysis to reconstruct the pre- and post-eruption Digital Elevation Models (DEMs) and, comparing with present-day DEM, to analyze morphometrically the influence of volcanism on the coastal landscape's development. The resulting landform complexity required the discretization of the lava field according to the coastline evolution and lava front sectors, and the subaerial or submarine lava placement. The pyroclastic materials' total erupted bulk volume (12,829,578 m3) corresponds to a volcanic eruption index (VEI) of 3. This event was primarily effusive. From a dense rock equivalent (DRE) volume of 25,615,424 m3, 87 % flowed as lava, 10 % formed the cinder cone, and 3 % the tephra fall deposits. We quantitatively demonstrate that dominant degradation occurs in the lava field, mainly disturbed by marine erosion. Marine erosion removed 9 % of the erupted volume of lava flows against 1 % by fluvial erosion. This work provides methods and results of great interest with different implications in oceanic volcanic islands, among which we can mention coastal planning (e.g., rock coast evolution) and volcanic risk assessment (e.g., the importance of Holocene sea-level rise on the development of shore platforms facilitating the progradation of lava deltas).Grant PGC2018-101027-B-I00 funded by MCIN/AEI/10.13039/501100011033 and by “ERDF A way of making Europe”, by the “European Union”. CPT acknowledges the PhD grant 2021 FISDU 00347 funded by the Departament de Recerca i Universitats de la Generalitat de Catalunya.Peer reviewe