Using bijective maps to improve free energy estimates

We derive a fluctuation theorem for generalized work distributions, related to bijective mappings of the phase spaces of two physical systems, and use it to derive a two-sided constraint maximum likelihood estimator of their free energy difference which uses samples from the equilibrium configurations of both systems. As an application, we evaluate the chemical potential of a dense Lennard-Jones fluid and study the construction and performance of suitable maps.Comment: 17 pages, 11 figure

Viscous three-dimensional analyses for nozzles for hypersonic propulsion

A Navier-Stokes computer code was validated using a number of two- and three-dimensional configurations for both laminar and turbulent flows. The validation data covers a range of freestream Mach numbers from 3 to 14, includes wall pressures, velocity profiles, and skin friction. Nozzle flow fields computed for a generic scramjet nozzle from Mach 3 to 20, wall pressures, wall skin friction values, heat transfer values, and overall performance are presented. In addition, three-dimensional solutions obtained for two asymmetric, single expansion ramp nozzles at a pressure ratio of 10 consists of the internal expansion region in the converging/diverging sections and the external supersonic exhaust in a quiescent ambient environment. The fundamental characteristics that were captured successfully include expansion fans; Mach wave reflections; mixing layers; and nonsymmetrical, multiple inviscid cell, supersonic exhausts. Comparison with experimental data for wall pressure distributions at the center planes shows good agreement

NONLINEAR POLARIZATION SPECTROSCOPY (FREQUENCY DOMAIN) STUDIES OF EXCITED STATE PROCESSES: THE B800–850ANTENNA OF RHODOBACTER SPHAEROIDES

Nonlinear polarization spectroscopy in the frequency domain allows rate constant determinations of fast electronic energy and phase relaxations together with characterization of the type of line broadening. Application of this method to the B850 component of the isolated B800–850antenna ofRhodobacter sphaeroides at room temperature shows that B850 is inhomogeneously broadened, with homogeneous widths between 30 and 200 cm−1, depending on the spectral position of the subforms. The corresponding phase relaxation times are clearly in the subpicosecond range. There is also indication of an up-to-now unspecified1–5 ps energy relaxation channel per subunit

Many-Body Corrections to Charged-Current Neutrino Absorption Rates in Nuclear Matter

Including nucleon--nucleon correlations due to both Fermi statistics and nuclear forces, we have developed a general formalism for calculating the charged--current neutrino--nucleon absorption rates in nuclear matter. We find that at one half nuclear density many--body effects alone suppress the rates by a factor of two and that the suppression factors increase to $\sim$5 at $4\times10^{14}$ g cm$^{-3}$. The associated increase in the neutrino--matter mean--free--paths parallels that found for neutral--current interactions and opens up interesting possibilities in the context of the delayed supernova mechanism and protoneutron star cooling.Comment: 11 pages, APS REVTeX format, 1 PostScript figure, uuencoded compressed, and tarred, submitted to Physical Review Letter

Audio Information Retrieval using Sinusoidal Modeling based Features

In this paper, we propose an approach for searching a speech query word in an audio data base. In this approach, we explore Sinusoidal modeling based features such as Amplitude, Frequency and Phase of the speech signal. Three independent systems are built using these features. Further, the Majority voting logic is used to arrive at a conclusion to locate (time stamp) the query word in the reference utterances. The studies are performed on the TIMIT database. The results show that, Sinusoidal based features can be used for speech processing in place of conventional approaches

Numerical Toy-Model Calculation of the Nucleon Spin Autocorrelation Function in a Supernova Core

We develop a simple model for the evolution of a nucleon spin in a hot and dense nuclear medium. A given nucleon is limited to one-dimensional motion in a distribution of external, spin-dependent scattering potentials. We calculate the nucleon spin autocorrelation function numerically for a variety of potential densities and distributions which are meant to bracket realistic conditions in a supernova core. For all plausible configurations the width of the spin-density structure function is found to be less than the temperature. This is in contrast with a naive perturbative calculation based on the one-pion exchange potential which overestimates the width and thus suggests a large suppression of the neutrino opacities by nucleon spin fluctuations. Our results suggest that it may be justified to neglect the collisional broadening of the spin-density structure function for the purpose of estimating the neutrino opacities in the deep inner core of a supernova. On the other hand, we find no indication that processes such as axion or neutrino pair emission, which depend on nucleon spin fluctuations, are substantially suppressed beyond the multiple-scattering effect already discussed in the literature. Aside from these practical conclusions, our model reveals a number of interesting and unexpected insights. For example, the spin-relaxation rate saturates with increasing potential strength only if bound states are not allowed to form by including a repulsive core. There is no saturation with increasing density of scattering potentials until localized eigenstates of energy begin to form.Comment: 14 latex pages in two-column format, 15 postscript figures included, uses revtex.sty and epsf.sty. Submitted to Physical Review

Preparation of lithium 5-lithiomethy-3-methylpyrazole-1-carboxylate and its reaction with α-oxoketene dithioacetals: a new general method for substituted and annelated pyrazolo[1,5-a]pyridines

5-Methylpyrazole derivative 1 is metallated at the C-5 methyl carbon atom to form lithium 5-lithiomethyl-3-methylpyrazole-1-carboxylate 3 which on reaction with α-oxoketene dithioacetals 4a-d, 12a-c and 15a-b yields substituted and annelated pyrazolo[1,5-a]pyridines 7a-d, 13a-c and 16a-b

On some singularities of the correlation functions that determine neutrino opacities

Certain perturbation graphs in the calculation of the effects of the medium on neutrino scattering in supernova matter have a nonintegrable singularity in a physical region. A number of papers have addressed the apparent pathology through an ansatz that invokes higher order (rescattering) effects. Taking the Gamow-Teller terms as an example, we display an expression for the spin-spin correlation function that determines the cross-sections. It is clear from the form that there are no pathologies in the order by order perturbation expansion. Explicit formulae are given for a simple case, leading to an answer that is very different from one given by other authors.Comment: 8 page