Structure variation and evolution in microphase-separated grafted diblock copolymer films

The phase behavior of grafted d-polystyrene-block-poly(methyl methacrylate) diblock copolymer films is examined, with particular focus on the effect of solvent and annealing time. It was observed that the films undergo a two-step transformation from an initially disordered state, through an ordered metastable state, to the final equilibrium configuration. It was also found that altering the solvent used to wash the films, or complete removal of the solvent prior to thermal annealing using supercritical CO2, could influence the structure of the films in the metastable state, though the final equilibrium state was unaffected. To aid in the understanding to these experimental results, a series of self-consistent field theory calculations were done on a model diblock copolymer brush containing solvent. Of the different models examined, those which contained a solvent selective for the grafted polymer block most accurately matched the observed experimental behavior. We hypothesize that the structure of the films in the metastable state results from solvent enrichment of the film near the film/substrate interface in the case of films washed with solvent or faster relaxation of the nongrafted block for supercritical CO2 treated (solvent free) films. The persistence of the metastable structures was attributed to the slow reorganization of the polymer chains in the absence of solvent

Light-Front Holography: A First Approximation to QCD

Starting from the Hamiltonian equation of motion in QCD, we identify an invariant light-front coordinate $\zeta$ which allows the separation of the dynamics of quark and gluon binding from the kinematics of constituent spin and internal orbital angular momentum. The result is a single variable light-front Schrodinger equation for QCD which determines the eigenspectrum and the light-front wavefunctions of hadrons for general spin and orbital angular momentum. This light-front wave equation is equivalent to the equations of motion which describe the propagation of spin-$J$ modes on anti-de Sitter (AdS) space.Comment: 4 pages. The limits of validity of the model are further discussed. To appear in Physical Review Letter