75 research outputs found
The effect of phosphorus on the iron redox ratio, viscosity, and density of an evolved ferro-basalt
Despite the abundant evidence for the enrichment of phosphorus during the petrogenesis of natural ferro-basalts, the effect of phosphorus on the physical properties of these melts is poorly understood. The effects of phosphorus on the viscosity, density and redox ratio of a ferro-basaltic melt have been determined experimentally. The viscosity measurements were obtained using the concentric cylinder method on a ferro-basaltic melt above its liquidus, at 1 atm, in equilibrium with air and with CO2. The density measurements were performed using the double Pt-bob Archimedean method at superliquidus conditions under 1 atm of air. The redox ratio was obtained by wet chemical analysis of samples collected during physical property measurements. Phosphorus pentoxide reduces ferric iron in ferro-basaltic melt. The reduction due to P2O5 is much larger than that for most other oxide components in basaltic melts. A coefficient for the reduction of ferric iron has been generated for inclusion in calculation schemes. The effect of P2O5 on the viscosity is shown to be complex. The initial reduction of ferric iron with the addition of P2O5 results in a relatively small change in viscosity, while further addition of P2O5 results in a strong increase. The addition of phosphorus to a ferro-basaltic melt also reduces the density. A partial molar volume of 64.5±0.7 cm3/mol for P2O5 in this melt has been obtained at 1300° C, yielding a volume of 12.9 cm3/mol per oxygen, consistent with a tetrahedral coordination for this high field strength cation. The effects of P2O5 on redox state, density and viscosity provide constraints on the structural role of phosphorus in these melts. The results suggest a complex interaction of phosphorus with the aluminosilicate network, and tetrahedral ferric iron. In light of the significant effects of phosphorus on the physical and chemical properties of ferro-basaltic liquids, and the extreme enrichments possible in these liquids in nature, the role of phosphorus in these melts should, in future, be considered more carefully
High temperature behavior of electrostatic precipitator ash from municipal solid waste combustors
International audienceMunicipal solid waste (MSW) flue gas residues require further treatment prior to disposal or reuse, and vitrification is one of the main solidification-stabilization processes.This paper investigates the high temperature behavior of MSW flue gas residues, performed in laboratory experiments up to 1400°C, and coupled with thermogravimetric analyses, X-ray diffraction, chemical and electron microprobe analyses. Melting temperatures of electrostatic precipitator (ESP) ash are in the range of 1202-1272 °C, whereas semi-dry scrubber residues melt between 1900 and 2300 °C. The mean liquidus temperature of flue gas residues can be simply evaluated as a function of their CaO content, by using the CaO-SiO2-Al2O3 ternary diagram. For ESP ash, the liquidus phase is a Zn-rich aluminous spinel, followed by anorthite at 1225 °C, and melilite at 1190 °C. The total mass loss reaches 18 wt.% at 1300 °C. Moreover, 90% of evaporation takes place below 1000 °C, linked to evaporation of C, Cl, S, Na, K, and of the toxic metals Hg, Cd, Pb, Cu. Due to the high partial pressure of chlorine during heating, chloride is the most probable form of evaporation for Cd, Pb, and Cu. However, most of Zn, Cr, Ni, Sb and Sn remain in the vitrified product
The effect of phosphorus on the iron redox ratio, viscosity, and density of an evolved ferro-basalt
Despite the abundant evidence for the enrichment of phosphorus during the petrogenesis of natural ferro-basalts, the effect of phosphorus on the physical properties of these melts is poorly understood. The effects of phosphorus on the viscosity, density and redox ratio of a ferro-basaltic melt have been determined experimentally. The viscosity measurements were obtained using the concentric cylinder method on a ferro-basaltic melt above its liquidus, at 1 atm, in equilibrium with air and with CO2. The density measurements were performed using the double Pt-bob Archimedean method at superliquidus conditions under 1 atm of air. The redox ratio was obtained by wet chemical analysis of samples collected during physical property measurements. Phosphorus pentoxide reduces ferric iron in ferro-basaltic melt. The reduction due to P2O5 is much larger than that for most other oxide components in basaltic melts. A coefficient for the reduction of ferric iron has been generated for inclusion in calculation schemes. The effect of P2O5 on the viscosity is shown to be complex. The initial reduction of ferric iron with the addition of P2O5 results in a relatively small change in viscosity, while further addition of P2O5 results in a strong increase. The addition of phosphorus to a ferro-basaltic melt also reduces the density. A partial molar volume of 64.5±0.7 cm3/mol for P2O5 in this melt has been obtained at 1300° C, yielding a volume of 12.9 cm3/mol per oxygen, consistent with a tetrahedral coordination for this high field strength cation. The effects of P2O5 on redox state, density and viscosity provide constraints on the structural role of phosphorus in these melts. The results suggest a complex interaction of phosphorus with the aluminosilicate network, and tetrahedral ferric iron. In light of the significant effects of phosphorus on the physical and chemical properties of ferro-basaltic liquids, and the extreme enrichments possible in these liquids in nature, the role of phosphorus in these melts should, in future, be considered more carefully
Lead Isotopic Composition of Fly Ash and Flue Gas Residues from Municipal Solid Waste Combustors in France: Implications for Atmospheric Lead Source Tracing.
Fly ash and flue gas residues from eight municipal solid waste combustors (MSWC) in France (1992-93 and 1998/2002) were analyzed for their Pb isotopic composition. Fly ashes are more representative of solid residual particles, whereas flue gas residues reflect mostly the composition of gas phases. Both sample types contain hundreds to thousands of micrograms of metals per gram. Leaching experiments showed that metals are present in condensed phases, probably as sulfates and chlorides, and suggest that Cd, Pb, and Zn are highly fractionated from one another during volatilization/condensation processes occurring during combustion. Although all the samples analyzed define a fairly restricted range in Pb isotopic compositions (206Pb/207Pb = 1.148-1.158 and 208Pb/206Pb = 2.101-2.114) compared to other environmental samples, some MSWC produce materials having distinct isotopic compositions, whereas others display very similar ones. Isotopic heterogeneity is also measured between samples from a single MSWC. This is interpreted as resulting from the heterogeneity of the waste source materials. The range of Pb isotopic composition of incinerator materials form a well-defined linear array in the 208Pb/206Pb versus 206Pb/207Pb diagram. This array is compatible with the previously reported European standard pollution (ESP) line and most probably represent the average lead isotopic composition of industrial atmospheric emissions in France, with the following ratios: 206Pb/207Pb = 1.154 ± 0.003 and 208Pb/206Pb = 2.107 ± 0.003 (1)
Vapor-Melt Exchange -- Constraints on Chondrite Formation Conditions and Processes
The bulk volatile contents of chondritic meteorites provide clues to their
origins. Matrix and chondrules carry differing abundances of moderately
volatile elements, with chondrules carrying a refractory signature. At the high
temperatures of chondrule formation and the low pressures of the solar nebula,
many elements, including Na and Fe, should have been volatile. Yet the evidence
is that even at peak temperatures, at or near the liquidus, Na and Fe (as FeO
and Fe-metal) were present in about their current abundances in molten
chondrules. This seems to require very high solid densities during chondrule
formation to prevent significant evaporation. Evaporation should also be
accompanied by isotopic mass fractionation. Evidence from a wide range of
isotopic systems indicates only slight isotopic mass fractionations of
moderately vola-tile elements, further supporting high solid densities.
However, olivine-rich, FeO-poor chondrules commonly have pyroxene-dominated
outer zones that have been interpreted as the prod-ucts of late condensation of
SiO2 into chondrule melts. Late condensation of more refractory SiO2 is
inconsistent with the apparent abundances of more volatile Na, FeO and Fe-metal
in many chondrules. Despite significant recent experimental work bearing on
this problem, the conditions under which chondrules behaved as open systems
remain enigmatic
Assessment of diseases susceptibility of peach cultivars in experimental plots and on-farm for organic and low-input systems. Baseline of French case studies
Despite a high turn-over of new peach cultivars, their suitability for organic and low-input systems remains unknown for most of them. Diseases susceptibility is an important criteria to consider since diseases control is a bottleneck to peach production in theses systems. Since 2001, 81 peach cultivars were assessed in 2 experimental sites and 7 on-farm plots
On automatic class insertion with overloading
Also published in Proceedings of the 11th ACM SIGPLAN conference on Object-oriented programming, systems, languages, and applications (OOPSLA)International audienceSeveral algorithms [Cas92, MS89, Run92, DDHL94a, DDHL95, GMM95] have been proposed to automatically insert a class into an inheritance hierarchy. But actual hierarchies all include overriden and overloaded properties that these algorithms handle either very partially or not at all. Partially handled means handled provided there is a separate given function f able to compare overloaded properties [DDHL95, GMM95].In this paper, we describe a new version of our algorithm (named Ares) which handles automatic class insertion more efficiently using such a function f. Although impossible to fully define, this function can be computed for a number of well defined cases of overloading and overriding. We give a classification of such cases and describe the computation process for a well-defined set of nontrivial cases.The algorithm preserves these important properties:- preservation of the maximal factorization of properties- preservation of the underlying structure (Galois lattice) of the input hierarchy- conservation of relevant classes of the input hierarchy with their properties
Thermal fatigue as the origin of regolith on small asteroids
Space missions and thermal infrared observations3 have shown that small asteroids (kilometre-sized or smaller) are covered by a layer of centimetre-sized or smaller particles, which constitute the regolith. Regolith generation has traditionally been attributed to the fall back of impact ejecta and by the break-up of boulders bymicrometeoroid impact. Laboratory experiments6 and impact models, however, show that crater ejecta velocities are typically greater than several tens of centimetres per second,which corresponds to the gravitational escape velocity of kilometre-sized asteroids.Therefore, impact debris cannot be the main source of regolith on small asteroids. Here we report that thermal fatigue, a mechanism of rock weathering and fragmentation with no subsequent ejection, is the dominant process governing regolith generation on small asteroids.We find that thermal fragmentation induced by the diurnal temperature variations breaks up rocks larger than a few centimetres more quickly than do micrometeoroid impacts. Because thermal fragmentation is independent of asteroid size, this process can also contribute to regolith production on larger asteroids. Production of fresh regolith originatingin thermal fatigue fragmentationmay be an important process for the rejuvenation of the surfaces of near-Earth asteroids, and may explain the observed lack of low-perihelion, carbonaceous, near-Earth asteroids
Evolution of oxygen isotopic composition in the inner solar nebula
Changes in the chemical and isotopic composition of the solar nebula with
time are reflected in the properties of different constituents that are
preserved in chondritic meteorites. CR carbonaceous chondrites are among the
most primitive of all chondrite types and must have preserved solar nebula
records largely unchanged. We have analyzed the oxygen and magnesium isotopes
in a range of the CR constituents of different formation temperatures and ages,
including refractory inclusions and chondrules of various types. The results
provide new constraints on the time variation of the oxygen isotopic
composition of the inner (<5 AU) solar nebula - the region where refractory
inclusions and chondrules most likely formed. A chronology based on the decay
of short-lived 26Al (t1/2 ~ 0.73 Ma) indicates that the inner solar nebula gas
was 16O-rich when refractory inclusions formed, but less than 0.8 Ma later, gas
in the inner solar nebula became 16O-poor and this state persisted at least
until CR chondrules formed ~1-2 Myr later. We suggest that the inner solar
nebula became 16O-poor because meter-size icy bodies, which were enriched in
17,18O due to isotopic self-shielding during the ultraviolet photo dissociation
of CO in the protosolar molecular cloud or protoplanetary disk, agglomerated
outside the snowline, drifted rapidly towards the Sun, and evaporated at the
snowline. This led to significant enrichment in 16O-depleted water, which then
spread through the inner solar system. Astronomical studies of the spatial
and/or temporal variations of water abundance in protoplanetary disks may
clarify these processes.Comment: 27 pages, 5 figure
- …