Enhanced Electrorheological Performance of Nb-Doped TiO₂ Microspheres Based Suspensions and Their Behavior Characteristics in Low-Frequency Dielectric Spectroscopy

Titanium dioxide and Nb-doped titanium dioxide microspheres with the same size were fabricated by a simple sol–gel method, and the formation mechanism of Nb-doped titanium dioxide microspheres was proposed. Titanium dioxide and Nb-doped titanium dioxide microspheres were adopted as dispersed materials for electrorheological (ER) fluids to investigate the influence of the charge increase introduced by Nb doping on the ER activity. The results showed that Nb doping could effectively enhance the ER performance. Combining with the analysis of dielectric spectroscopy, it was found that the interface polarization of Nb-doped TiO₂ ER fluid was larger than that of TiO₂ ER fluid, which might be caused by more surface charges in Nb-TiO₂ microspheres due to Nb⁵⁺ doping and resulting in enhancement of electric field force and strengthening of fibrous structure. In addition, by comparing and analyzing the permittivity curves of Nb-TiO₂/LDPE solid composite and Nb-TiO₂/silicone-oil fluid composite, it could be concluded that the enhancement of permittivity at low frequency resulted from the increase of the order degree of dispersed particles in ER fluid rather than from the quasi-dc (QDC) behavior. Moreover, the absolute value of slope of permittivity curves (<i>K</i>) at 0.01 Hz could be utilized as the standard for judging the ability to maintain the chainlike structure. The relationships between polarizability of dispersed particles, dielectric spectrum, parameter <i>K</i>, and ER properties were discussed in detail

Intercalation Synthesis of Prussian Blue Analogue Nanocone and Their Conversion into Fe-Doped Co_<i>x</i>P Nanocone for Enhanced Hydrogen Evolution

Compared with the monometallic phosphides, bimetallic phosphides can further improve the catalytic performance for hydrogen evolution reaction (HER). As such, the rational design and facile synthesis of bimetallic-based phosphides with well-controlled architectures and compositions is of scientific and technological importance. In this work, Fe–Co Prussian blue analogue (PBA) nanocones (NCs) have been successfully fabricated via an intercalation reaction strategy by utilizing layer structured α-Co­(OH)₂ NCs as self-sacrificing templates. After calcination and phosphorization process, Fe–Co PBA NCs can be converted to Fe-doped Co_<i>x</i>P NCs without obvious shrinkage. Electrochemical tests show that Fe incorporation can effectively promote the electrocatalytic activities of Co_<i>x</i>P. This simple and effective method will be of benefit for the development of other functional Co-based bimetallic compounds. Furthermore, this strategy can possibly be extended to fabricate a series of PBA materials with special structure and novel morphology, which can serve as a promising platform for diverse applications, especially in energy storage and conversion