12 research outputs found
Stabilizing Single Sites on Solid Supports: Robust Grafted Ti(IV)-Calixarene Olefin Epoxidation Catalysts via Surface Polymerization and Cross-Linking
This manuscript develops a surface polymerization and cross-linking approach for the stabilization of single-site catalysts on solid surfaces, which is demonstrated here for grafted Ti(IV)-calixarene Lewis acids on silica. Our approach relies on cationic polymerization that is initiated by an adsorbed B(C_6F_5)_3 and uses styrene as the monomer and diisopropenylbenzene as the cross-linking agent. The mildness of this polymerization method is demonstrated by its lack of blocking micropores and only slight consumption of mesopore internal surface area on the basis of N2 physisorption data at 77 K, both of which are in contrast to previously reported surface-polymerization approaches. Catalysis of samples before and after polymerization and cross-linking was investigated with a probe reaction consisting of the epoxidation of 1-octene with tert-butyl hydroperoxide as oxidant, which is known to be catalyzed by Lewis-acid sites, and a comparison of catalyst hydrolytic stability was performed. Added water in the latter was used as a a trigger to induce site aggregation, as a stress test to determine the effectiveness of site protection by our polymerization approach. Consistent with the N2 physisorption data, catalysis data demonstrate that surface polymerization does not block small-molecule reactant and product access to Lewis-acid sites on the surface, since the conversion remains essentially unchanged before and after surface polymerization and cross-linking. DR UV–vis, TGA, and catalysis data reveal that the grafted Ti(IV)-calixarene sites on silica maintain their catalytic activity even after being treated with corrosive protic stress-test solution. In sharp contrast, grafted sites without the polymer layer leach nearly all of their calixarene and Ti contents during similar stress testing, resulting in the near complete loss of catalytic activity. We hypothesize that the surface polymer acts as a nanoreactor gatekeeper, which prevents the large Ti(IV)-calixarene site from leaching and keeps surface complexes as single sites grafted on the silica surface, by blocking access for the migration of sites from the surface to bulk solution
Stabilizing Single Sites on Solid Supports: Robust Grafted Ti(IV)-Calixarene Olefin Epoxidation Catalysts via Surface Polymerization and Cross-Linking
This manuscript develops a surface polymerization and cross-linking approach for the stabilization of single-site catalysts on solid surfaces, which is demonstrated here for grafted Ti(IV)-calixarene Lewis acids on silica. Our approach relies on cationic polymerization that is initiated by an adsorbed B(C_6F_5)_3 and uses styrene as the monomer and diisopropenylbenzene as the cross-linking agent. The mildness of this polymerization method is demonstrated by its lack of blocking micropores and only slight consumption of mesopore internal surface area on the basis of N2 physisorption data at 77 K, both of which are in contrast to previously reported surface-polymerization approaches. Catalysis of samples before and after polymerization and cross-linking was investigated with a probe reaction consisting of the epoxidation of 1-octene with tert-butyl hydroperoxide as oxidant, which is known to be catalyzed by Lewis-acid sites, and a comparison of catalyst hydrolytic stability was performed. Added water in the latter was used as a a trigger to induce site aggregation, as a stress test to determine the effectiveness of site protection by our polymerization approach. Consistent with the N2 physisorption data, catalysis data demonstrate that surface polymerization does not block small-molecule reactant and product access to Lewis-acid sites on the surface, since the conversion remains essentially unchanged before and after surface polymerization and cross-linking. DR UV–vis, TGA, and catalysis data reveal that the grafted Ti(IV)-calixarene sites on silica maintain their catalytic activity even after being treated with corrosive protic stress-test solution. In sharp contrast, grafted sites without the polymer layer leach nearly all of their calixarene and Ti contents during similar stress testing, resulting in the near complete loss of catalytic activity. We hypothesize that the surface polymer acts as a nanoreactor gatekeeper, which prevents the large Ti(IV)-calixarene site from leaching and keeps surface complexes as single sites grafted on the silica surface, by blocking access for the migration of sites from the surface to bulk solution
SSZ-70 borosilicate delamination without sonication: effect of framework topology on olefin epoxidation catalysis
We report a scalable delamination procedure for a SSZ-70-framework layered-zeolite precursor, which for the first time does not involve either sonication or long-chain surfactants. Our approach instead relies on the mild heating of layered zeolite precursor B-SSZ-70(P) in an aqueous solution containing Zn(NO_3)_2 and tetrabutylammonium fluoride. Powder X-ray diffraction data are consistent with a loss of long-range order along the z-direction, while ^(29)Si MAS NMR spectroscopy demonstrates preservation of the zeolite framework crystallinity during delamination. The resulting delaminated material, DZ-2, possesses 1.4-fold higher external surface area relative to the nondelaminated three-dimensional zeolite B-SSZ-70, based on N2 physisorption data at 77 K. DZ-2 was functionalized with cationic Ti heteroatoms to synthesize Ti-DZ-2 via exchange with framework B. Ti-DZ-2 contains isolated titanium centers in its crystalline framework, as shown by UV-Vis spectroscopy. The generality of the synthetic delamination approach and catalyst synthesis is demonstrated with the synthesis of delaminated material DZ-3, which is derived from layered zeolite precursor ERB-1(P) with MWW framework topology. Upon catalytic testing for the epoxidation of 1-octene with ethylbenzene hydroperoxide as oxidant, under harsh tail-end conditions that deactivate amorphous Ti-silica-based catalysts, Ti-DZ-2 exhibits the highest per-Ti-site activity, selectivity, and stability for 1-octene epoxidation of all catalysts investigated. This testing includes the prior benchmark delaminated zeolite catalyst in this area, Ti-UCB-4, which possesses similar external surface area to Ti-DZ-2 but requires sonication and long-chain surfactants for its synthesis. The synthesis of DZ-2 is the first example of an economical delamination of layered zeolite precursor SSZ-70(P) and opens up new doors to the development of delaminated zeolites as commercial catalysts
Synthesis, Physicochemical Characterization, and Catalytic Evaluation of Fe\u3csup\u3e3+\u3c/sup\u3e-Containing SSZ-70 Zeolite
Whereas one-dimensional, 10-membered ring zeolites are typically used for hydroisomerization, Fe3+-containing SSZ-70 (Fe-SSZ-70) shows remarkable isomerization selectivity for a zeolite containing 12- and partially blocked 14-membered rings, in addition to 10-membered rings. Fe-SSZ-70 was compared to Al3+-containing SSZ-70 (Al-SSZ-70) in constraint index and n-decane hydrocracking tests. Fe-SSZ-70 exhibited a 74% total isomer yield (64% yield of monobranched isomers and 10% cracking yield) at 85% conversion compared to 49% total isomer yield (41% yield of monobranched isomers and 36% cracking yield) for Al-SSZ-70 at the same conversion. The selectivity to isomerization is attributed to the weaker acid strength of Fe-SSZ-70 over Al-SSZ-70. Fe-SSZ-70 was directly synthesized with Fe3+ isomorphously substituted in tetrahedral positions. The coordination environment of the Fe3+ was characterized using Mössbauer, electron paramagnetic resonance, and diffuse reflectance UV-vis spectroscopies. The physicochemical properties were further probed with inductively coupled plasma atomic emission spectroscopy, temperature-programmed desorption of isopropylamine, and nitrogen adsorption-desorption. The Fe3+ was tetrahedrally coordinated in the as-made materials and became partially octahedrally coordinated upon calcination; enough Fe3+ remained in the framework after calcination for Fe-SSZ-70 to remain catalytically active
Effect of Coordination Environment in Grafted Single-Site Ti-SiO_2 Olefin Epoxidation Catalysis
The effect of calixarene ligand symmetry, as dictated by lower-rim substitution pattern, on the coordination to a Ti(IV) cation is assessed in solution and when grafted on SiO_2, and its effect on epoxidation catalysis by Ti(IV)-calixarene grafted on SiO_2 is investigated. C_(2v) symmetric Ti-tert-butylcalix[4]arene complexes that are 1,3-alkyl disubstituted at the lower rim (di-R-Ti) are compared to previously reported grafted C_s symmetric complexes, which are singly substituted at the lower rim (mono-R-Ti). ^(13)C MAS NMR spectra of complexes isotopically enriched at the lower-rim alkyl position indicate that di-R-Ti predominantly grafts onto silica as the conformation found in solution, exhibiting a deshielded alkyl resonance compared to the grafted mono-R-Ti complexes, which is consistent with stronger alkyl ether→Ti dative interactions that are hypothesized to result in higher electron density at the Ti center. Moreover, ^(13)C MAS NMR spectroscopy detects an additional contribution from an “endo” conformer for grafted di-R-Ti sites, which is not observed in solution. Based on prior molecular modeling studies and on ^(13)C MAS NMR spectroscopy chemical shifts, this “endo” conformer is proposed to have similar Ti–(alkyl ether) distances at the lower-rim and electron density at the Ti center relative to grafted mono-R-Ti complexes. Differences between grafted mono-R-Ti and di-R-Ti sites can be observed by ligand-to-metal charge transfer edge-energies, calculated from diffuse-reflectance UV–visible spectroscopy at 2.24 ± 0.02 and 2.16 ± 0.02 eV, respectively. However, rates of tert-butyl hydroperoxide consumption in the epoxidation of 1-octene are found to be largely unchanged when compared to those of the grafted mono-R-Ti complexes, with average rate constants of ~1.5 M^(−2) s^(−1) and initial TOF of ~4 ks^(−1) at 323 K. This suggests that an “endo” conformation of grafted di-R-Ti may prevail during catalysis. Despite this, grafted di-C_1-Ti complexes can be more selective than mono-C_1-Ti complexes (45 vs. 34 % at a 50 % conversion at 338 and 353 K), illustrating the importance of the Ti coordination environment on epoxidation catalysis
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Spectroscopic Characterization of μ-η1:η1-Peroxo Ligands Formed by Reaction of Dioxygen with Electron-Rich Iridium Clusters.
Although oxygen is a common ligand in supported metal catalysts, its coordination has been challenging to elucidate. We now characterize a diiridium complex that has been previously shown by X-ray diffraction crystallography to incorporate a μ-η1:η1-peroxo ligand. We observe markedly enhanced intensity at 788 cm-1 in the Raman spectrum of this complex, which is a consequence of bonding of the peroxo ligand but does not shift upon 18O labeling. Electronic structure calculations at the density functional theory level suggest that this increase in Raman intensity results from bands associated with rocking of CH2 substituents directly attached to P(Ph)2 groups coupling with the O-O band. These results provide part of the foundation for understanding oxygen ligands on a silica-supported tetrairidium carbonyl cluster stabilized with bulky electron-donating phosphine ligands [p-tert-butyl-calix[4]arene(OPr)3(OCH2PPh2) (Ph = phenyl; Pr = propyl)]. Reaction of the cluster with O2 also led to the growing in of a Raman band at 788 cm-1, similar to that in the diiridium complex and also assigned to the bonding of a bridging peroxo ligand. Infrared spectra recorded as the supported cluster reacted in sequential exposures to (i) H2, (ii) O2, (iii) H2, and (iv) CO indicate that two bridging peroxo ligands were bonded irreversibly per tetrairidium cluster, replacing bridging carbonyl ligands without altering either the cluster frame or the phosphine ligands. X-ray absorption near edge and infrared spectra include isosbestic points signifying a stoichiometrically simple reaction of the cluster with O2, and mass spectra of the effluent gas show that CO2 formed by oxidation of one terminal CO ligand per cluster as H2 (and not H2O) formed, evidence that hydride ligands had been present on the cluster following treatment (i). The understanding of how O2 reacts with the metal polyhedron provides a foundation for understanding of how oxidation catalysis may proceed on the surfaces of noble metals
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Spectroscopic Characterization of μ-η1:η1-Peroxo Ligands Formed by Reaction of Dioxygen with Electron-Rich Iridium Clusters.
Although oxygen is a common ligand in supported metal catalysts, its coordination has been challenging to elucidate. We now characterize a diiridium complex that has been previously shown by X-ray diffraction crystallography to incorporate a μ-η1:η1-peroxo ligand. We observe markedly enhanced intensity at 788 cm-1 in the Raman spectrum of this complex, which is a consequence of bonding of the peroxo ligand but does not shift upon 18O labeling. Electronic structure calculations at the density functional theory level suggest that this increase in Raman intensity results from bands associated with rocking of CH2 substituents directly attached to P(Ph)2 groups coupling with the O-O band. These results provide part of the foundation for understanding oxygen ligands on a silica-supported tetrairidium carbonyl cluster stabilized with bulky electron-donating phosphine ligands [p-tert-butyl-calix[4]arene(OPr)3(OCH2PPh2) (Ph = phenyl; Pr = propyl)]. Reaction of the cluster with O2 also led to the growing in of a Raman band at 788 cm-1, similar to that in the diiridium complex and also assigned to the bonding of a bridging peroxo ligand. Infrared spectra recorded as the supported cluster reacted in sequential exposures to (i) H2, (ii) O2, (iii) H2, and (iv) CO indicate that two bridging peroxo ligands were bonded irreversibly per tetrairidium cluster, replacing bridging carbonyl ligands without altering either the cluster frame or the phosphine ligands. X-ray absorption near edge and infrared spectra include isosbestic points signifying a stoichiometrically simple reaction of the cluster with O2, and mass spectra of the effluent gas show that CO2 formed by oxidation of one terminal CO ligand per cluster as H2 (and not H2O) formed, evidence that hydride ligands had been present on the cluster following treatment (i). The understanding of how O2 reacts with the metal polyhedron provides a foundation for understanding of how oxidation catalysis may proceed on the surfaces of noble metals
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A Stable Silanol Triad in the Zeolite Catalyst SSZ-70.
Nests of three silanol groups are located on the internal pore surface of calcined zeolite SSZ-70. 2D 1 H double/triple-quantum single-quantum correlation NMR experiments enable a rigorous identification of these silanol triad nests. They reveal a close proximity to the structure directing agent (SDA), that is, N,N'-diisobutyl imidazolium cations, in the as-synthesized material, in which the defects are negatively charged (silanol dyad plus one charged SiO- siloxy group) for charge balance. It is inferred that ring strain prevents the condensation of silanol groups upon calcination and removal of the SDA to avoid energetically unfavorable three-rings. In contrast, tetrad nests, created by boron extraction from B-SSZ-70 at various other locations, are not stable and silanol condensation occurs. Infrared spectroscopic investigations of adsorbed pyridine indicate an enhanced acidity of the silanol triads, suggesting important implications in catalysis
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A Stable Silanol Triad in the Zeolite Catalyst SSZ-70.
Nests of three silanol groups are located on the internal pore surface of calcined zeolite SSZ-70. 2D 1 H double/triple-quantum single-quantum correlation NMR experiments enable a rigorous identification of these silanol triad nests. They reveal a close proximity to the structure directing agent (SDA), that is, N,N'-diisobutyl imidazolium cations, in the as-synthesized material, in which the defects are negatively charged (silanol dyad plus one charged SiO- siloxy group) for charge balance. It is inferred that ring strain prevents the condensation of silanol groups upon calcination and removal of the SDA to avoid energetically unfavorable three-rings. In contrast, tetrad nests, created by boron extraction from B-SSZ-70 at various other locations, are not stable and silanol condensation occurs. Infrared spectroscopic investigations of adsorbed pyridine indicate an enhanced acidity of the silanol triads, suggesting important implications in catalysis