31,559 research outputs found
Structure and dielectric properties of polar fluids with extended dipoles: results from numerical simulations
The strengths and short-comings of the point-dipole model for polar fluids of
spherical molecules are illustrated by considering the physically more relevant
case of extended dipoles formed by two opposite charges separated by a
distance (dipole moment ). Extensive Molecular Dynamics
simulations on a high density dipolar fluid are used to analyse the dependence
of the pair structure, dielectric constant \eps and dynamics as a function of
the ratio (\sig is the molecular diameter), for a fixed dipole
moment . The point dipole model is found to agree well with the extended
dipole model up to d/\sig \simeq 0.3. Beyond that ratio, \eps shows a
non-trivial variation with d/\sig. When d/\sig>0.6, a transition is
observed towards a hexagonal columnar phase; the corresponding value of the
dipole moment, \mu^2/\sig^3 k T=3, is found to be substantially lower than
the value of the point dipole required to drive a similar transition.Comment: 10 pages, 11 figures; Paper submitted to Molecular Physic
Microscopic expressions for the thermodynamic temperature
We show that arbitrary phase space vector fields can be used to generate
phase functions whose ensemble averages give the thermodynamic temperature. We
describe conditions for the validity of these functions in periodic boundary
systems and the Molecular Dynamics (MD) ensemble, and test them with a
short-ranged potential MD simulation.Comment: 21 pages, 2 figures, Revtex. Submitted to Phys. Rev.
Modelling bacterial behaviour close to a no-slip plane boundary: the influence of bacterial geometry
We describe a boundary-element method used to model the hydrodynamics of a bacterium propelled by a single helical flagellum. Using this model, we optimize the power efficiency of swimming with respect to cell body and flagellum geometrical parameters, and find that optima for swimming in unbounded fluid and near a no-slip plane boundary are nearly indistinguishable. We also consider the novel optimization objective of torque efficiency and find a very different optimal shape. Excluding effects such as Brownian motion and electrostatic interactions, it is demonstrated that hydrodynamic forces may trap the bacterium in a stable, circular orbit near the boundary, leading to the empirically observable surface accumulation of bacteria. Furthermore, the details and even the existence of this stable orbit depend on geometrical parameters of the bacterium, as described in this article. These results shed some light on the phenomenon of surface accumulation of micro-organisms and offer hydrodynamic explanations as to why some bacteria may accumulate more readily than others based on morphology
Infrared Quasi Fixed Points and Mass Predictions in the MSSM II: Large tan(beta) Scenario
We consider the infrared quasi fixed point solutions of the renormalization
group equations for the Yukawa couplings and soft supersymmetry breaking
parameters in the MSSM in the \underline{large } regime. The
existence of IR quasi fixed points together with the values of gauge couplings,
third generation quarks, lepton and Z-boson masses allows one to predict masses
of the Higgs bosons and SUSY particles as functions of the only free parameter,
, or the gluino mass. The lightest Higgs boson mass for TeV is found to be GeV for and
GeV for .Comment: 15 pages, LateX file with 4 eps figures, corrected numbers, new
column in table, last versio
Limit cycles in the presence of convection, a travelling wave analysis
We consider a diffusion model with limit cycle reaction functions, in the
presence of convection. We select a set of functions derived from a realistic
reaction model: the Schnakenberg equations. This resultant form is
unsymmetrical. We find a transformation which maps the irregular equations into
model form. Next we transform the dependent variables into polar form. From
here, a travelling wave analysis is performed on the radial variable. Results
are complex, but we make some simple estimates.
We carry out numerical experiments to test our analysis. An initial `knock'
starts the propagation of pattern. The speed of the travelling wave is not
quite as expected. We investigate further. The system demonstrates distinctly
different behaviour to the left and the right. We explain how this phenomenon
occurs by examining the underlying behaviour.Comment: 20 pages, 5 figure
Ornstein-Zernike equation and Percus-Yevick theory for molecular crystals
We derive the Ornstein-Zernike equation for molecular crystals of axially
symmetric particles and apply the Percus-Yevick approximation to this system.
The one-particle orientational distribution function has a nontrivial
dependence on the orientation and is needed as an input. Despite some
differences, the Ornstein-Zernike equation for molecular crystals has a similar
structure as for liquids. We solve both equations for hard ellipsoids on a sc
lattice. Compared to molecular liquids, the tensorial orientational correlators
exhibit less structure. However, depending on the lengths a and b of the
rotation axis and the perpendicular axes of the ellipsoids, different behavior
is found. For oblate and prolate ellipsoids with b >= 0.35 (units of the
lattice constant), damped oscillations in distinct directions of direct space
occur for some correlators. They manifest themselves in some correlators in
reciprocal space as a maximum at the Brillouin zone edge, accompanied by maxima
at the zone center for other correlators. The oscillations indicate alternating
orientational fluctuations, while the maxima at the zone center originate from
nematic-like orientational fluctuations. For a <= 2.5 and b <= 0.35, the
oscillations are weaker. For a >= 3.0 and b <= 0.35, no oscillations occur any
longer. For many of the correlators in reciprocal space, an increase of a at
fixed b leads to a divergence at the zone center q = 0, consistent with
nematic-like long range fluctuations, and for some oblate and prolate systems
with b ~< 1.0 a simultaneous tendency to divergence of few other correlators at
the zone edge is observed. Comparison with correlators from MC simulations
shows satisfactory agreement. We also obtain a phase boundary for
order-disorder transitions.Comment: 20 pages, 13 figures, submitted to Phys. Rev.
Entropy-induced smectic phases in rod-coil copolymers
We present a self-consistent field theory (SCFT) of semiflexible (wormlike)
diblock copolymers, each consisting of a rigid and a flexible part. The
segments of the polymers are otherwise identical, in particular with regard to
their interactions, which are taken to be of an Onsager excluded-volume type.
The theory is developed in a general three-dimensional form, as well as in a
simpler one-dimensional version. Using the latter, we demonstrate that the
theory predicts the formation of a partial-bilayer smectic-A phase in this
system, as shown by profiles of the local density and orientational
distribution functions. The phase diagram of the system, which includes the
isotropic and nematic phases, is obtained in terms of the mean density and
rigid-rod fraction of each molecule. The nematic-smectic transition is found to
be second order. Since the smectic phase is induced solely by the difference in
the rigidities, the onset of smectic ordering is shown to be an entropic effect
and therefore does not have to rely on additional Flory-Huggins-type repulsive
interactions between unlike chain segments. These findings are compared with
other recent SCFT studies of similar copolymer models and with computer
simulations of several molecular models.Comment: 13 pages, 8 figure
Recommended from our members
What motivates academic dishonesty in students? A reinforcement sensitivity theory explanation
BACKGROUND: Academic dishonesty (AD) is an increasing challenge for universities worldwide. The rise of the Internet has further increased opportunities for students to cheat.
AIMS: In this study, we investigate the role of personality traits defined within Reinforcement Sensitivity Theory (RST) as potential determinants of AD. RST defines behaviour as resulting from approach (Reward Interest/reactivity, goal-drive, and Impulsivity) and avoidance (behavioural inhibition and Fight-Flight-Freeze) motivations. We further consider the role of deep, surface, or achieving study motivations in mediating/moderating the relationship between personality and AD.
SAMPLE: A sample of UK undergraduates (N = 240).
METHOD: All participants completed the RST Personality Questionnaire, a short-form version of the study process questionnaire and a measure of engagement in AD, its perceived prevalence, and seriousness.
RESULTS: Results showed that RST traits account for additional variance in AD. Mediation analysis suggested that GDP predicted dishonesty indirectly via a surface study approach while the indirect effect via deep study processes suggested dishonesty was not likely. Likelihood of engagement in AD was positively associated with personality traits reflecting Impulsivity and Fight-Flight-Freeze behaviours. Surface study motivation moderated the Impulsivity effect and achieving motivation the FFFS effect such that cheating was even more likely when high levels of these processes were used.
CONCLUSIONS: The findings suggest that motivational personality traits defined within RST can explain variance in the likelihood of engaging in dishonest academic behaviours
OH Zeeman Magnetic Field Detections Toward Five Supernova Remnants Using the VLA
We have observed the OH (1720 MHz) line in five galactic SNRs with the VLA to
measure their magnetic field strengths using the Zeeman effect. We detected all
12 of the bright ( mJy) OH (1720 MHz) masers previously detected
by Frail et al. (1996) and Green et al. (1997) and measured significant
magnetic fields (i.e. ) in ten of them. Assuming that the
``thermal'' Zeeman equation can be used to estimate for OH
masers, our estimated fields range from 0.2 to 2 mG. These magnetic field
strengths are consistent with the hypothesis that ambient molecular cloud
magnetic fields are compressed via the SNR shock to the observed values.
Magnetic fields of this magnitude exert a considerable influence on the
properties of the cloud with the magnetic pressures ( erg
cm) exceeding the pressure in the ISM or even the thermal pressure of
the hot gas interior to the remnant. This study brings the number of galactic
SNRs with OH (1720 MHz) Zeeman detections to ten.Comment: 23 pages, 14 figures, accepted to ApJ, for higher resolution images
of Figs 4,11, and 12 see http://www.pa.uky.edu/~brogan/brog_publ.htm
- …