Enrichment of the r-process Element Europium in the Galactic Halo

We investigate the enrichment of europium, as a representative of r-process elements, in the Galactic halo. In present chemical evolution models, stars are assumed to be formed through shock processes by supernovae (SNe). The enrichment of the interstellar medium is calculated by a one-zone approach. The observed large dispersions in [Eu/Fe] for halo stars, converging with increasing metallicity, can be explained with our models. In addition, the mass range of SNe for the {\it r}-process site is constrained to be either stars of $8-10 M_\odot$ or $\gtrsim 30 M_\odot$.Comment: 5 pages (including 4 figures), LaTeX, uses aas2pp4.sty, accepted to ApJ

Encapsulation and characterization of proton-bound amine homodimers in a water-soluble, self-assembled supramolecular host

Cyclic amines can be encapsulated in a water-soluble self-assembled supramolecular host upon protonation. The hydrogen-bonding ability of the cyclic amines, as well as the reduced degrees of rotational freedom, allows for the formation of proton-bound homodimers inside of the assembly that are otherwise not observable in aqueous solution. The generality of homodimer formation was explored with small N-alkyl aziridines, azetidines, pyrrolidines, and piperidines. Proton-bound homodimer formation is observed for N-alkylaziridines (R = methyl, isopropyl, tert-butyl), N-alkylazetidines (R = isopropyl, tert-butyl), and N-methylpyrrolidine. At high concentration, formation of a proton-bound homotrimer is observed in the case of N-methylaziridine. The homodimers stay intact inside the assembly over a large concentration range, thereby suggesting cooperative encapsulation. Both G3(MP2)B3 and G3B3 calculations of the proton-bound homodimers were used to investigate the enthalpy of the hydrogen bond in the proton-bound homodimers and suggest that the enthalpic gain upon formation of the proton-bound homodimers may drive guest encapsulation