Interchain photogeneration of charged solitons in trans-(CH)x

Journal ArticleIn a recent Letter1 Rothberg, Jedju, Etemad, and Baker (RJEB) used a novel photoinduced-absorption (PA) technique to study charged-soliton (S ?) dynamics in trans-(CH)X with picosecond resolution by measuring transient PA at 0.45 eV. Both intrachain and interchain photogeneration of S ? are reported. The former process occurs instantaneously, while the latter process is delayed by about 30 ps and was interpreted1 as neutral soliton (S?) to S ? conversion. In this Comment we would like to experimentally support and complement RJEB's measurements and to further discuss the interchain photogeneration process

Effective group dispersion of terahertz quantum-cascade lasers

Terahertz (THz) quantum-cascade lasers (QCLs) are based on complex semiconductor heterostructures, in which the optical gain is generated by intersubband transitions. Using the spacing of the laser modes in the emission spectra, we have determined the effective group refractive index for more than one hundred THz QCLs of the hybrid design with Fabry-Pérot resonators based on single-plasmon waveguides. The experimentally obtained values of for emission frequencies between 2.5 and 5.6 THz generally follow the trend of derived from electromagnetic simulations. However, for a certain number of QCLs, the experimental values of exhibit a rather large deviation from the general trend and the simulation results. From a thorough analysis, we conclude that differences in the optical gain/loss spectra are responsible for this deviation, which lead to a modification of the dispersion in the active region and consequently to altered values of. The analysis also provides evidence that these differences in the gain/loss spectra originate from both, the details of the design and the gain broadening due to interface roughness. © 2020 The Author(s). Published by IOP Publishing Ltd

Terahertz quantum-cascade lasers as high-power and wideband, gapless sources for spectroscopy

Terahertz (THz) quantum-cascade lasers (QCLs) are powerful radiation sources for high-resolution and high-sensitivity spectroscopy with a discrete spectrum between 2 and 5 THz as well as a continuous coverage of several GHz. However, for many applications, a radiation source with a continuous coverage of a substantially larger frequency range is required. We employed a multi-mode THz QCL operated with a fast ramped injection current, which leads to a collective tuning of equally-spaced Fabry-Pérot laser modes exceeding their separation. A continuous coverage over 72 GHz at about 4.7 THz was achieved. We demonstrate that the QCL is superior to conventional sources used in Fourier transform infrared spectroscopy in terms of the signal-to-noise ratio as well as the dynamic range by one to two orders of magnitude. Our results pave the way for versatile THz spectroscopic systems with unprecedented resolution and sensitivity across a wide frequency range