2 research outputs found
Nickel-Catalyzed Coupling of Azoles with Aromatic Nitriles
This
manuscript describes the Ni-catalyzed coupling of azoles with
aromatic nitriles. The use of BPh<sub>3</sub> promotes these arylations
with electronically diverse azoles and benzonitriles. While the nickel
catalyst is necessary for the arylations of phenyl oxazoles, arylation
of benzoxazoles with some nitriles affords the arylated products even
in the absence of the Ni catalyst albeit in lower yield than the catalyzed
process. The Ni-catalyzed process exhibits higher rates and a broader
scope than the uncatalyzed transformation
Nickel-Catalyzed Coupling of Azoles with Aromatic Nitriles
This
manuscript describes the Ni-catalyzed coupling of azoles with
aromatic nitriles. The use of BPh<sub>3</sub> promotes these arylations
with electronically diverse azoles and benzonitriles. While the nickel
catalyst is necessary for the arylations of phenyl oxazoles, arylation
of benzoxazoles with some nitriles affords the arylated products even
in the absence of the Ni catalyst albeit in lower yield than the catalyzed
process. The Ni-catalyzed process exhibits higher rates and a broader
scope than the uncatalyzed transformation