123 research outputs found
Sign change of the Grueneisen parameter and magnetocaloric effect near quantum critical points
We consider the Grueneisen parameter and the magnetocaloric effect near a
pressure and magnetic field controlled quantum critical point, respectively.
Generically, the Grueneisen parameter (and the thermal expansion) displays a
characteristic sign change close to the quantum-critical point signaling an
accumulation of entropy. If the quantum critical point is the endpoint of a
line of finite temperature phase transitions, T_c \propto (p_c-p)^Psi, then we
obtain for p<p_c, (1) a characteristic increase \Gamma \sim T^{-1/(\nu z)} of
the Grueneisen parameter Gamma for T>T_c, (2) a sign change in the Ginzburg
regime of the classical transition, (3) possibly a peak at T_c, (4) a second
increase Gamma \sim -T^{-1/(nu z)} below T_c for systems above the upper
critical dimension and (5) a saturation of Gamma \propto 1/(p_c-p). We argue
that due to the characteristic divergencies and sign changes the thermal
expansion, the Grueneisen parameter and magnetocaloric effect are excellent
tools to detect and identify putative quantum critical points.Comment: 10 pages, 7 figures; final version, only minor change
Universally diverging Grueneisen parameter and the magnetocaloric effect close to quantum critical points
At a generic quantum critical point, the thermal expansion is more
singular than the specific heat . Consequently, the "Gr\"uneisen ratio'',
\GE=\alpha/c_p, diverges. When scaling applies, \GE \sim T^{-1/(\nu z)} at
the critical pressure , providing a means to measure the scaling
dimension of the most relevant operator that pressure couples to; in the
alternative limit and , \GE \sim \frac{1}{p-p_c} with a
prefactor that is, up to the molar volume, a simple {\it universal} combination
of critical exponents. For a magnetic-field driven transition, similar
relations hold for the magnetocaloric effect .
Finally, we determine the corrections to scaling in a class of metallic quantum
critical points.Comment: 4 pages, 1 figure; general discussion on how the Grueneisen exponent
measures the scaling dimension of the most relevant operator at any QCP is
expande
Rejuvenation of metallic glasses by non-affine thermal strain.
When a spatially uniform temperature change is imposed on a solid with more than one phase, or on a polycrystal of a single, non-cubic phase (showing anisotropic expansion-contraction), the resulting thermal strain is inhomogeneous (non-affine). Thermal cycling induces internal stresses, leading to structural and property changes that are usually deleterious. Glasses are the solids that form on cooling a liquid if crystallization is avoided--they might be considered the ultimate, uniform solids, without the microstructural features and defects associated with polycrystals. Here we explore the effects of cryogenic thermal cycling on glasses, specifically metallic glasses. We show that, contrary to the null effect expected from uniformity, thermal cycling induces rejuvenation, reaching less relaxed states of higher energy. We interpret these findings in the context that the dynamics in liquids become heterogeneous on cooling towards the glass transition, and that there may be consequent heterogeneities in the resulting glasses. For example, the vibrational dynamics of glassy silica at long wavelengths are those of an elastic continuum, but at wavelengths less than approximately three nanometres the vibrational dynamics are similar to those of a polycrystal with anisotropic grains. Thermal cycling of metallic glasses is easily applied, and gives improvements in compressive plasticity. The fact that such effects can be achieved is attributed to intrinsic non-uniformity of the glass structure, giving a non-uniform coefficient of thermal expansion. While metallic glasses may be particularly suitable for thermal cycling, the non-affine nature of strains in glasses in general deserves further study, whether they are induced by applied stresses or by temperature change.This research was supported by the World Premier International Research Center Initiative (WPI), MEXT, Japan, by NSF China and MOST 973 China, and by the Engineering and the Engineering and Physical Sciences Research Council, UK (Materials World Network project). Y.H.S. acknowledges support from a China Scholarship Council (CSC) scholarship.This is the author accepted manuscript. The final version is available from Nature Publishing Group via http://dx.doi.org/10.1038/nature1467
Organisationskultur. Eine Konkretisierung aus systemtheoretischer Perspektive
Kühl S. Organisationskultur. Eine Konkretisierung aus systemtheoretischer Perspektive. Managementforschung. 2018;28(1):7-35.Die Bestimmung des Verhältnisses von Informalität und Organisationskultur bereitet in der Organisationstheorie Schwierigkeiten. Das liegt daran, dass der Begriff Informalität häufig stillschweigend durch den Begriff der Organisationskultur ersetzt wurde, ohne dass dafür eine präzise, abgrenzungsscharfe Definition vorgenommen worden wäre. Unter Rückgriff auf Ãœberlegungen von Dario RodrÃguez argumentiert dieser Artikel, dass die beiden Begriffe Organisationskultur und Informalität das gleiche Phänomen bezeichnen: die nichtentschiedenen Entscheidungsprämissen einer Organisation. Dabei wird systematisch zwischen „unentscheidbaren Entscheidungsprämissen“ und „prinzipiell entscheidbaren, aber nicht entschiedenen Entscheidungsprämissen“ unterschieden. Es wird gezeigt, wie sich mit einer präzisen Bestimmung über das Konzept der Entscheidungsprämissen Ordnung in die „wilden Merkmallisten“ der Literatur sowohl über Informalität als auch Organisationskultur bringen lässt und empirische Phänomene genauer erfasst werden können
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