38 research outputs found

    A qualitative exploration of attitudes towards the use of outcome measures in child and adolescent mental health services

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    The aim of the present research was to explore clinician attitudes to outcome measures and, in particular, the facilitators and barriers to implementing outcome measures. An up-to-date exploration of clinician attitudes is especially needed in the context of recent policies on the implementation of outcome measures in child and adolescent mental health services (CAMHS), and because evidence suggests that there is a disparity between policy recommendations and the use of outcome measures in clinical practice. Semi-structured interviews were conducted with nine CAMHS clinicians from a Mental Health Trust in South London. Two levels of implementation emerged from the analysis: (1) the service level, regarding the implementation of outcome measures across a service to inform service improvement and (2) the session level, regarding the implementation of outcome measures within individual clinical sessions. The present research described training and ongoing support as a crucial facilitator of use at both service and session levels. This included help overcoming local contextual barriers, such as resources, information systems and administrative processes. The research showed that a balance is needed between a mandatory and uniform approach across a service and providing clinicians with support to use outcome measures with all service users for whom they are appropriate

    Bulk and Interfacial Shear Thinning of Immiscible Polymers

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    Nonequilibrium molecular dynamics simulations are used to study the shear thinning behavior of immiscible symmetric polymer blends. The phase separated polymers are subjected to a simple shear flow imposed by moving a wall parallel to the fluid-fluid interface. The viscosity begins to shear thin at much lower rates in the bulk than at the interface. The entire shear rate dependence of the interfacial viscosity is consistent with a shorter effective chain length s∗s^* that also describes the width of the interface. This s∗s^* is independent of chain length NN and is a function only of the degree of immiscibility of the two polymers. Changes in polymer conformation are studied as a function of position and shear rate.Shear thinning correlates more closely with a decrease in the component of the radius of gyration along the velocity gradient than with elongation along the flow. At the interface, this contraction of chains is independent of NN and consistent with the bulk behavior for chains of length s∗s^*. The distribution of conformational changes along chains is also studied. Central regions begin to stretch at a shear rate that decreases with increasing NN, while shear induced changes at the ends of chains are independent of NN.Comment: 8 pages, 8 figure

    Shear-banding in a lyotropic lamellar phase, Part 2: Temporal fluctuations

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    We analyze the temporal fluctuations of the flow field associated to a shear-induced transition in a lyotropic lamellar phase: the layering transition of the onion texture. In the first part of this work [Salmon et al., submitted to Phys. Rev. E], we have evidenced banded flows at the onset of this shear-induced transition which are well accounted for by the classical picture of shear-banding. In the present paper, we focus on the temporal fluctuations of the flow field recorded in the coexistence domain. These striking dynamics are very slow (100--1000s) and cannot be due to external mechanical noise. Using velocimetry coupled to structural measurements, we show that these fluctuations are due to a motion of the interface separating the two differently sheared bands. Such a motion seems to be governed by the fluctuations of σ⋆\sigma^\star, the local stress at the interface between the two bands. Our results thus provide more evidence for the relevance of the classical mechanical approach of shear-banding even if the mechanism leading to the fluctuations of σ⋆\sigma^\star remains unclear

    Interfaces in Diblocks: A Study of Miktoarm Star Copolymers

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    We study ABn_n miktoarm star block copolymers in the strong segregation limit, focussing on the role that the AB interface plays in determining the phase behavior. We develop an extension of the kinked-path approach which allows us to explore the energetic dependence on interfacial shape. We consider a one-parameter family of interfaces to study the columnar to lamellar transition in asymmetric stars. We compare with recent experimental results. We discuss the stability of the A15 lattice of sphere-like micelles in the context of interfacial energy minimization. We corroborate our theory by implementing a numerically exact self-consistent field theory to probe the phase diagram and the shape of the AB interface.Comment: 12 pages, 11 included figure

    Shear-banding in a lyotropic lamellar phase, Part 1: Time-averaged velocity profiles

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    Using velocity profile measurements based on dynamic light scattering and coupled to structural and rheological measurements in a Couette cell, we present evidences for a shear-banding scenario in the shear flow of the onion texture of a lyotropic lamellar phase. Time-averaged measurements clearly show the presence of structural shear-banding in the vicinity of a shear-induced transition, associated to the nucleation and growth of a highly sheared band in the flow. Our experiments also reveal the presence of slip at the walls of the Couette cell. Using a simple mechanical approach, we demonstrate that our data confirms the classical assumption of the shear-banding picture, in which the interface between bands lies at a given stress σ⋆\sigma^\star. We also outline the presence of large temporal fluctuations of the flow field, which are the subject of the second part of this paper [Salmon {\it et al.}, submitted to Phys. Rev. E]

    Interplay between elastic instabilities and shear-banding: three categories of Taylor–Couette flows and beyond

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    In the past twenty years, shear-banding flows have been probed by various techniques, such as rheometry, velocimetry and flow birefringence. In micellar solutions, many of the data collected exhibit unexplained spatiotemporal fluctuations. Recently, it has been suggested that those fluctuations originate from a purely elastic instability of the shear-banding flow. In cylindrical Couette geometry, the instability is reminiscent of the Taylor-like instability observed in viscoelastic polymer solutions. The criterion for purely elastic Taylor–Couette instability adapted to shear-banding flows suggested three categories of shear-banding depending on their stability. In the present study, we report on a large set of experimental data which demonstrates the existence of the three categories of shear-banding flows in various surfactant solutions. Consistent with theoretical predictions, increases in the surfactant concentration or in the curvature of the geometry destabilize the flow, whereas an increase in temperature stabilizes the flow. However, experiments also exhibit some interesting behaviors going beyond the purely elastic instability criterion.National Science Foundation (U.S.). Graduate Research Fellowship Progra
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