Developing novel heat treatments for automotive spring steels: Phase transformations, microstructure and performance

This Ph.D. thesis investigates the substitution of quenching and tempering treat-ments by isothermal bainitic treatments in automotive spring production. An isothermal bainitic treatment has benefits mainly in terms of energy savings, but it can also prevent quench cracking, distortion and residual stresses, commonly found in quenched and tempered components. A medium carbon low alloy spring steel commonly employed in automotive spring production is used for this research. The study focuses on the microstructure formation and its effect on the performance of a spring steel component.MSE-

Bainite Formation in Medium-Carbon Low-Silicon Spring Steels Accounting for Chemical Segregation

In this paper, the effect of chemical inhomogeneity on the isothermal bainite formation is investigated in medium-carbon low-silicon spring steel by dilatometry and microscopy. The analysis of the microstructure at different times during transformation shows that chemical segregation of substitutional alloying elements resulting from casting strongly affects the bainite formation by retarding the transformation kinetics and limiting the maximum achievable bainite fraction. During holding at temperatures close to and above the martensite start temperature, a homogeneous lower bainitic microstructure can be eventually obtained, whereas at higher temperatures, incomplete bainitic reaction is evident. It was also found that at the early stages of the transformation, differences in the bainite formation kinetics, due to local inhomogeneities in Cr and Mn concentration, result in retardation of the growth of bainite in the high Mn and Cr concentration regions. The calculated difference in driving force for nucleation between the enriched and the depleted areas is not by itself sufficient to explain the microstructures obtained and thus significant influence of growth on bainite formation is observed. Particularly, it was calculated and experimentally observed that Cr partitions in the carbides in the high Mn, Cr regions during the isothermal treatment, limiting the transformation kinetics.Materials Science and EngineeringMechanical, Maritime and Materials Engineerin

Microstructure and mechanical properties of medium carbon steel deposits obtained via Wire and Arc Additive Manufacturing using metal-cored wire

Wire and arc additive manufacturing (WAAM) is a 3D metal printing technique based on the arc welding process. WAAM is considered to be suitable to produce large-scale metallic components by combining high deposition rate and low cost. WAAM uses conventional welding consumable wires as feedstock. In some applications of steel components, one-off spare parts need to be made on demand from steel grades that do not exist as commercial welding wire. In this research, a specifically produced medium carbon steel (Grade XC-45), metal-cored wire, equivalent to a composition of XC-45 forged material, was deposited with WAAM to produce a thin wall. The specific composition was chosen because it is of particular interest for the on-demand production of heavily loaded aerospace components. The microstructure, hardness, and tensile strength of the deposited part were studied. Fractography studies were conducted on the tested specimens. Due to the multiple thermal cycles during the building process, local variations in microstructural features were evident. Nevertheless, the hardness of the part was relatively uniform from the top to the bottom of the construct. The mean yield/ultimate tensile strength was 620 MPa/817 MPa in the horizontal (deposition) direction and 580 MPa/615 MPa in the vertical (build) direction, respectively. The elongation in both directions showed a significant difference, i.e., 6.4% in the horizontal direction and 11% in the vertical direction. Finally, from the dimple-like structures observed in the fractography study, a ductile fracture mode was determined. Furthermore, a comparison of mechanical properties between WAAM and traditionally processed XC-45, such as casting, forging, and cold rolling was conducted. The results show a more uniform hardness distribution and higher tensile strength of the WAAM deposit using the designed metal-cored wires.(OLD) MSE-

Failure Mechanisms of Mechanically and Thermally Produced Holes in High-Strength Low-Alloy Steel Plates Subjected to Fatigue Loading

High-strength low-alloy steels (HSLA) are gaining popularity in structural applications in which weight reduction is of interest, such as heavy duty machinery, bridges, and offshore structures. Since the fatigue behavior of welds appears to be almost independent of the base material and displays little improvement when more resistant steel grades are employed, the use of bolted joints is an alternative joining technique which can lead to an increased fatigue performance of HSLA connections. Manufacturing a hole to allocate the fastener elements is an unavoidable step in bolted elements and it might induce defects and tensile residual stresses that could affect its fatigue behavior. This paper studies and compares several mechanical (punching, drilling, and waterjet-cut) and thermal (plasma and laser-cut) hole-making procedures in HSLA structural plates. A series of 63 uniaxial fatigue tests was completed, covering three HSLA grades produced by thermomechanically controlled process (TMCP) with yield strength ranging from 500 to 960 MPa. Samples were tested at single load level, which was considered representative in HSLA typical applications, according to the input received from end users. The manufactured holes were examined by means of optical and electron microscopy, 3D point measurement, micro hardness tests, X-ray diffraction, and electron backscatter diffraction (EBSD). The results give insight on cutting processes in HSLA and indicate how the fatigue failure is dominated by macro defects rather than by the steel grade. It was shown that the higher yield strength of the HSLA grades did not lead to a higher fatigue life. Best fatigue results were achieved with laser-cut specimens while punched samples withstood the lowest amount of cycles.(OLD) MSE-

The glass swing: a vector active structure made of glass struts and 3D-printed steel nodes

The majority of glass used in load-bearing structures is as planar elements. Some projects exist that use linear glass elements. This paper discusses in broad terms the design, engineering, and fabrication of a unique vector active glass structure consisting of glass bundles and partly printed steel connections. A structure was conceived that utilizes the glass bundles in a way that can be directly experienced by the users: a swing. To create a non-standard form for the swing, a structural optimization procedure was used. To realize the structure, a novel steel node was developed and produced using an additive manufacturing technique in steel. These novel applications have made the project innovation heavy, particularly considering the limited timeframe for its development and construction. Description is given of the several optimization techniques incorporated in the digital process, the assembly and testing of the glass bundles, and the manufacturing of the steel nodes by Wire and Arc Additive Manufacturing.Structural Design & MechanicsApplied Mechanics(OLD) MSE-

Atomic-scale investigations of isothermally formed bainite microstructures in 51CrV4 spring steel

Atomic-scale investigation was performed on 51CrV4 steel, isothermally held at different temperatures within the bainitic temperature range. Transmission electron microscopy (TEM) analysis revealed three different morphologies: lower, upper, and inverse bainite. Atom Probe Tomography (APT) analysis of lower bainite revealed cementite particles, which showed no evidence of partitioning of substitutional elements; only carbon partitioned into cementite to the equilibrium value. Carbon in the bainitic ferrite was found to segregate at dislocations and to form Cottrell atmospheres. The concentration of carbon remaining in solution measured by APT was more than expected at the equilibrium. Upper bainite contained cementite as well. Chromium and manganese were found to redistribute at the cementite-austenite interface and the concentration of carbon in the ferritic matrix was found to be lower than the one measured in the case of lower bainite. After isothermal treatments close to the bainite start temperature, another austenite decomposition product was found at locations with high concentration of Mn and Cr, resembling inverse bainite. Site-specific APT analysis of the inverse bainite reveals significant partitioning of manganese and chromium at the carbides and at the ferrite/martensite interfaces, unlike what is found at isothermal transformation products at lower temperatures.(OLD) MSE-5(OLD) MSE-3Materials Science and Engineerin