9 research outputs found
Desorption of hydrocarbon chains by association with ionic and nonionic surfactants under flow as a mechanism for enhanced oil recovery
The need to extract oil from wells where it is embedded on the surfaces of
rocks has led to the development of new and improved enhanced oil recovery
techniques. One of those is the injection of surfactants with water vapor,
which promotes desorption of oil that can then be extracted using pumps, as the
surfactants encapsulate the oil in foams. However, the mechanisms that lead to
the optimal desorption of oil and the best type of surfactants to carry out
desorption are not well known yet, which warrants the need to carry out basic
research on this topic. In this work, we report non equilibrium dissipative
particle dynamics simulations of model surfactants and oil molecules adsorbed
on surfaces, with the purpose of studying the efficiency of the surfactants to
desorb hydrocarbon chains, that are found adsorbed over flat surfaces. The
model surfactants studied correspond to nonionic and cationic surfactants, and
the hydrocarbon desorption is studied as a function of surfactant concentration
under increasing Poiseuille flow. We obtain various hydrocarbon desorption
isotherms for every model of surfactant proposed, under flow. Nonionic
surfactants are found to be the most effective to desorb oil and the mechanisms
that lead to this phenomenon are presented and discussed.Comment: 10 figures; to appear in Scientific Report
Importance of molecular interactions in colloidal dispersions
We review briefly the concept of colloidal dispersions, their general properties, and some of their most important applications, as well as the basic molecular interactions that give rise to their properties in equilibrium. Similarly, we revisit Brownian motion and hydrodynamic interactions associated with the concept of viscosity of colloidal dispersion. It is argued that the use of modern research tools, such as computer simulations, allows one to predict accurately some macroscopically measurable properties by solving relatively simple models of molecular interactions for a large number of particles. Lastly, as a case study, we report the prediction of rheological properties of polymer brushes using state-of-the-art, coarse-grained computer simulations, which are in excellent agreement with experiments. 漏 2015 R. L贸pez-Esparza et al