21 research outputs found

    Complexation of lithium and sodium cations with B-phosphorylate ethers, modelling terminal groups of organophosphorus podands. An experimental and theoretical study

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    The organophosphorus compounds o-Ph2P(O)C6H4OCH3 and Ph2P(O)C2H4OCH3, which are analogs of podands' terminal groups, have been synthesized. The thermodynamic characteristics of their complexation with LiNCS and NaNCS in acetonitrile were obtained by calorimetry. Molecular mechanics calculations on M+ L complexes with different stoichiometries M+:L = 1:1, 1:2 and 1:4 (M+ = Li+, Na+) were performed, as well as on their solvates with a limited number of MeCN molecules. It has been shown that the experimental data could be explained by taking into account both the specific features of the complex structure and the solvent effects. The possibility of the application of additive schemes in the investigation of the complexation of polydentate molecules is discussed

    TO THE QUESTION OF TYPOLOGIZATION OF THE RUSSIAN REGIONS

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    The article specifies the method of typologization of the Russian regions as the subjects of the Russian Federation. An attempt is made to update the existing scientific and practical model of classification of regions of modern Russia. The features of socio-economic and political criteria in assessing the status and resource capabilities of the region are emphasized. The article describes the differences in determining the ratings of Russian regions in the context of assessing the effectiveness of regional governments and in determining the types of relevant regions
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