Phase state of matter during metal and binary alloy conductor dispersion by a pulse of current

The paper covers the evolution of the liquid phase formed under heating metal conductors by a pulse of current with the density of [j=~106-:106] A/cm{2}. Following the theoretical assessment and experimental data, it was shown that the two-phase state (condensed phase - gas) during the early expansion of products of electric explosion of wires can be caused by the development of density fluctuations in the liquid phase of the metal. The density fluctuation formation is caused by the destruction of liquid phase clusters of short-range order. The study demonstrated the absence of the complete transition of the semiconductor matter into gas after the injection of energy exceeding the energy of sublimation E s

Synthesis of low-size flower-like AlOOH structures

Al/Cu, Al/Zn, and Al/Fe bimetallic nanoparticles have been obtained using the method of simultaneous electrical explosion of metal pairs in an argon atmosphere. The nanoparticles are chemically active and interact with water at 60°C forming flower-like hierarchical porous structures with a high specific surface area. As the Al/Cu nanopowder is oxidized with water, flower-like pseudoboehmite composite structures are formed with the size of under 1.0 [mu]m; structurally heterogeneous electron-dense spherical inclusions of unreacted metal copper and intermetallides are identified inside them. Al/Fe product transformations are presented by the flower-like pseudoboehmite surrounded by lamellar structures enriched with ferric oxides. Al/Zn nanoparticles react with water, forming the flower-like pseudoboehmite and mainly hexagonal zinc oxide laminae. The composite particles obtained can be used as antibacterial agents in manufacturing medical supplies

Investigation of the hemostatic action of low-dimensional electropositive structures

The paper studies the hemostatic action of the fibrous material containing agglomerates of low-dimensional electropositive structures of aluminum oxyhydroxide. The time of parenchymatous bleeding is found to decrease from 292.5 s at spontaneous hemostasis to 177.8 s with the attached fibrous material and to 215.7 s with gauze. The mixed mechanism of the hemostatic action is possible, i.e. along with the hygroscopic mechanism, plateletes aggregate due to destruction of a diffuse part of the double electrical layer in contact with low-dimensional electropositive structures of aluminum oxyhydroxide

Три новых чужеродных вида из семейства Chenopodiaceae во флоре России

Three new alien species of Chenopodiaceae s. str. (Amaranthaceae s. l.) are reported for the flora of Russia, the North American Chenopodiastrum simplex and Australian Dysphania carinata and D. pumilio. The identification of the specimens of Chenopodiastrum simplex from Moschny Island in the Leningrad Region (European Russia) was confirmed using both morphological and phylogenetic analyses. Morphologically, C. simplex is very similar to C. badachschanicum having the same fruit and seed characters. A single specimen of Dysphania carinata from Primorye Territory (the Russian Far East) was previously identified as Chenopodium pumilio (≡ Dysphania pumilio) incorrectly. Only recently, the latter species has been indeed found in Beslan town, Republic of North Ossetia - Alania (the North Caucasus). For each species, the possible degree of naturalization is discussed

Novel of core-shell AlOOH/Cu nanostructures: Synthesis, characterization, antimicrobial activity and in vitro toxicity in Neuro-2a cells

Core-shell micro/nanostructures were fabricated by the reaction of Al/Cu bimetallic nanoparticles with water. Al/Cu nanoparticles have been obtained using the method of simultaneous electrical explosion of a pair of the corresponding metal wires in an argon atmosphere. The nanoparticles are chemically active and interact with water at 60°C to form core-shell micro/nanostructures. The obtained products were characterized by means of X-ray diffraction, scanning electron microscopy, transmission electron microscopy and dynamic light scattering and the nitrogen adsorption method. The antibacterial activity of the synthesized structures was investigated against E. coli and St. aureus. The toxic effect of these nanostructures against the Neuro-2a neuroblastoma cell line was investigated. AlOOH/Cu nanostructures are shown to inhibit cell proliferation. The AlOOH/Cu nanostructures are good candidates for medical applications

Preparation of nano/micro bimodal aluminum powder by electrical explosion of wires

Electrical explosion of aluminum wires has been shown to be a versatile method for the preparation of bimodal nano/micro powders. The energy input into the wire has been found to determine the relative content of fine and coarse particles in bimodal aluminum powders. The use of aluminum bimodal powders has been shown to be promising for the development of high flowability feedstocks for metal injection molding and material extrusion additive manufacturing

Toxicity of the hybrid material based on low-dimensional structures of aluminum oxide

Aluminum oxides of various morphology and phase composition, including pseudoboehmite, have wide application in medicine. The novel hybrid material from polymer fibers and low-dimensional structures of pseudoboehmite fixed on them can be used as a wound dressing due to its highly absorbent and adsorbent properties. The in vivo investigation of acute and chronic toxicity of the novel hybrid material after a single dermal application in the acute experiment for 8 and 24 hours with outbred male and female rats reveals no irritation or other pathological changes. The chronic toxicity testing of the material after multiple dermal applications at two doses causes no death of animals and no pathological changes in their general condition, weight dynamics, and visceral morphology. The macro- and microscopy of internal organs shows no pathological changes as compared to control animals. The results obtained bear witness to the low potential risk of toxicity when using the hybrid material as a wound dressing

Synthesis of novel hierarchical micro/nanostructures AlOOH/AlFe and their application for As(V) removal

Hierarchical micro/nanostructured composites, which contain iron and/or its (hydr)oxides, demonstrate high rate and capacity of arsenic adsorption. The main objective of this paper is the use of novel low toxicity AlOOH/AlFe hierarchical micro/nanostructures for arsenic removal. AlOOH/AlFe composite was obtained by simple water oxidation in mild conditions using AlFe bimetallic nanopowder as a precursor. AlFe bimetallic nanopowder was produced by electrical explosive of two twisted wires in argon atmosphere. The productivity of the electrical explosion assembly was 50 g/h, with the consumption of the electrical energy was 75 kW·h/kg. AlFe bimetallic nanoparticles were chemically active and interacted with water at 60 °C. This nanocomposite AlOOH/AlFe is low cost and adsorbs more than 200 mg/g As(V) from its aqueous solution. AlOOH/AlFe composite has flower-like morphology and specific surface area 247.1 m2/g. The phase composition of nanostructures is present AlOOH boehmite and AlFe intermetallic compound. AlOOH/AlFe composite was not previously used for this. The flower-shape AlOOH morphology not only facilitated deliverability, but increased the As(V) sorption capacity by up to 200 mg/g. The adsorption kinetics has been found to be described by a pseudo-second-order equation of Lagergren and Weber-Morris models while the experimental adsorption isotherm is closest to the Freundlich model. This indicates the energy heterogeneity of the adsorbent surface and multilayer adsorption. The use of non-toxic nanostructures opens up new options to treat water affected by arsenic pollution