The Spin Liquid State of the Tb2Ti2O7 Pyrochlore Antiferromagnet: A Puzzling State of Affairs

The pyrochlore antiferromagnet Tb2Ti2O7 has proven to be an enigma to experimentalists and theorists working on frustrated magnetic systems. The experimentally determined energy level structure suggests a local Ising antiferromagnet at low temperatures, T < 10 K. An appropriate model then predicts a long-range ordered Q = 0 state below approximately 2 K. However, muon spin resonance experiments reveal a paramagnetic structure down to tens of milli-Kelvin. The importance of fluctuations out of the ground state effective Ising doublet has been recently understood, for the measured paramagnetic correlations can not be described without including the higher crystal field states. However, these fluctuations treated within the random phase approximation (RPA) fail to account for the lack of ordering in this system below 2 K. In this work, we briefly review the experimental evidence for the collective paramagnetic state of Tb2Ti2O7. The basic theoretical picture for this system is discussed, where results from classical spin models are used to motivate the investigation of quantum effects to lowest order via the RPA. Avenues for future experimental and theoretical work on Tb2Ti2O7 are presented.Comment: Latex2e,6 pages, IOP format, introduction shortened and other minor corrections, replaced with published version in the Proceedings of the Highly Frustrated Magnetism 2003 Conference, Grenobl

Ferroelectric and Dipolar Glass Phases of Non-Crystalline Systems

In a recent letter [Phys. Rev. Lett. {\bf 75}, 2360 (1996)] we briefly discussed the existence and nature of ferroelectric order in positionally disordered dipolar materials. Here we report further results and give a complete description of our work. Simulations of randomly frozen and dynamically disordered dipolar soft spheres are used to study ferroelectric ordering in non-crystalline systems. We also give a physical interpretation of the simulation results in terms of short- and long-range interactions. Cases where the dipole moment has 1, 2, and 3 components (Ising, XY and XYZ models, respectively) are considered. It is found that the Ising model displays ferroelectric phases in frozen amorphous systems, while the XY and XYZ models form dipolar glass phases at low temperatures. In the dynamically disordered model the equations of motion are decoupled such that particle translation is completely independent of the dipolar forces. These systems spontaneously develop long-range ferroelectric order at nonzero temperature despite the absence of any fined-tuned short-range spatial correlations favoring dipolar order. Furthermore, since this is a nonequilibrium model we find that the paraelectric to ferroelectric transition depends on the particle mass. For the XY and XYZ models, the critical temperatures extrapolate to zero as the mass of the particle becomes infinite, whereas, for the Ising model the critical temperature is almost independent of mass and coincides with the ferroelectric transition found for the randomly frozen system at the same density. Thus in the infinite mass limit the results of the frozen amorphous systems are recovered.Comment: 25 pages (LATEX, no macros). 11 POSTSCRIPT figures enclosed. Submitted to Phisical Review E. Contact: [email protected]

Evidence for gapped spin-wave excitations in the frustrated Gd2Sn2O7 pyrochlore antiferromagnet from low-temperature specific heat measurements

We have measured the low-temperature specific heat of the geometrically frustrated pyrochlore Heisenberg antiferromagnet Gd2Sn2O7 in zero magnetic field. The specific heat is found to drop exponentially below approximately 350 mK. This provides evidence for a gapped spin-wave spectrum due to an anisotropy resulting from single ion effects and long-range dipolar interactions. The data are well fitted by linear spin-wave theory, ruling out unconventional low energy magnetic excitations in this system, and allowing a determination of the pertinent exchange interactions in this material

Non-trivial fixed point structure of the two-dimensional +-J 3-state Potts ferromagnet/spin glass

The fixed point structure of the 2D 3-state random-bond Potts model with a bimodal ($\pm$J) distribution of couplings is for the first time fully determined using numerical renormalization group techniques. Apart from the pure and T=0 critical fixed points, two other non-trivial fixed points are found. One is the critical fixed point for the random-bond, but unfrustrated, ferromagnet. The other is a bicritical fixed point analogous to the bicritical Nishimori fixed point found in the random-bond frustrated Ising model. Estimates of the associated critical exponents are given for the various fixed points of the random-bond Potts model.Comment: 4 pages, 2 eps figures, RevTex 3.0 format requires float and epsfig macro

Quantum spin fluctuations in the dipolar Heisenberg-like rare earth pyrochlores

The magnetic pyrochlore oxide materials of general chemical formula R2Ti2O7 and R2Sn2O7 (R = rare earth) display a host of interesting physical behaviours depending on the flavour of rare earth ion. These properties depend on the value of the total magnetic moment, the crystal field interactions at each rare earth site and the complex interplay between magnetic exchange and long-range dipole-dipole interactions. This work focuses on the low temperature physics of the dipolar isotropic frustrated antiferromagnetic pyrochlore materials. Candidate magnetic ground states are numerically determined at zero temperature and the role of quantum spin fluctuations around these states are studied using a Holstein-Primakoff spin wave expansion to order 1/S. The results indicate the strong stability of the proposed classical ground states against quantum fluctuations. The inclusion of long range dipole interactions causes a restoration of symmetry and a suppression of the observed anisotropy gap leading to an increase in quantum fluctuations in the ground state when compared to a model with truncated dipole interactions. The system retains most of its classical character and there is little deviation from the fully ordered moment at zero temperature.Comment: Latex2e, 18 pages, 4 figures, IOP forma

Zero-temperature phase of the XY spin glass in two dimensions: Genetic embedded matching heuristic

For many real spin-glass materials, the Edwards-Anderson model with continuous-symmetry spins is more realistic than the rather better understood Ising variant. In principle, the nature of an occurring spin-glass phase in such systems might be inferred from an analysis of the zero-temperature properties. Unfortunately, with few exceptions, the problem of finding ground-state configurations is a non-polynomial problem computationally, such that efficient approximation algorithms are called for. Here, we employ the recently developed genetic embedded matching (GEM) heuristic to investigate the nature of the zero-temperature phase of the bimodal XY spin glass in two dimensions. We analyze bulk properties such as the asymptotic ground-state energy and the phase diagram of disorder strength vs. disorder concentration. For the case of a symmetric distribution of ferromagnetic and antiferromagnetic bonds, we find that the ground state of the model is unique up to a global O(2) rotation of the spins. In particular, there are no extensive degeneracies in this model. The main focus of this work is on an investigation of the excitation spectrum as probed by changing the boundary conditions. Using appropriate finite-size scaling techniques, we consistently determine the stiffness of spin and chiral domain walls and the corresponding fractal dimensions. Most noteworthy, we find that the spin and chiral channels are characterized by two distinct stiffness exponents and, consequently, the system displays spin-chirality decoupling at large length scales. Results for the overlap distribution do not support the possibility of a multitude of thermodynamic pure states.Comment: 18 pages, RevTex 4, moderately revised version as publishe

Neutron spectroscopic study of crystal field excitations in Tb2Ti2O7 and Tb2Sn2O7

We present time-of-flight inelastic neutron scattering measurements at low temperature on powder samples of the magnetic pyrochlore oxides Tb2Ti2O7 and Tb2Sn2O7. These two materials possess related, but different ground states, with Tb2Sn2O7 displaying "soft" spin ice order below Tn~0.87 K, while Tb2Ti2O7 enters a hybrid, glassy spin ice state below Tg~0.2 K. Our neutron measurements, performed at T=1.5 K and 30 K, probe the crystal field states associated with the J=6 states of Tb3+ within the appropriate Fd\bar{3}m pyrochlore environment. These crystal field states determine the size and anisotropy of the Tb3+ magnetic moment in each material's ground state, information that is an essential starting point for any description of the low-temperature phase behavior and spin dynamics in Tb2Ti2O7 and Tb2Sn2O7. While these two materials have much in common, the cubic stanate lattice is expanded compared to the cubic titanate lattice. As our measurements show, this translates into a factor of ~2 increase in the crystal field bandwidth of the 2J+1=13 states in Tb2Ti2O7 compared with Tb2Sn2O7. Our results are consistent with previous measurements on crystal field states in Tb2Sn2O7, wherein the ground state doublet corresponds primarily to m_J=|\pm 5> and the first excited state doublet to mJ=|\pm 4>. In contrast, our results on Tb2Ti2O7 differ markedly from earlier studies, showing that the ground state doublet corresponds to a significant mixture of mJ=|\pm 5>, |\mp 4>, and |\pm 2>, while the first excited state doublet corresponds to a mixture of mJ=|\pm 4>, |\mp 5>, and |\pm 1>. We discuss these results in the context of proposed mechanisms for the failure of Tb2Ti2O7 to develop conventional long-range order down to 50 mK.Comment: 12 pages, 6 figures. Version is the same as the published one, except for figure placement on page

Vortex lines in the three-dimensional XY model with random phase shifts

The stability of the ordered phase of the three-dimensional XY-model with random phase shifts is studied by considering the roughening of a single stretched vortex line due to the disorder. It is shown that the vortex line may be described by a directed polymer Hamiltonian with an effective random potential that is long range correlated. A Flory argument estimates the roughness exponent to $\zeta=3/4$ and the energy fluctuation exponent to $\omega=1/2$, thus fulfilling the scaling relation $\omega=2\zeta-1$. The Schwartz-Edwards method as well as a numerical integration of the corresponding Burger's equation confirm this result. Since $\zeta<1$ the ordered phase of the original XY-model is stable.Comment: 8 pages RevTeX, 3 eps-figures include