Changes induced by UV radiation in the presence of sodium benzoate in films formulated with polyvinyl alcohol and carboxymethyl cellulose

This work was focused on: i) developing single and blend films based on carboxymethyl cellulose (CMC) and polyvinyl alcohol (PVOH) studying their properties, ii) analyzing the interactions between CMC and PVOH and their modifications UV-induced in the presence of sodium benzoate (SB), and iii) evaluating the antimicrobial capacity of blend films containing SB with and without UV treatment. Once the blend films with SB were exposed to UV radiation, they exhibited lower moisture content as well as a greater elongation at break and rougher surfaces compared to those without treatment. Considering oxygen barrier properties, the low values obtained would allow their application as packaging with selective oxygen permeability. Moreover, the characteristics of the amorphous phase of the matrix prevailed with a rearrangement of the structure of the polymer chain, causing a decrease of the crystallinity degree. These results were supported by X-rays and DSC analysis. FT-IR spectra reflected some degree of polymer–polymer interaction at a molecular level in the amorphous regions. The incorporation of sodium benzoate combined with UV treatment in blend films was positive from the microbial point of view because of the growth inhibition of a wide spectrum of microorganisms. From a physicochemical perspective, the UV treatment of films also changed their morphology rendering them more insoluble in water, turning the functionalized blend films into a potential material to be applied as food packaging.Fil: Villarruel, S.. Universidad Nacional de La Plata. Facultad de Ciencias Exactas; ArgentinaFil: Giannuzzi, Leda. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; ArgentinaFil: Rivero, Sandra G. M.. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; ArgentinaFil: Pinotti, Adriana Noemi. Provincia de Buenos Aires. Gobernación. Comisión de Investigaciones Científicas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Consejo Nacional de Investigaciones Científicas y Técnicas. Centro Científico Tecnológico Conicet - La Plata. Centro de Investigación y Desarrollo en Criotecnología de Alimentos. Universidad Nacional de La Plata. Facultad de Ciencias Exactas. Centro de Investigación y Desarrollo en Criotecnología de Alimentos; Argentin

Thermal characterization methodology for dry finishing turning of SAF 2507 stainless steel based on finite element simulations and surrogate models

This paper addresses the numerical thermal characterization of a 3D turning process of a SAF 2507 stainless steel. A thermographic test campaign was conducted to measure the temperature distribution at the tool-workpiece interface. The campaign was accommodated by means of a L18 fractional factorial design of experiment. The 3D turning process was simulated using the software TWS Advantedge. The heat transfer numerical coefficients were calibrated against experimental measures to obtain temperature values as accurate as possible. A statistical methodology framework was adopted to study the dependence of the coefficients from the machining parameters. A heat transfer surrogate model was then built and next experimentally validated

IC.IDO as a tool for displaying machining processes. The logic interface between computer-aided-manufacturing and virtual reality

This scientific communication investigates the logic interface of a CAM solver, i.e., MasterCAM, into a Virtual Reality (VR) environment. This integration helps in displaying machining operations in virtual reality. Currently, to partially visualize the results of a simulation in an immersive environment, an import/export procedure must be done manually. Here, a software plugin integrated into IC.IDO (by ESI Group) has been realized and fully described. This application allows the complete integration of CAM solver into the VR environment. In particular, the VERICUT solver has been integrated into VR. This kind of integration has never been done yet

Study on the State Feedback Selection and Measurement for the Application of an LQRI Secondary Voltage Regulator to a Transmission System

The electrical power system is being significantly affected by the climate change mitigation actions. The power generation, originally centralized, is transitioning towards a more decentralized paradigm due to the coal-fired power plants shut off and the increase in renewable power. Issues in transmission system's voltage control may arise, if the voltage regulation architecture is not modified accordingly. To this aim, in this paper it is investigated the use of a Linear Quadratic Regulator with Integral action (LQRI) for the secondary voltage regulation, aimed at exploiting several reactive power sources as actuators. Being the LQR class of regulators requiring the system state to correctly operate, and being a transmission system a complex system, a critical investigation must be done. In particular, it is needed to identify the variables that are directly measured in a real system, determine if they can be useful for the LQRI state feedback, and finally study the effect of the different possible feedback selection on the regulation performance

Reactive Power Resources Management in a Voltage Regulation Architecture Based on LQRI Control

The Italian transmission system's voltage control is based on its subdivision into decoupled control areas, where a hierarchical regulation architecture is applied. However, the structure and the voltage regulation of the electrical power system are being significantly impacted by the actions being taken to limit climate change. The increase in renewable energy sources exploitation is leading to a more-distributed and converter-based energy production. In addition, the forthcoming coal-fired plants shut-off will force the shift from providing regulation capability with a small number of big power plants, towards using a big number of smaller resources. Thus, in the near future a decrease in the effectiveness of the present voltage control architecture is expected. To solve such issue, a new voltage control architecture is needed, involving the more-distributed and converter-based energy production systems, as well as no longer relying on physically decoupled control areas. Therefore, in this paper a coordinated LQRI secondary voltage control is presented, able to use each grid-available reactive power source as an actuator. Furthermore, a bumpless transfer technique is proposed to solve the problem of managing a varying number of actuators (due to the reactive power resources' connection and disconnection)

Occurrence of Toxic Cyanobacterial Blooms in Rio de la Plata Estuary, Argentina: Field Study and Data Analysis

Water samples were collected during 3 years (2004–2007) at three sampling sites in the Rio de la Plata estuary. Thirteen biological, physical, and chemical parameters were determined on the water samples. The presence of microcystin-LR in the reservoir samples, and also in domestic water samples, was confirmed and quantified. Microcystin-LR concentration ranged between 0.02 and 8.6 μg.L−1. Principal components analysis was used to identify the factors promoting cyanobacteria growth. The proliferation of cyanobacteria was accompanied by the presence of high total and fecal coliforms bacteria (>1500 MNP/100 mL), temperature ≥25°C, and total phosphorus content ≥1.24 mg·L−1. The observed fluctuating patterns of Microcystis aeruginosa, total coliforms, and Microcystin-LR were also described by probabilistic models based on the log-normal and extreme value distributions. The sampling sites were compared in terms of the distribution parameters and the probability of observing high concentrations for Microcystis aeruginosa, total coliforms, and microcystin-LR concentration

Flexible distributed Bragg reflectors as optical outcouplers for OLEDs based on a polymeric anode

Top-emitting OLEDs (TOLEDs) represent a promising technology for the development of next-generation flexible and rollable displays, thanks to their improved light outcoupling and their compatibility with opaque substrates. Metal thin films are the most used electrodes for the manufacturing of TOLEDs, but they show poor resistance to mechanical deformation, which compromises the long-term durability of flexible devices. This paper reports the exploitation of a dielectric mirror (DBR) based on seven pairs of TiO2 and SiO2 combined with a polymeric electrode as an alternative to the bottom metal electrode in flexible TOLEDs. The DBR showed a maximum reflectivity of 99.9% at about 550 nm, and a stop-band width of about 200 nm. The reflectivity remained unchanged after bending and treatment with water and solvents. Green TOLED devices were fabricated on top of DBRs, and demonstrated good stability in terms of electro-optical and colorimetric characteristics, according to varying viewing angles. These results demonstrate that the combination of the flexible DBR with the polymeric anode is an interesting strategy for improving the durability of flexible TOLEDs for display applications, implemented on different kinds of free-standing ultra-thin substrates