The effect of varying volume fraction of microcapsules on fresh, mechanical and self-healing properties of mortars

Spherical polymeric microcapsules, carrying liquid sodium silicate, were used for autonomic self-healing of mortars. Microcapsules were added at varying volume fractions (V$_f$), with respect to the cement volume, from as low as 4% up to 32% and their effect on fresh, mechanical and self-healing properties was investigated. For this purpose a series of techniques were used ranging from static mechanical testing, ultrasonic measurements, capillary sorption tests and optical microscopy. A detailed investigation was also carried out at the microstructural level utilising scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX). Results showed that although increasing V$_f$ resulted in a ~27% reduction in the mechanical properties, the corresponding improvement in the self-healing potential was significantly higher. Areal crack mouth healing reached almost 100%. Also, the measured crack depth and sorptivity coefficient reduced to a maximum of 70% and 54% respectively in microcapsule-containing specimens. SEM/EDX observations showed that the regions in the periphery of fractured microcapsules are very dense. In this region, high healing product formation is also observed. Elemental analysis revealed that these products are mainly ettringite and calcium-silicate-hydrate (C-S-H).Engineering and Physical Sciences Research Council (Project Ref. EP/K026631/1 – ‘‘Materials for Life”)This is the final version of the article. It first appeared from Elsevier via http://dx.doi.org/10.1016/j.conbuildmat.2016.06.11

First UK field application and performance of microcapsule-based self-healing concrete

Maintaining the health and reliability of our infrastructure is of strategic importance. The current state of the UK infrastructure, and the associated huge costs of inspection, maintenance, repair and eventual replacement, is not sustainable and is no longer environmentally viable. The design of infrastructure, mainly concrete, remains traditional and poor material performance continues to be the main cause of deterioration and failure in our infrastructure systems. Biomimetic materials, that emulate natural biological systems in their ability to self-healing, provide an exciting and plausible solution. Embedding cementitious materials with in-built capabilities to sense and respond to their environmental triggers could potentially eliminate all external interventions and deliver a resilience infrastructure. The work presented in this paper forms part of a national initiative that has been developing biomimetic cementitious infrastructure materials which culminated in the first large-scale field trials of self-healing concrete in the UK testing four different but complementary technologies that were developed. This paper focuses on one self-healing technology, namely microcapsules, which contain a healing agent that is released on their rupture as a result of crack propagation. The paper will present details of the microcapsules used, their implementation in concrete and in the field trials and time-related, field and laboratory, assessment of the self-healing process. It also highlights challenges faced and improvements that are now on-going to produce the next generation of the microcapsule self-healing cementitious system

Polymeric microcapsules with switchable mechanical properties for self-healing concrete: synthesis, characterisation and proof of concept

Microcapsules, with sodium silicate solution as core, were produced using complex coacervation in a double, oil-in-water-in oil, emulsion system. The shell material was a gelatin–acacia gum crosslinked coacervate and the produced microcapsules had diameters ranging from 300 to 700 μm. The shell material designed with switchable mechanical properties. When it is hydrated exhibits soft and ‘rubbery’ behaviour and, when dried, transitions to a stiff and ‘glassy’ material. The microcapsules survived drying and rehydrating cycles and preserved their structural integrity when exposed to highly alkaline solutions that mimic the pH environment of concrete. Microscopy revealed that the shell thickness of the microcapsules varies across their perimeter from 5 to 20 μm. Thermal analysis showed that the produced microcapsules were very stable up to 190 °C. Proof of concept investigation has demonstrated that the microcapsules successfully survive and function when exposed to a cement-based matrix. Observations showed that the microcapsules survive mixing with cement and rupture successfully upon crack formation releasing the encapsulated sodium silicate solution.Financial support from the Engineering and Physical Sciences Research Council (EPSRC—United Kingdom) for this study (Project Ref. EP/K026631/1—‘Materials for Life’) is gratefully acknowledged

Command and Control on the Move: Assessing the Impact of Input Device, Button Size, and Road Condition

PROCEEDINGS of the HUMAN FACTORS AND ERGONOMICS SOCIETY 50th ANNUAL MEETING, 2006The article of record as published may be found at https://doi.org/10.1177/154193120605000517Digital command and control systems have contributed to the success of the U. S. military in combat in recent years. Force XXI Battle Command Brigade and Below (FBCB2) and Blue Force Tracker are examples of systems that have provided an advantage on the battlefield. However, interface design of these systems has not been optimal, especially when they are employed in high stress and mobile environments. The present study examined the effects of input device (touch screen or trackball), button size (small, medium, large), and road conditions (still, highway, off-road) on performance. The dependent variables were accuracy, reaction time, and motion sickness. The experimenters tested seven undergraduate freshmen from the U.S. Military Academy. The data show that a touch screen monitor with large button size is optimal for moving vehicles. These findings have important implications for the design of human-machine systems expected to operate on the move

The effect of varying volume fraction of microcapsules on fresh, mechanical and self-healing properties of mortars

Spherical polymeric microcapsules, carrying liquid sodium silicate, were used for autonomic self-healing of mortars. Microcapsules were added at varying volume fractions (Vf), with respect to the cement volume, from as low as 4% up to 32% and their effect on fresh, mechanical and self-healing properties was investigated. For this purpose a series of techniques were used ranging from static mechanical testing, ultrasonic measurements, capillary sorption tests and optical microscopy. A detailed investigation was also carried out at the microstructural level utilising scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDX). Results showed that although increasing Vf resulted in a ∼27% reduction in the mechanical properties, the corresponding improvement in the self-healing potential was significantly higher. Areal crack mouth healing reached almost 100%. Also, the measured crack depth and sorptivity coefficient reduced to a maximum of 70% and 54% respectively in microcapsule-containing specimens. SEM/EDX observations showed that the regions in the periphery of fractured microcapsules are very dense. In this region, high healing product formation is also observed. Elemental analysis revealed that these products are mainly ettringite and calcium-silicate-hydrate (C-S-H)

Assessment of microencapsulated sodium silicate for self-healing of cementitious materials

Self-healing is inherent in cementitious materials such as concrete. This is largely caused by the continued hydration of cement as well as the formation of calcium carbonate. This autogenic self-healing can be improved through the addition of microencapsulated silica minerals that disperse throughout the cementitious matrix. When cracks propagate within the material, they rupture the microcapsules thus causing a release of their contents into the crack volume. The released material reacts with the calcium hydroxide present in the material to produce calcium-silicate-hydrate (C-S-H). Microcapsules containing sodium silicate were added into cement paste and mortar. The effect of microcapsule addition on rheological and mechanical properties of cement and mortar was investigated. At the tested volume fractions (0-12%), it is clear that microcapsule addition has little detrimental effect on properties. The improved healing performance for microcapsule-containing mortar specimens is demonstrated through durability tests. It is clear that an increase in microcapsule addition results in improved sealing of cracks and this results in a reduction in sorptivity. The results in this paper are useful for determining the quantity of microcapsules to be added into cementitious materials for autonomic self-healing

Sealing of cracks in cement using microencapsulated sodium silicate

© 2016 IOP Publishing Ltd. Cement-based materials possess an inherent autogenous self-healing capability allowing them to seal, and potentially heal, microcracks. This can be improved through the addition of microencapsulated healing agents for autonomic self-healing. The fundamental principle of this self-healing mechanism is that when cracks propagate in the cementitious matrix, they rupture the dispersed capsules and their content (cargo material) is released into the crack volume. Various healing agents have been explored in the literature for their efficacy to recover mechanical and durability properties in cementitious materials. In these materials, the healing agents are most commonly encapsulated in macrocontainers (e.g. glass tubes or capsules) and placed into the material. In this work, microencapsulated sodium silicate in both liquid and solid form was added to cement specimens. Sodium silicate reacts with the calcium hydroxide in hydrated cement paste to form calcium-silicate-hydrate gel that fills cracks. The effect of microcapsule addition on rheological and mechanical properties of cement is reported. It is observed that the microcapsule addition inhibits compressive strength development in cement and this is observed through a plateau in strength between 28 and 56 days. The improvement in crack-sealing for microcapsule-containing specimens is quantified through sorptivity measurements over a 28 day healing period. After just seven days, the addition of 4% microcapsules resulted in a reduction in sorptivity of up to 45% when compared to specimens without any microcapsule addition. A qualitative description of the reaction between the cargo material and the cementitious matrix is also provided using x-ray diffraction analysis

Polymeric microcapsules with switchable mechanical properties for self-healing concrete: synthesis, characterisation and proof of concept

Microcapsules, with sodium silicate solution as core, were produced using complex coacervation in a double, oil-in-water-in oil, emulsion system. The shell material was a gelatin–acacia gum crosslinked coacervate and the produced microcapsules had diameters ranging from 300 to 700 μm. The shell material designed with switchable mechanical properties. When it is hydrated exhibits soft and ‘rubbery’ behaviour and, when dried, transitions to a stiff and ‘glassy’ material. The microcapsules survived drying and rehydrating cycles and preserved their structural integrity when exposed to highly alkaline solutions that mimic the pH environment of concrete. Microscopy revealed that the shell thickness of the microcapsules varies across their perimeter from 5 to 20 μm. Thermal analysis showed that the produced microcapsules were very stable up to 190 °C. Proof of concept investigation has demonstrated that the microcapsules successfully survive and function when exposed to a cement-based matrix. Observations showed that the microcapsules survive mixing with cement and rupture successfully upon crack formation releasing the encapsulated sodium silicate solution

First UK field application and performance of microcapsule-based self-healing concrete

Maintaining the health and reliability of our infrastructure is of strategic importance. The current state of the UK infrastructure, and the associated huge costs of inspection, maintenance, repair and eventual replacement, is not sustainable and is no longer environmentally viable. The design of infrastructure, mainly concrete, remains traditional and poor material performance continues to be the main cause of deterioration and failure in our infrastructure systems. Biomimetic materials, that emulate natural biological systems in their ability to self-healing, provide an exciting and plausible solution. Embedding cementitious materials with in-built capabilities to sense and respond to their environmental triggers could potentially eliminate all external interventions and deliver a resilience infrastructure. The work presented in this paper forms part of a national initiative that has been developing biomimetic cementitious infrastructure materials which culminated in the first large-scale field trials of self-healing concrete in the UK testing four different but complementary technologies that were developed. This paper focuses on one self-healing technology, namely microcapsules, which contain a healing agent that is released on their rupture as a result of crack propagation. The paper will present details of the microcapsules used, their implementation in concrete and in the field trials and time-related, field and laboratory, assessment of the self-healing process. It also highlights challenges faced and improvements that are now on-going to produce the next generation of the microcapsule self-healing cementitious system

A Comparison of Computational and Experimental Fluid Dynamics Studies between Scaled and Original Wing Sections, in Single-Phase and Two-Phase Flows, and Evaluation of the Suggested Method

The correlation between computational fluid dynamics (CFD) and experimental fluid dynamics (EFD) is crucial for the behavior prediction of aerodynamic bodies. This paper’s objective is twofold: (1) to develop a method that approaches commercial CFD codes and their link with EFD in a more efficient way, using a downscaled model, and (2) to investigate the effect of rain on the aerodynamic behavior of a wing. More specifically, we investigate the one-phase and two-phase flow over a typical wing section NACA 641-212 airfoil, in the commercial code Ansys Fluent. Two computational models were developed; the first model represents the original dimensions of the wing, while the second is downscaled to 23% of the original. The response of the models in air and air–water flow were primarily studied, as well as the impact on aerodynamic efficiency due to the existence of the second phase. For the computational fluid dynamics simulations, a pressure-based solver with a second-order upwind scheme for the spatial discretization and the Spalart–Allmaras (SA) turbulence model were utilized. Meanwhile, for the two-phase flow of air–water, the discrete phase model (DPM) with wall–film boundary conditions on the surface of the wing and two-way coupling between continuous and discrete phase was considered. The second phase was simulated as water droplets injected in the continuous phase, in a Euler–Lagrange approach. The experimental model was constructed in accordance with the downscaled model and tested in a subsonic wind tunnel, using 3D printing technology which reduced the experiment expenses. The presence of water in two-phase flow was proven to deteriorate the aerodynamic factors of the wing compared to one-phase flow, as expected. The three-stage comparison of CFD and EFD results showed a very good convergence, in both single and two-phase flow. This can lead to the conclusion that a rapid and low-cost study for the estimation of the aerodynamic performance of objects with high accuracy is feasible with the suggested method