7 research outputs found
Chiral photonic super-crystals based on helical van der Waals homostructures
Chirality is probably the most mysterious among all symmetry transformations.
Very readily broken in biological systems, it is practically absent in
naturally occurring inorganic materials and is very challenging to create
artificially. Chiral optical wavefronts are often used for the identification,
control and discrimination of left- and right-handed biological and other
molecules. Thus, it is crucially important to create materials capable of
chiral interaction with light, which would allow one to assign arbitrary chiral
properties to a light field. In this paper, we utilized van der Waals
technology to assemble helical homostructures with chiral properties (e. g.
circular dichroism). Because of the large range of van der Waals materials
available such helical homostructures can be assigned with very flexible
optical properties. We demonstrate our approach by creating helical
homostructures based on multilayer AsS, which offers the most
pronounced chiral properties even in thin structures due to its strong biaxial
optically anisotropy. Our work showcases that the chirality of an
electromagnetic system may emerge at an intermediate level between the
molecular and the mesoscopic one due to the tailored arrangement of non-chiral
layers of van der Waals crystals and without additional patterning
Exploring van der Waals materials with high anisotropy: geometrical and optical approaches
The emergence of van der Waals (vdW) materials resulted in the discovery of
their giant optical, mechanical, and electronic anisotropic properties,
immediately enabling countless novel phenomena and applications. Such success
inspired an intensive search for the highest possible anisotropic properties
among vdW materials. Furthermore, the identification of the most promising
among the huge family of vdW materials is a challenging quest requiring
innovative approaches. Here, we suggest an easy-to-use method for such a survey
based on the crystallographic geometrical perspective of vdW materials followed
by their optical characterization. Using our approach, we found As2S3 as a
highly anisotropic vdW material. It demonstrates rare giant in-plane optical
anisotropy, high refractive index and transparency in the visible range,
overcoming the century-long record set by rutile. Given these benefits, As2S3
opens a pathway towards next-generation nanophotonics as demonstrated by an
ultrathin true zero-order quarter-waveplate that combines classical and the
Fabry-Perot optical phase accumulations. Hence, our approach provides an
effective and easy-to-use method to find vdW materials with the utmost
anisotropic properties.Comment: 11 pages, 5 figure
Chiral photonic super-crystals based on helical van der Waals homostructures
Chirality is probably the most mysterious among all symmetry transformations. Very readily broken in biological systems, it is practically absent in naturally occurring inorganic materials and is very challenging to create artificially. Chiral optical wavefronts are often used for the identification, control and discrimination of left- and right-handed biological and other molecules. Thus, it is crucially important to create materials capable of chiral interaction with light, which would allow one to assign arbitrary chiral properties to a light field. In this paper, we utilized van der Waals technology to assemble helical homostructures with chiral properties (e. g. circular dichroism). Because of the large range of van der Waals materials available such helical homostructures can be assigned with very flexible optical properties. We demonstrate our approach by creating helical homostructures based on multilayer AsS, which offers the most pronounced chiral properties even in thin structures due to its strong biaxial optically anisotropy. Our work showcases that the chirality of an electromagnetic system may emerge at an intermediate level between the molecular and the mesoscopic one due to the tailored arrangement of non-chiral layers of van der Waals crystals and without additional patterning
Planar and van der Waals heterostructures for vertical tunnelling single electron transistors (vol 10, 230, 2019)
NATURE COMMUNICATIONS10
Data for manuscript "Wandering principal optical axes in van der Waals triclinic materials"
Data for manuscript "Wandering principal optical axes in van der Waals triclinic materials"</p