2 research outputs found
Process analysis and improvement of a Claus unit of an existing gas plant
This research is a part of Master degree research programme at Cranfield University
to study Claus process and perform process analysis on an existing Sulphur recovery
unit in a gas plant.
The Mellitah Plant, in Western Libya, is a gas plant designed to treat raw gas and
condensate from offshore gas fields in several processing units where the sour gas
(H2S, CO2, COS, SC2) is removed to meet the international emission standard, in order
to control the emission and pollution from the flue gas. The acid gases are treated in
Claus unit where H2S is converted to sulphur in multi-reaction steps. These reactions
start in a combustion reaction zone, thermal reactor, to produce a suitable mixture of
H2S to SO2. The mixture reacts in Claus catalytic reactors to produce sulphur vapour.
The sulphur vapour is condensed in multi-condensing steps after each catalytic
reactor.
The ultimate aim of this research is to carry out the process analysis for Claus unit in
order to recover the waste energy to increase the plant productivity, minimise the use
of the plant utilities, and decrease the environmental pollution. A process model of the
plant was developed and validated in Aspen HYSYS. The process was then analysed,
the analysis has resulted in a significant increase in Claus unit overall conversion ratio
which has increased from 61% to 97.63% H2S base. Consequently, Claus unit
productivity has increased by approximately 1.72 times. In addition, a higher amount
of energy is recovered in a form of heat by heating the boiler feed water to produce
both high pressure steam in the waste heat boiler and low pressure steam in 1st and
2nd sulphur condensers. Both high pressure and low pressure steam total production
are increased by 1.5 times. All this has been achieved at high conversion ratio number
of 2 in tail gas which represents optimum O2/H2S ratio in the thermal reactor feed and
the high conversion number can be kept in between 1.5 to 3 during plant normal
operation
Age, microfacies and depositional environment of the Middle to Late Paleocene shallow-marine carbonates in the Sirt Basin of Libya (Upper Sabil Formation) : "Are Intisar domal structures pinnacle reefs?"
In the central-eastern Sirt Basin, enigmatic Intisar domal structures host significant hydrocarbon accumulations. These structures have been commonly interpreted as pinnacle reefs/bioherms occurring in the open-marine basinal environment. Generally, pinnacle reefs/bioherms are mainly characterized by in situ carbonates. The current study challenges the Intisar pinnacle reef/bioherm model by examining one of the domal structures in terms of biostratigraphy, microfacies and depositional environment. These structures were dated using larger benthic foraminifera, which yielded a Middle to Late Paleocene age (Selandian–Early Thanetian). Thirteen microfacies types representing different carbonate ramp environments ranging from outer ramp to inner ramp, were defined. Outer ramp deposits have been observed adjacent to the domal structure, represented mainly by wackestone with small benthic and planktonic foraminifera. The outer ramp deposits are most likely isochronous to the domal structures. The lower part of the domal structures is composed mainly of foraminiferal–algal–echinodermal packstones. The upper part is characterized by foraminiferal–algal–echinodermal packstones with intercalated microbialite–coral boundstones. The euphotic inner ramp deposits are preserved on the crest of the domal structure, consisting of grainstone and packstone rich in Glomalveolina. As a result of this study, the Intisar domal structures are seen as erosional relics of a carbonate ramp and no evidence for pinnacle reef/bioherm model was found