The effect of Fe atoms on the adsorption of a W atom on W(100) surface

We report a first-principles calculation that models the effect of iron (Fe) atoms on the adsorption of a tungsten (W) atom on W(100) surfaces. The adsorption of a W atom on a clean W(100) surface is compared with that of a W atom on a W(100) surface covered with a monolayer of Fe atoms. The total energy of the system is computed as the function of the height of the W adatom. Our result shows that the W atom first adsorbs on top of the Fe monolayer. Then the W atom can replace one of the Fe atoms through a path with a moderate energy barrier and reduce its energy further. This intermediate site makes the adsorption (and desorption) of W atoms a two-step process in the presence of Fe atoms and lowers the overall adsorption energy by nearly 2.4 eV. The Fe atoms also provide a surface for W atoms to adsorb facilitating the diffusion of W atoms. The combination of these two effects result in a much more efficient desorption and diffusion of W atoms in the presence of Fe atoms. Our result provides a fundamental mechanism that can explain the activated sintering of tungsten by Fe atoms.Comment: 9 pages, 2 figure

High Temperature Partition Function of the Rigid String

We find that the high temperature limit of the free energy per unit length for the rigid string agrees dimensionally with that of the QCD string (unlike the Nambu-Goto string). The sign, and in fact the phase, do not agree. While this may be a clue to a string theory of QCD, we note that the problem of the fourth derivative action makes it impossible for the rigid string to be a correct description.Comment: 7 page

Rapid Steel Tooling Via Solid Freeform Fabrication

With increasing part complexity and requirements for long production runs, tooling has become an expensive process that requires long lead times to manufacture. This lengthens the amount oftime from "art to part". Rapid tooling via stereolithography (SLA), filled epoxies, etc. have been stopgap measures to produce limited prototyping runs from (10 to 500 parts). This gives poor dimensional analysis and does not allow for limited production runs of 1000+ parts. The method ofproducing prototype tooling with a powdered metal process has been developed that produces tooling with a hardness greater than 35 HRC and total shrinkage less than 0.5%. This tooling process manufactures production ready tooling that will perform extended cycle runs (100,000+). Manufacturing ofthis tooling takes 1 to 2 weeks and will compare favorably with production grade steel tooling. Originals drawn in 3D CAD can be used to prototype the master that will allow for the production ofthe rapid metal tool set. process starts with a rapid prototyped model made by whatever process is desired or a machined master. For this paper a Sander's Model Maker II® rapid prototyping machine was used to fabricate the model. After the model ofthe tool set is made, a silicone rubber negative is cast around that model. After the silicone rubber model is made, a heated slurry ofmetal powders and polymers is poured into the mold to create the green tool set. The tool set is left to cool, and then removed from the silicone rubber mold. The tool set is then debound and sintered to produce a final tool set with properties approaching hardened tool steel.Mechanical Engineerin

Digestion of Protein in Premature and Term Infants.

Premature birth rates and premature infant morbidity remain discouragingly high. Improving nourishment for these infants is the key for accelerating their development and decreasing disease risk. Dietary protein is essential for growth and development of infants. Studies on protein nourishment for premature infants have focused on protein requirements for catch-up growth, nitrogen balance, and digestive protease concentrations and activities. However, little is known about the processes and products of protein digestion in the premature infant. This review briefly summarizes the protein requirements of term and preterm infants, and the protein content of milk from women delivering preterm and at term. An in-depth review is presented of the current knowledge of term and preterm infant dietary protein digestion, including human milk protease and anti-protease concentrations; neonatal intestinal pH, and enzyme activities and concentrations; and protein fermentation by intestinal bacteria. The advantages and disadvantages of incomplete protein digestion as well as factors that increase resistance to proteolysis of particular proteins are discussed. In order to better understand protein digestion in preterm and term infants, future studies should examine protein and peptide fragment products of digestion in saliva, gastric, intestinal and fecal samples, as well as the effects of the gut micro biome on protein degradation. The confluence of new mass spectrometry technology and new bioinformatics programs will now allow thorough identification of the array of peptides produced in the infant as they are digested

Co-movements in commodity prices: a note based on network analysis

This paper analyses co-movements in a wide group of commodity prices during the time period 1992-2010. Our methodological approach is based on the correlation matrix and the networks inside. Through this approach we are able to summarize global interaction and interdependence, capturing the existing heterogeneity in the degrees of synchronization between commodity prices. Our results produce two main findings: (a) we do not observe a persistent increase in the degree of co-movement of the commodity prices in our time sample, however from mid-2008 to the end of 2009 co-movements almost doubled when compared with the average correlation; (b) we observe three groups of commodities which have exhibited similar price dynamics (metals, oil and grains and oilseeds) and which have increased their degree of co-movement during the sampled period. These results suggest that speculation and uncertainty are drivers of the sharp slump in commodity prices synchronization.commodity prices, co-movement, hierarchy and topology, networks, complex systems

Torsion and Nonmetricity in Scalar-Tensor Theories of Gravity

We show that the gravitational field equations derived from an action composed of i) an arbitrary function of the scalar curvature and other scalar fields plus ii) connection-independent kinetic and source terms, are identical whether one chooses nonmetricity to vanish and have non-zero torsion or vice versa.Comment: 10 page