Effects of acidity, number of hydroxyl group, and carbon chain length of carboxylic acids on starch cross-linking

Corn starch film samples cross-linked using malic, malonic, and succinic acids, and thermoplastic starch were characterized and tested for their water absorption, surface morphology, structural change, and thermomechanical properties. The acids vary in acidity, number of hydroxyl groups, and carbon chain length. The presence of an additional hydroxyl group has helped malic acid form more hydrogen bonding between starch molecules. The relatively higher acidity in malic acid compared to succinic acid is found to be another factor for its better cross-linking potential. The additional carbon chain in succinic acid, which reduces its solubility and acidity; has negatively affected its cross-linking potential. Among the three variables studied, number of hydroxyl group has highly influenced the cross-linking potential, followed by acidity and carbon chain length, respectively. Consequently, the elongation at break and water absorption resistance of thermoplastic starch were improved from 108.63 ​MPa to 175.72 ​MPa and from 140% to 80%, respectively, cross-linking corn starch with malic acid

Development and Characterization of Sisal Fiber Reinforced Polypropylene Composite Materials

In most of the developing countries, plastic polypropylene is not fully recycled and converted in-to use after it is once used. Sisal fiber is also widely available in different developing countries like Ethiopia. Adding this two materials and developing automotive interior part was taken as a primary motive for it reduces cost and is environmentally friendly. Thus, the main purpose of this research is to develop composite material from natural fibre (sisal fiber) reinforced with recycled plastic waste (polypropylene) for interior automobile accessories specifically for internal door trim panel application. This research examines effect of fiber length, fiber loading and chemical treatment of fiber on the physical and chemical properties of the sisal fiber reinforced polypropylene (SFRPP) composite material. The waste polypropylene and the treated and untreated sisal fiber with variable length and weight ratio (fiber/matrix ratio) were mixed. Flammability of sisal fiber reinforced Polypropylene (SFRPP) composites material was examined by a horizontal burning test according to ASTM D635 and chemical resistance of the sisal fibre reinforced PP composites was studied using ASTM D543 testing method. The result on the flammability test shows that treated fiber has lower burning rate than untreated fiber and decreases with increase in fiber length and fiber loading. The resistance of the composites to water has increased as the fiber length increases and decreased as the fiber loading increase. Generally, SFRPP composite is found to have better resistance to water than NaOH and H2SO4 and treating the fiber has brought considerable improvement on chemical resistance of the composite. Fiber loading and fiber length has positive and negative effect on the flammability of the SFRPP composite respectively