Electric Switching of the Charge-Density-Wave and Normal Metallic Phases in Tantalum Disulfide Thin-Film Devices

We report on switching among three charge-density-wave phases - commensurate, nearly commensurate, incommensurate - and the high-temperature normal metallic phase in thin-film 1T-TaS2 devices induced by application of an in-plane electric field. The electric switching among all phases has been achieved over a wide temperature range, from 77 K to 400 K. The low-frequency electronic noise spectroscopy has been used as an effective tool for monitoring the transitions, particularly the switching from the incommensurate charge-density-wave phase to the normal metal phase. The noise spectral density exhibits sharp increases at the phase transition points, which correspond to the step-like changes in resistivity. Assignment of the phases is consistent with low-field resistivity measurements over the temperature range from 77 K to 600 K. Analysis of the experimental data and calculations of heat dissipation suggest that Joule heating plays a dominant role in the electric-field induced transitions in the tested 1T-TaS2 devices on Si/SiO2 substrates. The possibility of electrical switching among four different phases of 1T-TaS2 is a promising step toward nanoscale device applications. The results also demonstrate the potential of noise spectroscopy for investigating and identifying phase transitions in materials.Comment: 32 pages, 7 figure

Low-Frequency Noise Spectroscopy of Charge-Density-Wave Phase Transitions in Vertical Quasi-2D Devices

We report results regarding the electron transport in vertical quasi-2D layered 1T-TaS2 charge-density-wave devices. The low-frequency noise spectroscopy was used as a tool to study changes in the cross-plane electrical characteristics of the quasi-2D material below room temperature. The noise spectral density revealed strong peaks - changing by more than an order-of-magnitude - at the temperatures closely matching the electrical resistance steps. Some of the noise peaks appeared below the temperature of the commensurate to nearly-commensurate charge-density-wave transition, possibly indicating the presence of the debated "hidden" phase transitions. These results confirm the potential of the noise spectroscopy for investigations of electron transport and phase transitions in novel materials.Comment: 16 pages; 5 figure

Impact of land use/cover change and slope gradient on soil organic carbon stock in Anjeni watershed, Northwest Ethiopia

Today’s agri-food systems face the triple challenge of addressing food security, adapting to climate change, and reducing the climate footprint by reducing the emission of greenhouse gases (GHG). In agri-food systems, changes in land use and land cover (LULC) could affect soil physicochemical properties, particularly soil organic carbon (SOC) stock. However, the impact varies depending on the physical, social, and economic conditions of a given region or watershed. Given this, a study was conducted to quantify the impact of LULC and slope gradient on SOC stock and C sequestration rate in the Anjeni watershed, which is a highly populated and intensively cultivated area in Northwest Ethiopia. Seventy-two soil samples were collected from 0–15 and 15–30 cm soil depths representing four land use types and three slope gradients. Soil samples were selected systematically to match the historical records (30 years) for SOC stock comparison. Four land use types were quantified using Landsat imagery analysis. As expected, plantation forest had a significantly (p \u3c 0.05) higher SOC (1.94 Mg ha−1) than cultivated land (1.38 Mg ha−1), and gentle slopes (1–15%) had the highest SOC (1.77 Mg ha−1) than steeper slopes (\u3e 30%). However, higher SOC stock (72.03 Mg ha−1) and SOC sequestration rate (3.00 Mg ha−1 year−1) were recorded when cultivated land was converted to grassland, while lower SOC stock (8.87 Mg ha−1) and sequestration rate (0.77 Mg ha−1 year−1) were recorded when land use changed from cultivation to a plantation forest. The results indicated that LULC changes and slope gradient had a major impact on SOC stock and C sequestration rate over 30 years in a highly populated watershed. It is concluded that in intensively used watersheds, a carefully planned land use that involves the conversion of cultivated land to grassland could lead to an increase in soil C sequestration and contributes to reducing the carbon footprint of agri-food systems

Effect of Selected Conventional and Non-conventional Mineral Fillers with ‘Enset’ Fibers on Compaction Characteristics of Stone Mastic Asphalt Pavement (SMAP)

The content and type of ingredient materials are used to prepare the asphalt mix to affect the pavement surface's quality. This study aimed to investigate the compaction characteristics of Stone Mastic Asphalt Pavement (SMAP) mix using two different types of mineral fillers; namely, crushed stone and Ambo sandstone dust with local material enset fiber. Results indicated that the filler type and the content with or without fiber have a great effect on compaction characteristics of Stone Mastic Asphalt Pavement. The test results also showed that the addition of enset fiber in asphalt mix increases density, compaction energy, and strength of asphalt mix and reduces Marshall flow of the mixes. Besides, crushed stone dust and Ambo sandstone dust with enset fiber affect the Marshall property and compaction characteristics of the stone mastic asphalt mix differentially. The Ambo sandstone dust filler has a low density and has high binder absorption capacity compared with crushed stone dust filler in SMA mixes. In this study, the optimum binder content for the mixture by using Ambo sandstone dust (8%, 6.41%), (8.5%, 6.48%) & (10%, 6.43%) as well as the mixture using crushed stone dust filler at (8%, 5.84%), (8.5%,6.32%) & (10%,5.96%) was determined. The optimum fiber content obtained at 0.3% suggests that using enset fiber in stone mastic asphalt mixture improves the strength of asphalt pavements to resist external loads. The enset fiber at 0.3% better modifies stone mastic asphalt pavement properties. Finally, it is postulated that the performance of pavement is affected by filler type and content. Simultaneously, the Marshall property has a linear relationship with compaction characteristics. It showed the possibility of constructing stone mastic asphalt pavement in Ethiopia by using locally available materials

Experimental Study on Application of Marble Waste as Conventional Aggregate for Base Course Materials

Recently, highway and construction industries utilize a substantial quantity of conventional aggregates. The increasing demands for conventional aggregate cause an increase in the cost of construction, reduction of natural resources, and continuing deterioration of the earth's surface. On the other hand, the waste generated from the marble industries during the process of cutting and polishing was increasing day by day all over the world. In Ethiopia, the use of Marble Waste Aggregate materials in road construction as a base course material was not well-known, and it was simply wasted at every place where the marble production was continuing. Therefore, this paper focused on evaluating the possibility of using marble waste aggregate as conventional aggregate in the base course layer of flexible pavements by experimental method. To achieve the objectives of the research, mechanical stabilization and laboratory tests have been carried out at different percentage replacement of Conventional Aggregate by (0%, 20%, 40%, 50%, 60%, 80%, and 100%) of Marble Waste Aggregate weights. Marble wastes materials are collected from Burayyu city, Alisha marble processing industry. The laboratory test results for MWA indicated SG, ACV, AIV, LAA, Flakiness Index , Elongation Index, Plastic Index, Water Absorption, and CBR of 2.74%, 23.63%, 26.21%, 27.03%, 26.48%, 13.29%, Non Plastic, 0.50% and 73.3%, respectively. These test results fulfilled the ERA standard specification for some tests, and they showed marginal quality values to the standard specification for GB2 and GB3 base course materials. CBR and gradation test results shown failure to meet the standard specification. Thus, mechanical stabilization was done to improve the mechanical and physical properties of the Marble Waste Aggregate. Blending of 80%MWA with 20% CA results in SG, ACV, AIV, LAA, Flakiness Index, Elongation Index, Plastic Index, Water Absorption, and CBR of 2.83%, 18.2%, 21.52%, 22.58%, 23.79%, 16.29%, Non Plastic, 0.80%,and 82.5% respectively. At this proportion, the gradation also observed to fit with the required ERA standard specification of GB2 and GB3 materials. Therefore, the use of marble waste aggregate up to 80% by weight is recommended for the road base course layer, when it is found near to the construction site and in places where the materials are abundantly available

Combined Effects of Molasses-Lime Treatment on Poor Quality Natural Gravel Materials Used for Sub-Base and Base Course Construction

At the time of industrial development, the production of large amounts of wastage required proper disposal. To reduce the disposal problem, utilization of wastage in construction works is a very important aspect. The reuse of industrial waste had gained high momentum for achieving sustainable waste management locally and globally. Keeping this in mind, research carried out to assess the utilization of molasses, lime, and molasses-lime for improving natural gravel for sub-base and base course construction from the Jimma Jiren quarry site. The natural gravel from this quarry site is known to have poor quality since it did not satisfy the ERA standard specification for sub-base and base course construction. To use Jiren natural gravel as a sub-base or base course construction material, it is necessary to improve its engineering properties. The laboratory test matrix in each test plan included variations in additive type, additive content, and curing period. It was established 8% cane molasses by weight of dry soil as the maximum for effective stabilization of natural gravel for sub-base construction, but not suitable for a base course layer. Results indicated that the natural gravel specimens from the Jiren quarry site stabilized with lime provided higher CBR values than molasses used alone. On the other hand, replacing 50% of lime content with molasses indicated better results than the performance of either individual additive. Therefore, the natural gravel blended with the molasses-lime combination is much better when it used for sub-base and base course construction to treat such an inferior quality of natural aggregates

Evaluation of the Performance of Brick Dust as a Filler Material for Hot Asphalt Mix Design A Case Study in Jimma Zone

A bituminous paving mixture is a mixture of coarse aggregate, fine aggregate, and bitumen mixed in suitable proportion to result in a strong and durable mix in order to withstand traffic load. In this paving mix, ordinary stone dust, and cement used as filler material. One of the main problems in the construction of a bituminous paving mixture is the insufficient amount of filler from crushing stone aggregate, and cement supply is low. A study has been carried out in this research to explore the use of Brick dust as filler material for the bituminous mixture. The objective is intended to evaluate the performance of brick dust as fillers in Hot Asphalt Mix design, according to the test procedure specified by ASTM. Several specimens of hot asphalt mixture were prepared according to ASTM D 1559 using an aggregate blend with brick filler and aggregate blend without brick filler. The aggregate blending made by using Job mix formula to obtain the percentage of mixed material. For aggregate blended without brick G-1 32%, G-2 23%, and G-3 45% for Aggregate blended with brick filler G-1 30%, G-2 18%, G-3 45% and G-4 7%; where G-1 Coarse Aggregate 3/4, G-2 Coarse Aggregate 3/8, G-3 Fine Aggregate, and G-4 brick filler. It concluded that the results of the Marshall test of mix design showed satisfactory when hot asphalt mixed with these brick fillers. The Specimens blended with brick filler lead produce asphalt mixture with higher Marshall stability, lower flow, a less void filled with asphalt. Hence, brick dust can replace stone dust and cement filler in the bituminous paving mix. It is recommended to use brick dust as filler material in a bituminous paving mix may save considerable investment; as well as a reliable performance of the in-service highway can be achieved

EXPERIMENTAL STUDY OF STABILIZED EXPANSIVE SOIL USING PUMICE MIXED WITH LIME FOR SUBGRADE ROAD CONSTRUCTION

Unsuitable soil materials along the alignment of road projects have a significant influence on planning, design, construction, and maintenance. Expansive soils are susceptible to considerable volume changes due to seasonal variations and moisture content. Most soils found in Jimma and Ambo Zones composed of plastic clay soil, causing severe damage at the intermittent of pavement sections. This research study conducted laboratory investigation considering combinations of materials blended to stabilize the expansive soil for subgrade construction. An experimental type of study performed started by collecting specimens. Two clayey soil specimens considered to test the free swell index obtained from a depth of 1.5m to remove the organic impurities. Results indicated the chemical analysis of pumice contained 82.68%, while its physical properties of the test of fineness specific surface and residue on 45 microns showed 3770 cm2/gm and 30%, respectively. As the lime content increased, the CBR strength also increased. But, if the percent content of lime decreased with an increasing pumice content, the CBR value did not show any significant increase. Both the chemical and physical properties satisfied the requirements according to ASTM C-618. Hence, this experiment obtained 7% lime + 3% pumice as an optimum mix ratio to stabilize expansive soils