8 research outputs found
Effect of the Intrinsic Width on the Piezoelectric Force Microscopy of a Single Ferroelectric Domain Wall
Intrinsic domain wall width is a fundamental parameter that reflects bulk
ferroelectric properties and governs the performance of ferroelectric memory
devices. We present closed-form analytical expressions for vertical and lateral
piezoelectric force microscopy (PFM) profiles for the conical and disc models
of the tip, beyond point charge and sphere approximations. The analysis takes
into account the finite intrinsic width of the domain wall, and dielectric
anisotropy of the material. These analytical expressions provide insight into
the mechanisms of PFM image formation and can be used for quantitative analysis
of the PFM domain wall profiles. PFM profile of a realistic domain wall is
shown to be the convolution of its intrinsic profile and resolution function of
PFM.Comment: 25 pages, 5 figures, 3 tables, 3 Appendices, To be submitted to J.
Appl. Phy
Fixed Volume Effect on Polar Properties and Phase Diagrams of Ferroelectric Semi-ellipsoidal Nanoparticles
For advanced applications in modern industry it is very important to reduce
the volume of ferroelectric nanoparticles without serious deterioration of
their polar properties. In many practically important cases fixed volume
(rather than fixed size) corresponds to realistic technological conditions of
nanoparticles fabrication. The letter is focused on the theoretical study of
the behavior of ferroelectric polarization, paramagnetoelectric coefficient and
phase diagrams of semi-ellipsoidal nanoparticles with fixed volume V. Our
approach combines the Landau-Ginzburg-Devonshire phenomenology, classical
electrostatics and elasticity theory. Our results show that the size effects of
the phase diagrams and polarization of semi-ellipsoidal BiFeO3 nanoparticles
nontrivially depends on V. These findings provide a path to optimize the polar
properties of nanoparticles by controlling their phase diagrams at a fixed
volume.Comment: 15 pages, 5 figures, we added the section IV. Paramagnetoelectric
(PME) coefficient at fixed volume in this version and changed title and
abstract accordingl
Domain wall conduction in multiaxial ferroelectrics
The conductance of domain wall structures consisting of either stripes or
cylindrical domains in multi-axial ferroelectric-semiconductors is analyzed.
The effects of the domain size, wall tilt and curvature, on charge
accumulation, are analyzed using the Landau-Ginsburg Devonshire (LGD) theory
for polarization combined with Poisson equation for charge distributions. Both
the classical ferroelectric parameters including expansion coefficients in
2-4-6 Landau potential and gradient terms, as well as flexoelectric coupling,
inhomogeneous elastic strains and electrostriction are included in the present
analysis. Spatial distributions of the ionized donors, free electrons and holes
were found self-consistently using the effective mass approximation for the
respective densities of states. The proximity and size effect of the electron
and donor accumulation/depletion by thin stripe domains and cylindrical
nanodomains are revealed. In contrast to thick domain stripes and thicker
cylindrical domains, in which the carrier accumulation (and so the static
conductivity) sharply increases at the domain walls only, small nanodomains of
radius less then 5-10 correlation length appeared conducting across entire
cross-section. Implications of such conductive nanosized channels may be
promising for nanoelectronics.Comment: 39 pages, 11 figures, 3 tables, 4 appendice
Direct Observation of an Interface Dipole between Two Metallic Oxides Caused by Localized Oxygen Vacancies
Oxygen vacancies are increasingly recognized to play a role in phenomena
observed at transition-metal oxide interfaces. Here we report a study of
SrRuO3/La0.7Sr0.3MnO3 (SRO/LSMO) interfaces using a combination of quantitative
aberration-corrected scanning transmission electron microscopy, electron energy
loss spectroscopy, and density-functional calculations. Cation displacements
are observed at the interface, indicative of a dipole-like electric field even
though both materials are nominally metallic. The observed displacements are
reproduced by theory if O vacancies are present in the near-interface LSMO
layers. The results suggest that atomic-scale structural mapping can serve as a
quantitative indicator of the presence of O vacancies at interfaces