1 research outputs found
Pressure Effect Studies on the Spin Transition of Microporous 3D Polymer [Fe(pz)Pt(CN)<sub>4</sub>]
Pressure effects
on the spin transition of the three-dimensional (3D) porous coordination
polymer {FeĀ(pz)Ā[PtĀ(CN)<sub>4</sub>]} have been investigated in the
interval 10<sup>5</sup> Paā1.0 GPa through variable-temperature
(10ā320 K) magnetic susceptibility measurements and spectroscopic
studies in the visible region at room temperature. These studies have
disclosed a different behavior of the compound under pressure. In
the magnetic experiments, a temperature independent paramagnetic behavior
has been observed under 0.4 GPa. In contrast, at room temperature
and at 0.8 GPa, a complete HS-to-LS transition has been evidenced.
The differences in the magnetic behavior are strongly related with
the porous structure of the compound and its capability to adsorb
the oil used as pressure transmission media in the magnetic experiments