Dielectric and thermal relaxation in the energy landscape

We derive an energy landscape interpretation of dielectric relaxation times in undercooled liquids, comparing it to the traditional Debye and Gemant-DiMarzio-Bishop pictures. The interaction between different local structural rearrangements in the energy landscape explains qualitatively the recently observed splitting of the flow process into an initial and a final stage. The initial mechanical relaxation stage is attributed to hopping processes, the final thermal or structural relaxation stage to the decay of the local double-well potentials. The energy landscape concept provides an explanation for the equality of thermal and dielectric relaxation times. The equality itself is once more demonstrated on the basis of literature data for salol.Comment: 7 pages, 3 figures, 41 references, Workshop Disordered Systems, Molveno 2006, submitted to Philosophical Magazin

The mixed convolved action

A series of stationary principles are developed for dynamical systems by formulating the concept of mixed convolved action, which is written in terms of mixed variables, using temporal convolutions and fractional derivatives. Dynamical systems with discrete and continuous spatial representations are considered as initial applications. In each case, a single scalar functional provides the governing differential equations, along with all the pertinent initial and boundary conditions, as the Euler-Lagrange equations emanating from the stationarity of this mixed convolved action. Both conservative and non-conservative processes can be considered within a common framework, thus resolving a long-standing limitation of variational approaches for dynamical systems. Several results in fractional calculus also are developed