Single crystal growth and anisotropy of CeRuPO

We report on the single crystal growth of the ferromagnetic Kondo lattice system CeRuPO using a Sn flux method. Magnetic susceptibility and electrical resistivity measurements indicate strong anisotropy of this structurally layered compound. They evidence that the magnetic moments order ferromagnetically along the c-direction of the tetragonal unit cell, whereas the crystal electric field (CEF) anisotropy favors the ab-plane. Therefore, CeRuPO presents the unusual case within rare earth systems, where the anisotropy of the interionic exchange interaction overcomes the single ion anisotropy due to the CEF interaction.Comment: 13 pages, 7 figures, high quality figures: http://www.cpfs.mpg.de/~krellner

Magnetic field dependence of the antiferromagnetic phase transitions in Co-doped YbRh_2Si_2

We present first specific-heat data of the alloy Yb(Rh_(1-x)Co_x)_2Si_2 at intermediate Co-contents x=0.18, 0.27, and 0.68. The results already point to a complex magnetic phase diagram as a function of composition. Co-doping of YbRh_2Si_2 (T_N^{x=0}=72 mK) stabilizes the magnetic phase due to the volume decrease of the crystallographic unit cell. The magnetic phase transitions are clearly visible as pronounced anomalies in C^{4f}(T)/T and can be suppressed by applying a magnetic field. Going from x=0.18 to x=0.27 we observe a change from two mean-field (MF) like magnetic transitions at T_N^{0.18}=1.1 K and T_L^{0.18}=0.65 K to one sharp \lambda-type transition at T_N^{0.27}=1.3 K. Preliminary measurements under magnetic field do not confirm the field-induced first-order transition suggested in the literature. For x=0.68 we find two transitions at T_N^{0.68}=1.14 K and T_L^{0.68}=1.06 K.Comment: Accepted for the ICM proceedings 200

Magnetization study on the field-induced quantum critical point in YbRh_2Si_2

We study the field-induced quantum critical point (QCP) in YbRh$_2$Si$_2$ by low-temperature magnetization, $M(T)$, and magnetic Gr\"uneisen ratio, $\Gamma_{\rm mag}$, measurements and compare the results with previous thermal expansion, $\beta(T)$, and critical Gr\"uneisen ratio, $\Gamma^{cr}(T)$, data on YbRh$_2$(Si$_{0.95}$Ge$_{0.05}$)$_2$. In the latter case, a slightly negative chemical pressure has been used to tune the system towards its zero-field QCP. The magnetization derivative $-dM/dT$ is far more singular than thermal expansion, reflecting a strongly temperature dependent pressure derivative of the field at constant entropy, $(dH/dP)_S=V_m\beta/(dM/dT)$ ($V_m$: molar volume), which saturates at $(0.15\pm 0.04)$ T/GPa for $T\to 0$. The line $T^\star(H)$, previously observed in Hall- and thermodynamic measurements, separates regimes in $T$-$H$ phase space of stronger $(\epsilon>1$) and weaker $(\epsilon<1$) divergent $\Gamma_{\rm mag}(T)\propto T^{-\epsilon}$.Comment: 4 Pages, 3 Figures, submitted to Proceedings of ICM 2009 (Karlsruhe

Electron Spin Resonance of the Yb 4f moment in Yb(Rh1-xCox)2Si2

[published in Phys. Rev. B 85, 035119 (2012)] The evolution of spin dynamics from the quantum critical system YbRh2Si2 to the stable trivalent Yb system YbCo2Si2 was investigated by Electron Spin Resonance (ESR) spectroscopy. While the Kondo temperature changes by one order of magnitude, all compositions of the single crystalline series Yb(Rh1-xCox)2Si2 show well defined ESR spectra with a clear Yb3+ character for temperatures below \approx 20 K. With increasing Co-content the ESR g-factor along the c-direction strongly increases indicating a continuous change of the ground state wave function and, thus, a continuous change of the crystal electric field. The linewidth presents a complex dependence on the Co-content and is discussed in terms of the Co-doping dependence of the Kondo interaction, the magnetic anisotropy and the influence of ferromagnetic correlations between the 4f states. The results provide evidence that, for low Co-doping, the Kondo interaction allows narrow ESR spectra despite the presence of a large magnetic anisotropy, whereas at high Co-concentrations, the linewidth is controlled by ferromagnetic correlations. A pronounced broadening due to critical correlations at low temperatures is only observed at the highest Co-content. This might be related to the presence of incommensurate magnetic fluctuations.Comment: 8 pages, 8 Figure

Ferromagnetic quantum critical fluctuations in YbRh_2(Si_{0.95}Ge_{0.05})_2

The bulk magnetic susceptibility $\chi(T,B)$ of YbRh$_2$(Si$_{0.95}$Ge$_{0.05}$)$_2$ has been investigated %by ac-and dc-magnetometry at low temperatures and close to the field-induced quantum critical point at $B_c=0.027$ T. For $B\leq 0.05$ T a Curie-Weiss law with a negative Weiss temperature is observed at temperatures below 0.3 K. Outside this region, the susceptibility indicates ferromagnetic quantum critical fluctuations: $\chi(T)\propto T^{-0.6}$ above 0.3 K, while at low temperatures the Pauli susceptibility follows $\chi_0\propto (B-B_c)^{-0.6}$ and scales with the coefficient of the $T^2$ term in the electrical resistivity. The Sommerfeld-Wilson ratio is highly enhanced and increases up to 30 close to the critical field.Comment: Physical Review Letters, to be publishe

Single crystal growth and anisotropy of CeRuPO

We report on the single crystal growth of the ferromagnetic Kondo lattice system CeRuPO using a Sn flux method. Magnetic susceptibility and electrical resistivity measurements indicate strong anisotropy of this structurally layered compound. They evidence that the magnetic moments order ferromagnetically along the c-direction of the tetragonal unit cell, whereas the crystal electric field (CEF) anisotropy favors the ab-plane. Therefore, CeRuPO presents the unusual case within rare earth systems, where the anisotropy of the interionic exchange interaction overcomes the single ion anisotropy due to the CEF interaction.Comment: 13 pages, 7 figures, high quality figures: http://www.cpfs.mpg.de/~krellner

Magnetic anisotropy of YbNi4P2

We report on transport and magnetic measurements between 1.8 and 400 K on single crystalline YbNi4P2, which was recently reported to be a heavy fermion system with a low lying ferromagnetic transition at T_C=0.17 K, based on data from polycrystals. The tetragonal crystal structure of YbNi4P2 presents quasi-one-dimensional Yb chains along the c direction. Here we show that at high temperatures, the magnetic anisotropy of YbNi4P2 is dominated by the crystal electrical field effect with an Ising-type behaviour, which gets more pronounced towards lower temperatures. The electrical resistivity also reflects the strong anisotropy of the crystal structure and favours transport along c, the direction of the Yb chains.Comment: SCES 2011 proceedings, in pres

Avoided ferromagnetic quantum critical point in CeRuPO

CeRuPO is a rare example of a ferromagnetic (FM) Kondo-lattice system. External pressure suppresses the ordering temperature to zero at about $p_c\approx3$ GPa. Our ac-susceptibility and electrical-resistivity investigations evidence that the type of magnetic ordering changes from FM to antiferromagnetic (AFM) at about $p^*\approx0.87$ GPa. Studies in applied magnetic fields suggest that ferromagnetic and antiferromagnetic correlations compete for the ground state at $p>p^*$, but finally the AFM correlations win. The change in the magnetic ground-state properties is closely related to the pressure evolution of the crystalline-electric-field level (CEF) scheme and the magnetic Ruderman-Kittel-Kasuya-Yosida (RKKY) exchange interaction. The N\'{e}el temperature disappears abruptly in a first-order-like fashion at $p_c$, hinting at the absence of a quantum critical point. This is consistent with the low-temperature transport properties exhibiting Landau-Fermi-liquid (LFL) behavior in the whole investigated pressure range up to 7.5 GPa.Comment: 12 figure