2 research outputs found
Charge Transfer and excitations in AgF
Charge transfer (CT) insulators are the parent phase of a large group of
today's unconventional high temperature superconductors. Here we study
experimentally and theoretically the interband excitations of the CT insulator
silver fluoride AgF, which has been proposed as an excellent analogue of
oxocuprates. Optical conductivity and resonant inelastic x-ray scattering
(RIXS) on AgF polycrystalline sample show a close similarity with that
measured on undoped LaCuO. While the former shows a CT gap
3.4~eV, larger than in the cuprate, -excitations are nearly at the
same energy in the two materials. DFT and exact diagonalization cluster
computations of the multiplet spectra show that AgF is more covalent than
the cuprate, in spite of the larger fundamental gap. Furthermore, we show that
AgF is at the verge of a charge transfer instability. The overall
resemblance of our data on AgF to those published previously on
LaCuO suggests that the underlying CT insulator physics is the same,
while AgF could also benefit from a proximity to a charge density wave
phase as in BaBiO. Therefore, our work provides a compelling support to the
future use of fluoroargentates for materials' engineering of novel
high-temperature superconductors.Comment: 13 pages, 9 Figures (including SI
Open Data to "Charge-Transfer and dd excitations in AgF2"
AbstractData set corresponding to a published paper
Journal: Phys. Rev. Research 4, 023108 (2022)
DOI: 10.1103/PhysRevResearch.4.02310