Atmospheric Chemistry Over Southern Africa

During the southern African dry season, regional haze from mixed industrial pollution, biomass burning aerosol and gases from domestic and grassland fires, and biogenic sources from plants and soils is worsened by a semi-permanent atmosphere gyre over the subcontinent. These factors were a driver of several major international field campaigns in the 1990s and early 2000s, and attracted many scientists to the region. Some researchers were interested in understanding fundamental processes governing chemistry of the atmosphere and interaction with climate change. Others found favorable conditions for evaluating satellite-derived measurements of atmospheric properties and a changing land surface. With that background in mind a workshop on atmospheric chemistry was held in South Africa. Sponsored by the International Commission for Atmospheric Chemistry and Global Pollution (ICACGP; http://www.icacgp.org/), the workshop received generous support from the South African power utility, Eskom, and the Climatology Research Group of the University of the Witwatersrand, Johannesburg, South Africa. The purpose of the workshop was to review some earlier findings as well as more recent findings on southern African climate vulnerability, chemical changes due to urbanization, land-use modification, and how these factors interact. Originally proposed by John Burrows, president of ICACGP, the workshop was the first ICACGP regional workshop to study the interaction of air pollution with global chemical and climate change. Organized locally by the University of the Witwatersrand, the workshop attracted more than 60 delegates from South Africa, Mozambique, Botswana, Zimbabwe, France, Germany, Canada, and the United States. More than 30 presentations were given, exploring both retrospective and prospective aspects of the science. In several talks, attention was focused on southern African chemistry, atmospheric pollution monitoring, and climate processes as they were studied in the field campaigns such as Transport and Atmospheric Chemistry Near the Equator-Atlantic (TRACE-A), Southern African Fire-Atmosphere Research Initiative (SAFARI-92), and Southern African Regional Science Initiative (SAFARI 2000). Since those large international efforts, satellites have matured enough to enable quantifiable measurements of regional land surface, atmosphere, and ocean. In addition, global and chemical transport models have also been advanced to incorporate various data. Thus, the timing of the workshop was right for a full-fledged re-assessment of the chemistry, physics, and socio-economical impacts caused by pollution in the region, including a characterization of sources, deposition, and feedbacks with climate change

Taking the Pulse of PyroCumulus Clouds

Forest fires can burn large areas, but can also inject smoke into the upper troposphere/lower stratosphere (UT/LS), where stakes are even higher for climate, because emissions tend to have a longer lifetime, and can produce significant regional and even global climate effects, as is the case with some volcanoes. Large forest fires are now believed to be more common in summer, especially in the boreal regions, where pyrocumulus (pyroCu), and occasionally pyrocumuionimbus (pyroCb) clouds are formed, which can transport emissions into the UT/LS. A major difficulty in developing realistic fire plume models is the lack of observational data within fire plumes that resolves structure at a few 100 m scales, which can be used to validate these models. Here, we report detailed airborne radiation measurements within strong pyroCu taken over boreal forest fires in Saskatchewan, Canada during the Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS) summer field campaign in 2008. We find that the angular distribution of radiance within the pyroCu is closely related to the diffusion domain in water clouds and can be described by very similar simple cosine functions. We demonstrate with Monte Carlo simulations that radiation transport in pyroCu is inherently a 3D phenomenon and must account for particle absorption. However, the simple cosine function promises to offer an easy solution for climate models. The presence of a prominent smoke core, defined by strong extinction in the UV, VIS and NIR, suggests that the core might be an important pathway for emission transport to the upper troposphere and lower stratosphere. We speculate that this plume injection core is generated and sustained by complex processes not yet well understood, but not necessarily related directly to the intense fires that originally initiated the plume rise

Surface Albedo Darkening from wildfires in Northern Sub-Saharan Africa

Wildfires are recognized as a key physical disturbance of terrestrial ecosystems and a major source of atmospheric trace gases and aerosols. They are known to produce changes in landscape patterns and lead to changes in surface albedo that can persist for long periods. Here, we estimate the darkening of surface albedo due to wildfires in different land cover ecosystems in the Northern Sub-Saharan Africa using data from the Moderate Resolution Imaging Spectroradiometer (MODIS). We determined a decrease in albedo after fires over most land cover types (e.g. woody savannas: (-0.00352 0.00003) and savannas: (- 0.003910.00003), which together accounted for >86% of the total MODIS fire count between 2003 and 2011). Grasslands had a higher value (-0.00454 0.00003) than the savannas, but accounted for only about 5% of the total fire count. A few other land cover types (e.g. Deciduous broad leaf: (0.00062 0.00015), and barren: 0.00027 0.00019), showed an increase in albedo after fires, but accounted for less than 1% of the total fires. Albedo change due to wildfires is more important during the fire season (October-February). The albedo recovery progresses rapidly during the first year after fires, where savannas show the greatest recovery (>77%) within one year, while deciduous broadleaf, permanent wetlands and barren lands show the least one-year recovery (56%). The persistence of surface albedo darkening in most land cover types is limited to about six to seven years, after which at least 98% of the burnt pixels recover to their pre-fire albedo

Simultaneous Retrieval of Aerosol and Surface Optical Properties from Combined Airborne- and Ground-Based Direct and Diffuse Radiometric Measurements

This paper presents a new method for simultaneously retrieving aerosol and surface reflectance properties from combined airborne and ground-based direct and diffuse radiometric measurements. The method is based on the standard Aerosol Robotic Network (AERONET) method for retrieving aerosol size distribution, complex index of refraction, and single scattering albedo, but modified to retrieve aerosol properties in two layers, below and above the aircraft, and parameters on surface optical properties from combined datasets (Cloud Absorption Radiometer (CAR) and AERONET data). A key advantage of this method is the inversion of all available spectral and angular data at the same time, while accounting for the influence of noise in the inversion procedure using statistical optimization. The wide spectral (0.34-2.30 m) and angular range (180 ) of the CAR instrument, combined with observations from an AERONET sunphotometer, provide sufficient measurement constraints for characterizing aerosol and surface properties with minimal assumptions. The robustness of the method was tested on observations made during four different field campaigns: (a) the Southern African Regional Science Initiative 2000 over Mongu, Zambia, (b) the Intercontinental Transport Experiment-Phase B over Mexico City, Mexico (c) Cloud and Land Surface Interaction Campaign over the Atmospheric Radiation Measurement (ARM) Central Facility, Oklahoma, USA, and (d) the Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS) over Elson Lagoon in Barrow, Alaska, USA. The four areas are dominated by different surface characteristics and aerosol types, and therefore provide good test cases for the new inversion method

Sensitivity of MODIS 2.1-(micrometers) Channel for Off-Nadir View Angles for Use in Remote Sensing of Aerosol

In this sensitivity study, we examined the ratio technique, the official method for remote sensing of aerosols over land from Moderate Resolution Imaging Spectroradiometer (MODIS) DATA, for view angles from nadir to 65 deg. off-nadir using Cloud Absorption Radiometer (CAR) data collected during the Smoke, Clouds, and Radiation-Brazil (SCAR-B) experiment conducted in 1995. For the data analyzed and for the view angles tested, results seem to suggest that the reflectance (rho)0.47 and (rho)0.67 are predictable from (rho)2.1 using: (rho)0.47 = (rho)2.1/6, which is a slight modification and (rho)0.67 = (rho)2.1/2. These results hold for target viewed from backscattered direction, but not for the forward direction

Evaluation of MISR Land Surface BRF Measurements: Intercomparison with Coincident Airborne and Ground Field Measurements

The bidirectional reflectance factor, BRF, retrieved by the Multiangle Imaging SpectroRadiometer, MISR, is compared with those coincidently measured from aircraft, by the Cloud Absorption Radiometer, CAR, and MISR airborne simulator, AirMISR, and on the ground, by the Portable Apparatus for Rabid Acquisition of Bidirectional Observations of Land and Atmosphere, PARABOLA Ill. The intercomparisons are made for six types of surfaces: bright desert, salt pans, grassland, forests, snow and the Dismal Swamp. The results show that MISR BRF values are mostly within +/- 10% in agreement with the corresponding airborne and ground measurements, independent of the surface types This study is part of an effort to evaluate and validate MISR surface products

Analysis of Snow Bidirectional Reflectance from ARCTAS Spring-2008 Campaign

The spring 2008 Arctic Research of the Composition of the Troposphere from Aircraft and Satellites (ARCTAS) experiment was one of major intensive field campaigns of the International Polar Year aimed at detailed characterization of atmospheric physical and chemical processes in the Arctic region. A part of this campaign was a unique snow bidirectional reflectance experiment on the NASA P-3B aircraft conducted on 7 and 15 April by the Cloud Absorption Radiometer (CAR) jointly with airborne Ames Airborne Tracking Sunphotometer (AATS) and ground-based Aerosol Robotic Network (AERONET) sunphotometers. The CAR data were atmospherically corrected to derive snow bidirectional reflectance at high 1 degree angular resolution in view zenith and azimuthal angles along with surface albedo. The derived albedo was generally in good agreement with ground albedo measurements collected on 15 April. The CAR snow bidirectional reflectance factor (BRF) was used to study the accuracy of analytical Ross-Thick Li-Sparse (RTLS), Modified Rahman-Pinty-Verstraete (MRPV) and Asymptotic Analytical Radiative Transfer (AART) BRF models. Except for the glint region (azimuthal angles phi less than 40 degrees), the best fit MRPV and RTLS models fit snow BRF to within 0.05. The plane-parallel radiative transfer (PPRT) solution was also analyzed with the models of spheres, spheroids, randomly oriented fractal crystals, and with a synthetic phase function. The latter merged the model of spheroids for the forward scattering angles with the fractal model in the backscattering direction. The PPRT solution with synthetic phase function provided the best fit to measured BRF in the full range of angles. Regardless of the snow grain shape, the PPRT model significantly over-/underestimated snow BRF in the glint/backscattering regions, respectively, which agrees with other studies. To improve agreement with experiment, we introduced a model of macroscopic snow surface roughness by averaging the PPRT solution over the slope distribution function and by adding a simple model of shadows. With macroscopic roughness described by two parameters, the AART model achieved an accuracy of about plus or minus 0.05 with a possible bias of plus or minus 0.03 in the spectral range 0.4-2.2 micrometers. This high accuracy holds at view zenith angles below 55-60 degrees covering the practically important range for remote sensing applications, and includes both glint and backscattering directions

MOD06 Optical and Microphysical Retrievals

Major efforts over the past six months included: (1) submission of MOD06 Optical and Microphysical Retrieval recompetition proposal, (2) delivery of a MODIS Atmosphere Level-3 update, (3) delivery of the MODIS Atmosphere s new combined Level-2 product, (4) development of an above-cloud precipitable water research algorithm and a multi-layer cloud detection algorithm, (5) continued development of a Fortran 90 version of the retrieval code for use with MAS as well as operational MODIS processing, (6) preliminary analysis of CRYSTAL-FACE field experiment in July 2002, (7) continued analysis of data obtained during the SAFARI 2000 dry season campaign in southern Africa, and the Arctic FIRE-ACE experiment