47 research outputs found
Solid-State and Gas-Phase Structures and Energetic Properties of the Dangerous Methyl and Fluoromethyl Nitrates
Reichel M, Krumm B, Vishnevskiy Y, et al. Solid-State and Gas-Phase Structures and Energetic Properties of the Dangerous Methyl and Fluoromethyl Nitrates. Angewandte Chemie (International ed. in English). 2019;58(51):18557-18561.An improved synthesis of the simplest nitric acid ester, methyl nitrate, and a new synthesis of fluoromethyl nitrate use the metathesis of the corresponding iodomethanes with silver nitrate. Both compounds were identified by spectroscopy and the structures determined for in situ grown crystals by X-ray diffraction as well as in the gas phase by electron diffraction. Fluorination leads to structures with shorter C-O and N-O bonds, has an energetically destabilizing effect and increases friction sensitivity, but decreases detonation performance. © 2019 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA
The Chemical Composition of Carbon-Rich, Very Metal-Poor Stars: A New Class of Mildly Carbon-Rich Objects Without Excess of Neutron-Capture Elements
We report on an analysis of the chemical composition of five carbon-rich,
very metal-poor stars based on high-resolution spectra. One star, CS22948-027,
exhibits very large overabundances of carbon, nitrogen, and the neutron-capture
elements, as found in the previous study of Hill et al.. This result may be
interpreted as a consequence of mass transfer from a binary companion that
previously evolved through the asymptotic giant branch stage. By way of
contrast, the other four stars we investigate exhibit no overabundances of
barium ([Ba/Fe]<0), while three of them have mildly enhanced carbon and/or
nitrogen ([C+N]+1). We have been unable to determine accurate carbon and
nitrogen abundances for the remaining star (CS30312-100). These stars are
rather similar to the carbon-rich, neutron-capture-element-poor star
CS22957-027 discussed previously by Norris et al., though the carbon
overabundance in this object is significantly larger ([C/Fe]=+2.2). Our results
imply that these carbon-rich objects with ``normal'' neutron-capture element
abundances are not rare among very metal-deficient stars. One possible process
to explain this phenomenon is as a result of helium shell flashes near the base
of the AGB in very low-metallicity, low-mass (M~< 1M_sun) stars, as recently
proposed by Fujimoto et al..
The moderate carbon enhancements reported herein ([C/Fe]+1) are similar to
those reported in the famous r-process-enhanced star CS22892-052. We discuss
the possibility that the same process might be responsible for this similarity,
as well as the implication that a completely independent phenomenon was
responsible for the large r-process enhancement in CS22892-052.Comment: 53 pages, 8 figures, to appear in Ap
Effects of cocaine and levamisole (as adulterant) on the isolated perfused Langendorff heart
Cocaine-related deaths occur regularly in forensic routine work. In cases in which the detected concentration of cocaine is rather low and other causes of death apart from intoxication can be ruled out, the question arises if adulterants of cocaine might have played a crucial role. In the present study, cardiac effects of cocaine, of the adulterant levamisole and of mixtures of both were evaluated using the isolated perfused Langendorff heart. While exposed to the substances, functional parameters heart rate, left ventricular pressure and coronary flow were documented. Relevant alterations of these parameters were found for cocaine as well as for levamisole. Exposing the hearts to a mixture of both resulted in a combination of these effects; the emergence of new alterations or an obvious aggravation were not detected. Nevertheless, the results imply that the consumption of cocaine adulterated with levamisole bares an increased risk for cardiac complications, especially in the presence of preexisting cardiac pathologies
Festkörper‐ und Gasphasenstrukturen sowie energetische Eigenschaften des gefährlichen Methyl‐ und Fluormethylnitrats
Reichel M, Krumm B, Vishnevskiy YV, et al. Festkörper‐ und Gasphasenstrukturen sowie energetische Eigenschaften des gefährlichen Methyl‐ und Fluormethylnitrats. Angewandte Chemie. 2019;131(51):18730-18734