Radiocarbon dating of methane and carbon dioxide evaded from a temperate peatland stream

Streams draining peatlands export large quantities of carbon in different chemical forms and are an important part of the carbon cycle. Radiocarbon (14C) analysis/dating provides unique information on the source and rate that carbon is cycled through ecosystems, as has recently been demonstrated at the air-water interface through analysis of carbon dioxide (CO2) lost from peatland streams by evasion (degassing). Peatland streams also have the potential to release large amounts of methane (CH4) and, though 14C analysis of CH4 emitted by ebullition (bubbling) has been previously reported, diffusive emissions have not. We describe methods that enable the 14C analysis of CH4 evaded from peatland streams. Using these methods, we investigated the 14C age and stable carbon isotope composition of both CH4 and CO2 evaded from a small peatland stream draining a temperate raised mire. Methane was aged between 1617-1987 years BP, and was much older than CO2 which had an age range of 303-521 years BP. Isotope mass balance modelling of the results indicated that the CO2 and CH4 evaded from the stream were derived from different source areas, with most evaded CO2 originating from younger layers located nearer the peat surface compared to CH4. The study demonstrates the insight that can be gained into peatland carbon cycling from a methodological development which enables dual isotope (14C and 13C) analysis of both CH4 and CO2 collected at the same time and in the same way

A priori estimates for the Hill and Dirac operators

Consider the Hill operator $Ty=-y''+q'(t)y$ in $L^2(\R)$, where $q\in L^2(0,1)$ is a 1-periodic real potential. The spectrum of $T$ is is absolutely continuous and consists of bands separated by gaps \g_n,n\ge 1 with length |\g_n|\ge 0. We obtain a priori estimates of the gap lengths, effective masses, action variables for the KDV. For example, if \m_n^\pm are the effective masses associated with the gap \g_n=(\l_n^-,\l_n^+), then |\m_n^-+\m_n^+|\le C|\g_n|^2n^{-4} for some constant $C=C(q)$ and any $n\ge 1$. In order prove these results we use the analysis of a conformal mapping corresponding to quasimomentum of the Hill operator. That makes possible to reformulate the problems for the differential operator as the problems of the conformal mapping theory. Then the proof is based on the analysis of the conformal mapping and the identities. Moreover, we obtain the similar estimates for the Dirac operator

Optical excitations in organic molecules, clusters and defects studied by first-principles Green's function methods

Spectroscopic and optical properties of nanosystems and point defects are discussed within the framework of Green's function methods. We use an approach based on evaluating the self-energy in the so-called GW approximation and solving the Bethe-Salpeter equation in the space of single-particle transitions. Plasmon-pole models or numerical energy integration, which have been used in most of the previous GW calculations, are not used. Fourier transforms of the dielectric function are also avoided. This approach is applied to benzene, naphthalene, passivated silicon clusters (containing more than one hundred atoms), and the F center in LiCl. In the latter, excitonic effects and the $1s \to 2p$ defect line are identified in the energy-resolved dielectric function. We also compare optical spectra obtained by solving the Bethe-Salpeter equation and by using time-dependent density functional theory in the local, adiabatic approximation. From this comparison, we conclude that both methods give similar predictions for optical excitations in benzene and naphthalene, but they differ in the spectra of small silicon clusters. As cluster size increases, both methods predict very low cross section for photoabsorption in the optical and near ultra-violet ranges. For the larger clusters, the computed cross section shows a slow increase as function of photon frequency. Ionization potentials and electron affinities of molecules and clusters are also calculated.Comment: 9 figures, 5 tables, to appear in Phys. Rev. B, 200

High Carbon in I Zwicky 18: New Results from Hubble Space Telescope Spectroscopy

We present new measurements of the gas-phase C/O abundance ratio in both the NW and SE components of the extremely metal-poor dwarf irregular galaxy I Zw 18, based on ultraviolet spectroscopy of the two H II regions using the Faint Object Spectrograph on the Hubble Space Telescope. We determine values of log C/O = -0.63 +/- 0.10 for the NW component and log C/O = -0.56 +/- 0.09 for the SE component. In comparison, log C/O = -0.37 in the sun, while log C/O = -0.85 +/- 0.07 in the three most metal-poor irregular galaxies measured by Garnett et al. (1995a). Our measurements show that C/O in I Zw 18 is significantly higher than in other comparably metal-poor irregular galaxies, and above predictions for the expected C/O from massive star nucleosynthesis. These results suggest that carbon in I Zw 18 has been enhanced by an earlier population of lower-mass carbon producing stars; this idea is supported by stellar photometry of I Zw 18 and its companion, which demonstrate that the current bursts of massive stars were not the first. Despite its very low metallicity, it is likely that I Zw 18 is not a ``primeval'' galaxy.Comment: 14 pages including 4 figures; uses aaspp4.sty. Accepted for publication in ApJ. Postscript version also available by e-mail request to author at [email protected]

Impact of increasing vegetarian availability on meal selection and sales in cafeterias.

Shifting people in higher income countries toward more plant-based diets would protect the natural environment and improve population health. Research in other domains suggests altering the physical environments in which people make decisions ("nudging") holds promise for achieving socially desirable behavior change. Here, we examine the impact of attempting to nudge meal selection by increasing the proportion of vegetarian meals offered in a year-long large-scale series of observational and experimental field studies. Anonymized individual-level data from 94,644 meals purchased in 2017 were collected from 3 cafeterias at an English university. Doubling the proportion of vegetarian meals available from 25 to 50% (e.g., from 1 in 4 to 2 in 4 options) increased vegetarian meal sales (and decreased meat meal sales) by 14.9 and 14.5 percentage points in the observational study (2 cafeterias) and by 7.8 percentage points in the experimental study (1 cafeteria), equivalent to proportional increases in vegetarian meal sales of 61.8%, 78.8%, and 40.8%, respectively. Linking sales data to participants' previous meal purchases revealed that the largest effects were found in the quartile of diners with the lowest prior levels of vegetarian meal selection. Moreover, serving more vegetarian options had little impact on overall sales and did not lead to detectable rebound effects: Vegetarian sales were not lower at other mealtimes. These results provide robust evidence to support the potential for simple changes to catering practices to make an important contribution to achieving more sustainable diets at the population level.NERC scolarshi

Carbon in Spiral Galaxies from Hubble Space Telescope Spectroscopy

We present measurements of the gas-phase C/O abundance ratio in six H II regions in the spiral galaxies M101 and NGC 2403, based on ultraviolet spectroscopy using the Faint Object Spectrograph on the Hubble Space Telescope. The C/O ratios increase systematically with O/H in both galaxies, from log C/O approximately -0.8 at log O/H = -4.0 to log C/O approx. -0.1 at log O/H = -3.4. C/N shows no correlation with O/H. The rate of increase of C/O is somewhat uncertain because of uncertainty as to the appropriate UV reddening law, and uncertainty in the metallicity dependence on grain depletions. However, the trend of increasing C/O with O/H is clear, confirming and extending the trend in C/O indicated previously from observations of irregular galaxies. Our data indicate that the radial gradients in C/H across spiral galaxies are steeper than the gradients in O/H. Comparing the data to chemical evolution models for spiral galaxies shows that models in which the massive star yields do not vary with metallicity predict radial C/O gradients that are much flatter than the observed gradients. The most likely hypothesis at present is that stellar winds in massive stars have an important effect on the yields and thus on the evolution of carbon and oxygen abundances. C/O and N/O abundance ratios in the outer disks of spirals determined to date are very similar to those in dwarf irregular galaxies. This implies that the outer disks of spirals have average stellar population ages much younger than the inner disks.Comment: 38 pages, 9 postscript figures, uses aaspp4.sty. Accepted for publication in The Astrophysical Journa

Gas-phase metallicity of 27 galaxies at intermediate redshift

The purpose of this work is to make available new gas-phase oxygen abundance measurements for a serendipitous sample of 27 galaxies with redshift 0.35<z<0.52. We measured the equivalent widths of the [O II]{\lambda}3727, H{\beta}, and [O III]{\lambda}{\lambda}4959, 5007 emission lines observed in the galaxy spectra obtained with the Visible Multi-Object Spectrograph mounted at the Very Large Telescope. For each galaxy, we derived the metallicity-sensitive emission lines ratio R23, ionization-sensitive emission lines ratio O32, and gas-phase oxygen abundance 12+log(O/H). The values of gas-phase oxygen abundance 12+log(O/H) we obtained for the sample galaxies are consistent with previous findings for galaxies at intermediate redshift.Comment: 5 pages, 3 postscript figures and 3 tables. A&A in pres

Qualitative Evaluation of Web-Based Digital Intervention to Prevent and Reduce Excessive Alcohol Use and Harm Among Young People Aged 14-15 Years: A "Think-Aloud" Study

BACKGROUND: In the United Kingdom, despite some downward trends in alcohol use among young people, over one-fifth of young people reported excessive alcohol use in the past month, which is associated with short- and long-term harm to health. Digital interventions to reduce alcohol use, such as websites, among young people present an appealing and cost-effective mode of intervention that can be integrated into the education system. However, relatively few school-based digital alcohol-focused interventions have been developed and evaluated for young people in the United Kingdom. OBJECTIVE: This study aims to develop a novel web-based intervention, Rethink Alcohol, to prevent and reduce excessive alcohol use and related harm among young people aged between 14 and 15 years, and explore the views of young people, teachers, and youth workers in relation to the content, design, and usability of the intervention. METHODS: Intervention development followed the person-based approach, using theories of social norms and social influence. Qualitative "Think-Aloud" interviews, either one-to-one or paired, were conducted while participants perused and worked through the web-based intervention, talking aloud. Participants included 20 young people (12 female, 8 male), 5 youth workers (4 female, 1 male), 3 teachers (2 male, 1 female), and 1 (male) clinical professional, recruited via youth groups and professional networks. Interviews were audio recorded, transcribed verbatim, and analyzed thematically. RESULTS: The prototype web-based intervention included normative feedback, information, a quiz, interactive activities, and scenarios. On a rating scale of impressions from poor (1) to excellent (5), participants gave an average score of 3.6/5. A total of 5 themes were identified: content, credibility of the website, making the website easy to understand, design and navigation, and suitability for the audience. These themes reflected views that the content was interesting, credible, informative, and embodied a neutral and nonjudgmental tone, but stronger messaging was needed regarding social pressures and short-term risks regarding safety and risk behavior alongside clarity around pathways of risk; credibility and trustworthiness of information were critical features, determined in part, by the professionalism of design and referencing of sources of information provided; and messages should be succinct and come to life through design and interactive features. CONCLUSIONS: Together, the data illustrated the importance and challenge of communicating nuanced alcohol-focused public health messages to young people in concise, clear, nonjudgmental, and appealing ways. Young people report interest in clear, credible, neutral, and interactive messages regarding social pressures and short-term risks of alcohol use via a web-based intervention. There is scope for optimization and feasibility testing of the Rethink Alcohol intervention

ISO SWS Observations of H II Regions in NGC 6822 and I ZW 36: Sulfur Abundances and Temperature Fluctuations

We report ISO SWS infrared spectroscopy of the H II region Hubble V in NGC 6822 and the blue compact dwarf galaxy I Zw 36. Observations of Br alpha, [S III] at 18.7 and 33.5 microns, and [S IV] at 10.5 microns are used to determine ionic sulfur abundances in these H II regions. There is relatively good agreement between our observations and predictions of S^+3 abundances based on photoionization calculations, although there is an offset in the sense that the models overpredict the S^+3 abundances. We emphasize a need for more observations of this type in order to place nebular sulfur abundance determinations on firmer ground. The S/O ratios derived using the ISO observations in combination with optical data are consistent with values of S/O, derived from optical measurements of other metal-poor galaxies. We present a new formalism for the simultaneous determination of the temperature, temperature fluctuations, and abundances in a nebula, given a mix of optical and infrared observed line ratios. The uncertainties in our ISO measurements and the lack of observations of [S III] lambda 9532 or lambda 9069 do not allow an accurate determination of the amplitude of temperature fluctuations for Hubble V and I Zw 36. Finally, using synthetic data, we illustrate the diagnostic power and limitations of our new method.Comment: 32 Pages total, including 6 encapsulated postscript figures (one with two parts). Accepted for Publication in the 20 Dec 2002 Ap