Determination of aqueous inclusion complexation constants and stoichiometry of alkyl(methyl)-methylimidazolium-based ionic liquid cations and neutral cyclodextrins by affinity capillary electrophoresis

Affinity CE (ACE) method was developed to characterize the complex formation between seven alkyl(methyl)methylimidazolium-based ionic liquid (IL) cations and eight neutral cyclodextrins (CD). The effective mobility data of the IL cations were processed according to classical nonlinear and linear treatments to obtain the complex stoichiometry and formation constant K. The majority of systems followed a 1:1 complexation stoichiometry model but in four cases a 1:2 stoichiometry was better satisfied. The K values obtained for each IL were compared to elucidate the main influences of IL and CD nature. The availability of these data should lend support to various application areas, including the screening and tailoring of new interactions in the solution for CE

BIOMOLECULAR INTERACTIONS BETWEEN SULFATED POLYSACCHARIDES AND PROTEINS: WELL SUITABILITY OF CAPILLARY ELECTROPHORESIS FOR THE DETERMINATION OF BINDING PARAMATER

Conférence du 06 au 11 Juillet 2003

Determination of Mo(VI)Zr(IV) interaction parameters in highly acidic solutions by UV absorbance spectrophotometry

International audienc

Investigation of Mo(VI) monomerdimer equilibrium in highly acidic solutions by UV absorbance spectroscopy using refined numerical processing

International audienc

Development of a Capillary Electrophoresis Assay Based on Free Sulfate Determination for the Direct Monitoring of Sulfoesterase Activity

International audienc

Séparation des isomères de position du fucose monosulfate par électrophorèse capillaire en milieu non aqueux avec détection par absorbance UV indirecte

Conférence du 13 au 15 Mai 200