Life cycle assessment of material footprint in recycling: A case of concrete recycling

Meeting the current demand for concrete requires not only mining tons of gravel and sand, but also burning large amounts of fossil fuel resources in cement kilning. Consequently, concrete recycling is crucial to achieving a material-efficient society, especially with the application of various categories of concrete and the goal of phasing out fossil fuels. A comparative life cycle assessment (LCA) is used to assess the engineering material footprint (EMF) and the fossil fuel material footprint (FMF) in closed-loop recycling of three types of concrete: siliceous concrete, limestone concrete, and lightweight aggregate concrete. This study aims to investigate the impact of (i) concrete categories, (ii) methods to model recycling, and (iii) using renewable energy sources on the material footprint in concrete recycling. The results highlight that the concrete recycling system can reduce 99% of the EMF and 66–93% of the FMF compared with the baseline system, in which concrete waste is landfilled. All three recycling modeling approaches indicate that concrete recycling can considerably reduce EMF and FMF compared with the baseline system, primarily resulting from the displacement of virgin raw materials. Using alternative diesels is more sensitive than adopting renewable electricity in reduction of the FMF in concrete recycling. Replacing diesel with electrolysis- and coal-based synthetic diesel for concrete recycling could even increase the FMF, while using biodiesel made from rapeseed and wood-based synthetic diesel can reduce 47–51% and 84–89% of the FMF, respectively, compared to the virgin diesel-based recycling system. Finally, we discussed the multifunctionality and rebound effects of recycling, and double-counting risk in material and energy accounting.Resources & Recyclin

Characterization and environmental risk assessment of heavy metals in construction and demolition wastes from five sources (chemical, metallurgical and light industries, and residential and recycled aggregates)

Total concentrations of heavy metals (Cu, Zn, Pb, Cr, Cd, and Ni) were measured among 63 samples of construction and demolition (C&D) wastes collected from chemical, metallurgical and light industries, and residential and recycled aggregates within China for risk assessment. The heavy metal contamination was primarily concentrated in the chemical and metallurgical industries, especially in the electroplating factory and zinc smelting plant. High concentrations of Cd were found in light industry samples, while the residential and recycled aggregate samples were severely polluted by Zn. Six most polluted samples were selected for deep research. Mineralogical analysis by X-ray fluorescence (XRF) spectrometry and X-ray diffraction (XRD), combined with element speciation through European Community Bureau of Reference (BCR) sequential extraction, revealed that a relatively slight corrosion happened in the four samples from electroplating plants but high transfer ability for large quantities of Zn and Cu. Lead arsenate existed in the acid extractable fraction in CI7-8 and potassium chromium oxide existed in the mobility fraction. High concentration of Cr could be in amorphous forms existing in CI9. The high content of sodium in the two samples from zinc smelter plants suggested severe deposition and erosion on the workshop floor. Large quantities of Cu existed as copper halide and most of the Zn appeared to be zinc, zinc oxide, barium zinc oxide, and zincite. From the results of the risk assessment code (RAC), the samples from the electroplating factory posed a very high risk of Zn, Cu, and Cr, a high risk of Ni, a middle risk of Pb, and a low risk of Cd. The samples from the zinc smelting plant presented a high risk of Zn, a middle risk of Cu, and a low risk of Pb, Cr, Cd, and Ni

Soil water depletion patterns of artificial forest species and ages on the Loess Plateau (China)

Afforestation as an effective measure to control soil erosion has achieved remarkable effects in northern China. However, large scale of artificial afforestation can increase soil water consumption and induce soil desiccation in arid and semi-arid areas. This study analyzed the variations of soil water storage following the conversion of croplands into forests with different species and stand ages on the Loess Plateau. Three most common artificial forests dominated by Salix matsudana, Populus cathayana, and Sophora japonica with stand ages of 5, 10, and 15 years were investigated to determine the variations in soil water storage. The results showed that soil water storage decreased with increasing afforestation ages and soil depth. Salix matsudana mainly consumed shallow soil water (0-100 cm), P. cathayana mainly consumed deep soil water (100-150 cm), while S. japonica had relatively lower water consumption than the other two species. Converting cropland into forest resulted in a significant water deficit. Soil water deficit in the 0-100 cm soil profiles was significantly higher under S. matsudana than under the other two artificial forests. Severe soil water depletion and obvious soil desiccation occurred after 12 years of afforestation. Therefore, artificial forests with less water consumption, e.g. S. japonica, should be given priority in future afforestation practice. To maintain the sustainability of vegetation, changes in land-use patterns should be considered after 12 years of afforestation