Diesel Exhaust Emissions and Mitigations

This chapter presents a concise treatment of diesel engine exhaust emissions and its mitigations. The working principle of the diesel engine is first given to establish the background and further to describe the influence of various parameters that affect the formation of engine exhaust emissions. The factors that influence exhaust emissions are linked to the engine design and the operating factors that promote good fuel-air mixing and combustion. These factors are air induction, fuel injection equipment, fuel injection schemes, in-cylinder gas exchange process and heat transfer. Thermochemistry essentially gives insight to the global reaction kinetics and how this is applied in practical engine combustion determinations in terms of equivalence ratios. Based on these, the fuel spray structure, atomization, penetration and the spray combustion model are described. The formation of exhaust emissions such as carbon monoxide, unburnt hydrocarbon and its intermediates, oxides of nitrogen and soot in diesel engines has been discussed. The techniques of their mitigation from the view of internal factors that deals with the optimization of engine design and it performance, as well as various exhaust after-treatment techniques used for NOx and soot reduction have been briefly discussed

Physics of puffing and microexplosion of emulsion fuel droplets

The physics of water-in-oil emulsion droplet microexplosion/puffing has been investigated using high-fidelity interface-capturing simulation. Varying the dispersed-phase (water) sub-droplet size/location and the initiation location of explosive boiling (bubble formation), the droplet breakup processes have been well revealed. The bubble growth leads to local and partial breakup of the parent oil droplet, i.e., puffing. The water sub-droplet size and location determine the after-puffing dynamics. The boiling surface of the water sub-droplet is unstable and evolves further. Finally, the sub-droplet is wrapped by boiled water vapor and detaches itself from the parent oil droplet. When the water sub-droplet is small, the detachment is quick, and the oil droplet breakup is limited. When it is large and initially located toward the parent droplet center, the droplet breakup is more extensive. For microexplosion triggered by the simultaneous growth of multiple separate bubbles, each explosion is local and independent initially, but their mutual interactions occur at a later stage. The degree of breakup can be larger due to interactions among multiple explosions. These findings suggest that controlling microexplosion/puffing is possible in a fuel spray, if the emulsion-fuel blend and the ambient flow conditions such as heating are properly designed. The current study also gives us an insight into modeling the puffing and microexplosion of emulsion droplets and sprays.This article has been made available through the Brunel Open Access Publishing Fund

Modeling temperature distribution inside an emulsion fuel droplet under convective heating: A key to predicting microexplosion and puffing

© 2016 by Begell House, Inc. Microexplosion/puffing is rapid disintegration of a water-in-oil emulsion droplet caused by explosive boiling of embedded superheated water sub-droplets. To predict microexplosion/puffing, modeling the temperature distribution inside an emulsion droplet under convective heating is a prerequisite, since the temperature field determines the location of nucleation (vapor bubble initiation from superheated water). In the first part of the present study, convective heating of water-in-oil emulsion droplets under typical combustor conditions is investigated using high-fidelity simulation in order to accurately model inner-droplet temperature distribution. The shear force due to the ambient air flow induces internal circulation inside a droplet. It has been found that for droplets under investigation in the present study, the liquid Peclet number PeL is in a transitional regime of 100 < PeL < 500. The temperature field is therefore somewhat distorted by the velocity field, but the distortion is not strong enough to form Hill's vortex for the temperature field. In the second part of the present study, a novel approach is proposed to model the temperature field distortion by introducing angular dependency of the thermal conductivity and eccentricity of the temperature field. The model can reproduce the main features of the temperature field inside an emulsion droplet, and can be used to predict the nucleation location, which is a key initial condition of microexplosion/puffing

Puffing-enhanced fuel/air mixing of an evaporating n-decane/ethanol emulsion droplet and a droplet group under convective heating

Pu ng of a decane/ethanol emulsion droplet and a droplet group under convective heating and its e ects on fuel/air mixing are investigated by direct numerical simulation (DNS) that resolves all the liquid/gas and liquid/liquid interfaces. With distinct di erences in the boiling point between decane and ethanol, the embedded ethanol subdroplets can be superheated and boil explosively. Pu ng, i.e. ejection of ethanol vapour, occurs from inside the parent decane droplet, causing secondary breakup of the droplet. The ejected ethanol vapour mixes with the outer gas mixture composed of air and vapour of the primary fuel decane, and its e ects on fuel/air mixing can be characterised by the scalar dissipation rates (SDRs). For the primary fuel SDR, the cross-scalar di usion due to ethanol vapour pu ng plays a dominant role in enhancing the micromixing. When the vapour ejection direction is inclined toward the wake direction, the wake is elongated, but the shape of the stoichiometric mixture fraction iso-surface is not changed much, indicating a limited e ect on droplet grouping in a spray. On the other hand, when the ejection direction is inclined toward the transverse direction, the stoichiometric surface is pushed further away in the transverse direction and its topology is changed by the pu ng. The trajectories of ejected ethanol vapour pockets can be predicted by the correlation obtained for a jet in cross ow, and the vapour pockets may reach a few diameters away from the droplet. Therefore, in a multiple-droplet con guration, the transverse ethanol vapour ejection due to pu ng may transiently change the droplet grouping characteristics. In simulation cases with multiple droplets, the interaction changing the droplet grouping due to pu ng has been con rmed, especially for droplets in the mostupstream position in a spray. This implies that pu ng should be accurately included in the mixing and combustion modelling of such a biofuel-blended diesel spray process.Financial support from the Engineering and Physical Sciences Research Council (EPSRC), grant No. EP/J018023/

Ramjet compression system for a hypersonic air transportation vehicle combined cycle engine

This report assesses the performance characteristics of a ramjet compression system in the application of a hypersonic vehicle. The vehicle is required to be self-powered and perform a complete flight profile using a combination of turbojet, ramjet and scramjet propulsion systems. The ramjet has been designed to operate between Mach 2.5 to Mach 5 conditions, allowing for start-up of the scramjet engine. Multiple designs, including varying ramp configurations and turbo-ramjet combinations, were investigated to evaluate their merits and limitations. Challenges arose with attempting to maintain sufficient pressure recoveries and favourable flow characteristics into the ramjet combustor. The results provide an engine inlet design capable of propelling the vehicle between the turbojet and scramjet phase of flight, allowing for the completion of its mission profile. Compromises in the design, however, had to be made in order to allow for optimisation of other propulsion systems including the scramjet nozzle and aerodynamics of the vehicle; it was concluded that these compromises were justified as the vehicle uses the ramjet engine for a minority of the flight profile as it transitions between low supersonic to hypersonic conditions

Non-thermal plasma system for marine diesel engine emissions control

Air pollutants generated by ships in both gaseous and particulate forms, have a long term effect on the quality of the environment and cause a significant exposure risk to people living in proximities of harbors or in neighboring coastal areas. It was recently estimated, that ships produce at least 15% of the world’s NOx (more than all of the world’s cars, buses and trucks combined), between 2.5 - 4% of greenhouse gases, 5% black carbon (BC), and between 3-7% of global SO2 output. Estimation of contribution of maritime shipping to global emissions of VOC and CO is not yet available. In order to reduce the environmental footprint of ships, the International Maritime Organization (IMO) recently issued the legislation of Marpol Annex VI guidelines which implies especially the introduction of, inter alia, stricter sulphur limits for marine fuel in ECAs under the revised MARPOL Annex VI, to 3.50% (from the current 4.50%), effective from 1 January 2012; then progressively to 0.50 %, effective from 1 January 2020, subject to a feasibility review to be completed no later than 2018. The limits applicable in Emission Control Zones (ECAs) for SOx and particulate matter were reduced to 1.00%, beginning on 1 July 2010 (from the original 1.50%); being further reduced to 0.10 %, effective from 1 January 2015. The Tier III controls apply only to the specified ships built from 2016 while operating in Emission Control Areas (ECA) established to limit NOx emissions, outside such areas the Tier II controls apply. The United States and Canada adopted national regulations enforcing IMO Tier III equivalent limits within the North American ECA effective 2016. The US Environmental Protection Agency (EPA) rule for Category III ships, however, references the international IMO standards. If the IMO emission standards are indeed delayed, the Tier III standards would be applicable from 2016 only for US flagged vessels. One of the proposed solutions towards marine diesel emission control is the non-thermal plasma process. We designed and built a non-thermal plasma reactor (NTPR) using a combination of Microwave (MW) and Electron Beam (EB) for treatment of marine diesel exhaust gas. A numerical model has been developed to better understand the marine exhaust gas/plasma kinetics. The reactor modelling and design can sustain 10kW of combined MW and EB power with a gas flow rate of 200l/s. The removal of NOx and SOx was continuously monitored using a portable dual Testo gas analyzer system while all other parameters (MW power, EB power, gas temperature/flow rate, etc.) were remotely recorded & stored through a Labview DAQ system. The reactor performance in NOx and SOx removal will be tested on a 200 kW two stroke marine engine. This study is a part of the DEECON (Innovative After-Treatment System for Marine Diesel Engine Emission Control) FP7 European project.The work was supported by the European Commission under DEECON FP7 European Project "Innovative After-Treatment System for Marine Diesel Engine Emission Control", contract No. 284745

Investigation of boost pressure and spark timing on combustion and NO emissions under lean mixture operation in hydrogen engines

Hydrogen may become a replacement for liquid fossil fuels, contributing to greenhouse gas emissions reductions by improving the thermal efficiency of boosted lean burn spark ignition engines. Single-zone engine combustion models are simple, but can yield useful results as a step in the design process for developing alternative fuel systems. The single-zone thermodynamic model is advanced by implementing a laminar flame speed sub-model to investigate combustion, an extended Zeldovich mechanism for nitric oxide emissions, and incorporating the Livengood-Wu integral model for knock characteristics. The results were validated using published experiments giving satisfactory predictions between simulation and experiment for spark timing variation, manifold air pressure, and equivalence ratios. A detailed analysis of boosted lean burn strategies showed that nitric oxide emissions increased with boosted pressure, hence emissions can be controlled through optimizing the excess air ratio and the start of combustion. Further techniques to achieve high thermal efficiency and to prevent knock for boosted lean burn hydrogen SI engine are discussed

Experimental understanding on the dynamics of micro-explosion and puffing in ternary emulsion droplets

Dynamics of puffing and micro-explosion phenomena occurring in ternary fuel emulsion droplets under high temperature environment were explored using high speed backlight imaging technique. A single droplet composed of diesel-biodiesel-ethanol emulsion was placed at the tip of a 75 µm gauge thermocouple and introduced rapidly into a furnace maintained at 500 °C. Several interesting features such as oscillation of suspended droplets, physical transformations occurring within the droplet, vapour expulsion, puffing, micro-explosion, sheet formation, perforations, growth of perforations, sheet disintegration and rotation of secondary droplets were observed. High resolution image analysis revealed separation of emulsion components within the core of the suspended droplet, which appeared either as a single nucleus or multiple nuclei. Two distinct types of micro-explosion were identified. For droplets encountering a single nucleus at the core resulted in a stronger vapour expulsion followed by intense micro-explosion. For droplets having multiple nuclei at the core resulted in a weaker vapour expulsion and slower growth of droplet prior to micro-explosion. Both types of micro-explosion process resulted in a number of child droplets. For the case of strong vapour expulsion nearly 80% of its child droplets have their sizes distributed within 150 μm compared to 60% for weaker vapour expulsion. The child droplets that were generated from the primary events of both puffing and micro-explosion cascaded further into secondary and tertiary events of puffing and micro-explosion in freely suspended environment.EPSR

Spray characteristics of air-assisted urea -SCR sprays of sub-atmospheric temperatures

EPSR

Quantitative nitric oxide measurements by means of laser-induced fluorescence in a heavy-duty Diesel engine

Quantitative in-cylinder laser-induced fluorescence measurements ofnitric oxide in a heavy-duty Diesel engine are presented. Special attention is paid to experimental techniques to assess the attenuation of the laser beam and the fluorescence signal by the cylinder contents.This attenuation can be considerable at certain stages in the combustionstroke. The temperature and pressure dependence of the fluorescence signal is described in various models. In this study, LIFsim was used.Finally, calibration was realized by concentration measurements in the exhaust gas