1 research outputs found
Synthesis, Crystal Structure, and Luminescent Properties of Novel Zinc Metal–Organic Frameworks Based on 1,3-Bis(1,2,4-triazol-1-yl)propane
Three
new zinc three-dimensional coordination polymers with flexible 1,3-bisÂ(1,2,4-triazol-1-yl)Âpropane
ligand were synthesized. The crystal structures of synthesized compounds
were determined, and structural peculiarities are discussed. Coordination
compounds with composition [ZnÂ(btrp)Â(bdc)]·<i>n</i>DMF are interpenetrated frameworks, while metal–organic framework
(MOF) [Zn<sub>3</sub>(btrp)Â(bdc)<sub>3</sub>]·<i>n</i>DMF is not. Thermal stability and luminescent properties of synthesized
compounds have been investigated. The possibility of usage of such
compounds as sensitive materials for some aromatic compounds are explored,
and it was shown that luminescence of coordination polymers is completely
quenched in the presence of nitrobenzene. Sorption properties of synthesized
MOFs toward nitrogen, carbon dioxide, and hydrogen were evaluated