Primary Au prospecting results in the Logrosán area (Central Iberian Zone, Spain).

The Central Iberian Zone presents an exceptional geological interest for its great exploration potential for a number of elements including gold. Metallogeny within the area is mainly related to regional metamorphism and late magmatic activity during the Variscan orogeny. In 2013-2014 junior company Mineral Exploration Network Ltd. has carried out an extensive prospecting field work with a primarily view to discover Au within the area around Logrosan granitic pluton (Cáceres, Spain). The main output of the survey was a localization and presorting of potentially mineralized territory unites at the extensive spatial scale (more than 240 sq. km). The known gold showings in the Central Iberian zone are considered to be synorogenic with a mainly metamorphic fluid source. As arsenic commonly forms widespread geochemical haloes near practically all orogenic gold deposits and appears to be easily and credibly measured by express analytical methods (XRF), it was selected as one of the major pathfinder elements for the initial prospecting. Designed geochemical survey allowed delineating potential target area with contrastive complex As-W-Zn-Pb anomaly in soil sediments and significant quantities of gold particles in heavy mineral concentrates. Placer gold particles analyses and their typomorphic features confirmed nearby primary gold source existence. The suggested scope of work proved to be efficient for assessing mineralization potential and selecting perspective target areas for a detailed drilling.  La Zona Centro Ibérica muestra un interés geológico excepcional debido a su gran potencial de exploración de gran número de elementos, incluido el oro. La metalogenia en esta área está relacionada con un metamorfismo regional y posterior actividad magmática durante la orogenia Varisca. Durante el periodo 2013-2014, la compañía Mineral Exploration Network Ltd llevó a cabo una prospección importante en el campo con una primera observación de Au dentro del área del plutón granítico de Logrosan (Cáceres, España). El primer objetivo de la campaña fue la localización y acotamiento de la zona potencialmente mineralizada a gran escala (más de 20 Km2). El oro descrito es considerado sinorogénico con una fuente principal relacionada con fluidos metamórficos. Como el arsénico aparece frecuentemente constituyendo geoquímicos halos cerca de la mayoría de los depósitos orogénicos de oro y parecen ser medidos fácilmente mediante métodos analíticos (XRF), fue seleccionado como uno de los principales elementos marcadores para realizar la prospección inicial. Los análisis geoquímicos seleccionados permitieron delimitar la zona de interés mediante el contraste del complejo anómalo As-W-Zn-Pb en los sedimentos del suelo y cantidades significativas de partículas de oro en concentraciones de minerales pesados. Los análisis de las partículas de los placeres de oro y sus características tipomórficas confirmaron inicialmente la presencia de oro. El objetivo inicial de este trabajo consistió en mostrar la eficiencia para tasar el potencial de mineralización y seleccionar las áreas idóneas para realizar perforaciones

Features of olivine crystallization in ordinary chondrites (Saratov meteorite): geochemistry of trace and rare earth elements

The paper discusses the geochemistry of major (EPMA) and trace (SIMS) elements in olivine of porphyritic, nonporphyritic chondrules, and the matrix of equilibrated ordinary chondrite Saratov (L4). Olivine corresponds to forsterite and is rather heterogeneous (Fo 73-77). No differences in the content of the major elements in the olivine of the chondrule and the matrix of the meteorite were found. However, the content of major and trace elements in olivine within chondrules varies considerably; high values found in olivine from barred chondrules. Olivine from porphyritic chondrules and the matrix of the Saratov meteorite have similar concentrations of trace elements. High concentrations of refractory (Zr, Y, Al) and moderately volatile (Sr and Ba) trace elements in barred olivine chondrule indicate the chondrule melt formation due to the melting of precursor minerals and its rapid cooling in the protoplanetary disk, which is consistent with the experimental data. The olivine of the chondrules center of the Saratov meteorite differs from the olivine of the chondrules rims and meteorite matrix by the increased values of the Yb/La ratio. No relict grains and magnesian cores of olivine were found in meteorite chondrules. Individual grains in the chondrules are distinguished by their enrichment in trace elements relative to the rest of the olivine grains in the chondrule

Fahlbands of the Keret archipelago, White Sea: the composition of rocks and minerals, ore mineralization

This paper presents a complex mineralogical and geochemical characteristic (based on SEM-EDS, ICP-MS analysis) of the fahlband rocks of the Kiv-Guba-Kartesh occurrence within the White Sea mobile belt (WSMB). The term “fahlband” first appeared in the silver mines of Kongsberg in the 17th century. Now fahlbands are interlayers or lenses with sulfide impregnation, located in the host, usually metamorphic rock. The level of sulfide content in the rock  exceed the typical accessory values, but at the same time be insufficient for massive ores. Fahlbands are weathered in a different way than the host rocks, so they are easily distinguished in outcrops due to their rusty-brown color. The studied rocks are amphibolites, differing from each other in garnet content and silicification degree. Ore mineralization is represented mainly by pyrrhotite and pyrite, and pyrrhotite grains are often replaced along the periphery by iron oxides and hydroxides, followed by pyrite overgrowth. At the same time, the rock contains practically unaltered pyrrhotite grains of irregular shape with fine exsolution structures composed of pentlandite, and individual pyrite grains with an increased Ni content (up to 5.4 wt.%). A relatively common mineral is chalcopyrite, which forms small grains, often trapped by pyrrhotite. We have also found single submicron sobolevskite and hedleyite grains. The REE composition of the fahlband rocks suggests that they are related to Archean metabasalts of the Seryakskaya and Loukhsko-Pisemskaya structures of the WSMB, rather than with metagabbroids and metaultrabasites common in the study area

Composition of spherules and lower mantle minerals, isotopic and geochemical characteristics of zircon from volcaniclastic facies of the Mriya lamproite pipe

The article presents the results of studying the rocks of the pyroclastic facies of the Mriya lamproite pipe, located on the Priazovsky block of the Ukrainian shield. In them the rock's mineral composition includes a complex of exotic mineral particles formed under extreme reduction mantle conditions: silicate spherules, particles of native metals and intermetallic alloys, oxygen-free minerals such as diamond, qusongite (WC), and osbornite (TiN). The aim of the research is to establish the genesis of volcaniclastic rocks and to develop ideas of the highly deoxidized mantle mineral association (HRMMA), as well as to conduct an isotopic and geochemical study of zircon. As a result, groups of minerals from different sources are identified in the heavy fraction: HRMMA can be attributed to the juvenile magmatic component of volcaniclastic rocks; a group of minerals and xenoliths that can be interpreted as xenogenic random material associated with mantle nodules destruction (hornblendite, olivinite and dunite xenoliths), intrusive lamproites (tremolite-hornblende) and crystalline basement rocks (zircon, hornblende, epidote, and granitic xenoliths). The studied volcaniclastic rocks can be defined as intrusive pyroclastic facies (tuffisites) formed after the lamproites intrusion. Obviously, the HRMMA components formed under extreme reducing conditions at high temperatures, which are characteristic of the transition core-mantle zone. Thus, we believe that the formation of primary metal-silicate HRMMA melts is associated with the transition zone D"

Pseudorutile-leucoxene-quartz ores of Timan ‒ a new genetic type of titanium raw materials: prospects for industrial development

The two largest deposits of Russia – Yaregskoye and Pizhemskoye belong to the same genetic type; hydrothermal-metamorphic indigenous deposits. They are located in the same Timan structure at a distance of no more than 230 km from each other. According to the total approved reserves and forecast resources of titanium dioxide, they are approaching 60% of the all-Russian and will form the basis of industrial titanium raw materials used in Russia in the near future. In the interests of technological mineralogy, morphological features, internal structure, chemical composition of grains of the two main titanium mineral phases ‒ leucoxene and pseudorutile, TiO2 polymorphs, as well as the composition of mineral microinclusions in these phases have been studied in detail. The compositions of all mineral phases in polished preparations of leucoxene and pseudorutile were analyzed by SEM-EDS method at the Institute of Geology and Geochronology of the Precambrian of the RAS, 147 chemical analyses were obtained at the point (3 µk) and many images of polished grains of anatase, leucoxene and pseudorutile were scanned over the area (20×20 µk). In the leucoxene grains themselves, 12 mineral phases were diagnosed and characterized in the form of inclusions: pseudorutile, rutile, anatase, quartz, hydromuscovite-illite, kaolinite, siderite, zircon, xenotime, pyrite, florencite, monazite and kularite. TiO2 polymorphs are verified by Raman spectroscopy and X-ray diffraction analysis. New evidence has been obtained that the transformation of ilmenite into leucoxene occurs hydrothermally through intermediate phases ‒ Fe-rutile and pseudorutile; the enlargement of rutile crystals in the leucoxene grain itself is shown; the presence of secondary crystals of siderite, florencite and others inside the studied grains